Improving autotrophic D-lactate production by heterologous expression of a pyruvate formate lyase in an LDHD-expressing Acetobacterium woodii strain. [PDF]
Baur KS +3 more
europepmc +1 more source
Caging Polyhalide Anions in Polycyclodextrin for Long‐Lasting Aqueous Zinc‐Iodine Batteries
We demonstrated poly(β‐cyclodextrin) gel as an ideal host material that effectively contains and releases polyhalide anions in aqueous zinc‐iodine batteries. Such a unique host‐guest chemistry prevents the shuttle effect of polyhalides. The corresponding batteries can operate via both 2e and 4e storage, attaining 60,000 cycles with more than 99% and 85%
Shangxu Jiang +7 more
wiley +1 more source
A unique dual d–p orbital hybridization strategy was established in a ternary PtGaGe alloy catalyst to overcome the longstanding activity–stability trade‐off in oxygen reduction reaction (ORR). Synergistic hybridization between Ga/Ge p orbitals and Pt d orbitals modulates the Pt electronic structure, optimizes oxygen intermediates adsorption, and ...
Qian Zhang +8 more
wiley +1 more source
Petrophysical characterization and chemical treatment of oil reservoir as a tool for choosing the best improved oil recovery techniques. [PDF]
Abou-Alfitooh SAM +5 more
europepmc +1 more source
In this work, we establish a direct correlation between internal compactness and particle architectural stability, identifying it as a key descriptor of cathode structural integrity. Simultaneously, the capacity contribution and compensation mechanism of ARR are resolved, revealing that the extent of irreversible capacity loss is governed by both the ...
Yizhen Huang +24 more
wiley +1 more source
Theoretical insight into the effect of CO coverage on formic acid formation from dissociated oxygen on χ-Fe<sub>5</sub>C<sub>2</sub>(510) in Fischer-Tropsch synthesis. [PDF]
Jiang J +6 more
europepmc +1 more source
Speciation‐Controlled C–F Bond Functionalization Enabled by Zwitterionic Pnictinidenes
Zwitterionic pnictinidenes turn C–F activation into C–X bond construction, enabling broad defluorinative functionalization of polyfluoro(hetero)arenes under mild conditions. Rather than following a metallomimetic Sb(I)/Sb(III) redox turnover, catalysis is redirected by ligand scrambling into a redox‐neutral manifold, revealing catalyst speciation as a ...
Irene Sánchez‐Sordo +4 more
wiley +1 more source
Non-radical pathways control methane sulfonation <i>versus</i> oxygenation C-H functionalization selectivity with Hg(ii) and Au(iii) catalysis. [PDF]
Koppaka A +5 more
europepmc +1 more source
Two isostructural conjugated‐MOFs (Fe‐Tp and Mn‐Tp) photocatalysts were engineered with nonequivalent microenvironmental redox tuning for hydrogen peroxide production. The manganese analog engages both the oxygen reduction reaction and the water oxidation reaction while suppressing decomposition, delivering 10 487 µmol g−1 h−1 with an apparent quantum ...
Kayaramkodath Chandran Ranjeesh +10 more
wiley +1 more source

