Bromide-mediated membraneless electrosynthesis of ethylene carbonate from CO2 and ethylene [PDF]
Nature CommunicationsCyclic carbonates, such as ethylene carbonate, are crucial in various applications, including lithium-ion batteries and polymers. Traditional production routes for ethylene carbonate rely on high-temperature thermocatalytic processes that use fossil-fuel-
Menglu Cai +3 more
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Protonated Ethylene Carbonate: A Highly Resonance‐Stabilized Cation [PDF]
ChemistryOpen, 2021 Invited for this month's cover picture is the group of Prof. Andreas J. Kornath at the LMU in Munich (Germany). The cover picture shows the crystal structure of the salt of protonated ethylene carbonate [C3H5O3][Sb2F11]. Protonated ethylene carbonate was
Stefanie Beck +2 more
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Breaking solvation dominance of ethylene carbonate via molecular charge engineering enables lower temperature battery [PDF]
Nature Communications, 2023 Low temperatures severely impair the performance of lithium-ion batteries, which demand powerful electrolytes with wide liquidity ranges, facilitated ion diffusion, and lower desolvation energy.
Yuqing Chen +12 more
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High-speed C–H chlorination of ethylene carbonate using a new photoflow setup [PDF]
Beilstein Journal of Organic Chemistry, 2022 We report the high-speed C–H chlorination of ethylene carbonate, which gives chloroethylene carbonate, a precursor to vinylene carbonate. A novel photoflow setup designed for a gas–liquid biphasic reaction turned out to be useful for the direct use of ...
Takayoshi Kasakado +4 more
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Synthesis of Glycerol Carbonate from Ethylene Carbonate Using Zinc Stearate as a Catalyst: Operating Conditions and Kinetic Modeling [PDF]
Molecules, 2023 With the advent of biodiesel as a substitute/additive for diesel, the production of glycerol has experienced an increase, as it is an unavoidable byproduct of the biodiesel process; therefore, novel products and processes based on this triol are being ...
Mariana Alvarez Serafini +4 more
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Palladium-catalyzed allylic etherification of phenols with vinyl ethylene carbonate [PDF]
Frontiers in Chemistry, 2022 The palladium-catalyzed decarboxylative reactions of phenols and vinyl ethylene carbonate to produce allylic aryl ethers under mild conditions have been established.
Shibo Lin +7 more
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Polymer Electrolytes Based on Na-Nafion Plasticized by Binary Mixture of Ethylene Carbonate and Sulfolane [PDF]
Membranes, 2022 The development of post-lithium current sources, such as sodium-ion batteries with improved energy characteristics and an increased level of safety, is one of the key issues of modern energy.
Anna A. Krupina +4 more
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Structure–Property Relationships of Poly(ethylene carbonate) and Poly(propylene carbonate) [PDF]
ACS Omega, 2017 Yuji Sasanuma, Yuta Takahashi
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MeTFSI (Me = Li, Na) Solvation in Ethylene Carbonate and Fluorinated Ethylene Carbonate: A Molecular Dynamics Study [PDF]
The Journal of Physical Chemistry B, 2021 Classical and ab initio molecular dynamics (MD) simulations have been performed for electrolytes based on LiTFSI and NaTFSI solutions in ethylene carbonate and its mono- and difluoro derivatives. Differences between electrolytes with Li+ or Na+ ions and the effect of fluorination on the structure and transport properties have been analyzed.
Piotr Wróbel +2 more
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Aquatrifluoridoboron–1,3-dioxolan-2-one (1/2)
IUCrData, 2023 The crystal structure of the co-crystal of aquatrifluoridoboron with two ethylene carbonate (systematic name: 1,3-dioxolan-2-one) molecules, BF3H2O·2OC(OCH2)2, was determined by low-temperature single-crystal X-ray diffraction.
Kristian Radan +3 more
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