Results 171 to 180 of about 3,255,505 (313)

Persistent Mono‐Oxo Bonding with Protactinium(V) Revealed in Highly Acidic Chloride Solutions

open access: yesAngewandte Chemie, EarlyView.
Protactinium(V) defies expectations. Its elusive mono‐oxo bond was revealed through a combination of extended X‐ray absorption fine structure (EXAFS) and X‐ray absorption near‐edge structure (XANES) analyses, as well as quantum chemical calculations. This bond persists even in 12 M HCl.
Melody Maloubier   +9 more
wiley   +2 more sources

Mitigating Thermal Runaway in Lithium Metal Batteries With Flame‐Retardant Magnesium Hydroxide Nanocomposite Gel Electrolytes

open access: yesAdvanced Energy Materials, EarlyView.
Lithium‐ion batteries are ubiquitous but pose significant safety risks especially with high‐energy‐density electrode materials. This study reports a nanocomposite gel electrolyte (NGE) with a flame‐retardant magnesium hydroxide (MH) matrix, which offers robust mechanical properties, high ionic conductivity, and enhanced thermal safety.
Cory M. Thomas   +5 more
wiley   +1 more source

Acid‐ and Nucleophile‐Gated Photoisomerization of Phosphaindirubin

open access: yesAngewandte Chemie, EarlyView.
Triply gated isomerization: In polar solvents, a phosphorus‐containing indirubin photoswitch undergoes visible‐light‐driven Z→E isomerization only when protonated, and reverts thermally via nucleophile‐catalyzed back‐isomerization. This three‐way control by light, acid, and nucleophile enables reversible photoisomerization.
Jacob Jan van der Wal   +8 more
wiley   +2 more sources

Microfluidic Mixing with the Dynamic Control of Magnetic Actuation

open access: yesAdvanced Intelligent Systems, EarlyView.
Schematic illustration and flow field visualization of magnetically actuated L‐shaped microrobots displaying cooperative vortex generation for enhanced microscale mixing. The left side shows the electromagnetic actuation setup, which enables programmable control of rotational direction and frequency.
Prashant Kishor Sharma   +2 more
wiley   +1 more source

Singlet Fission in Push–Pull Para‐Azaquinodimethane Films under the Gaze of Time Resolved Optical and Magnetic Spectroscopy

open access: yesAngewandte Chemie, EarlyView.
New push–pull para‐azaquinodimethane derivatives were synthetized through a sustainable protocol. Transient absorption results showed ultrafast intermolecular singlet fission (SF) in film and demonstrated for AsOMe higher triplet energy than for literature SF materials, with intriguing perspectives for photovoltaics toward silicon matched SF.
Martina Alebardi   +11 more
wiley   +2 more sources

Phylogenomics, ecomorphological evolution, and historical biogeography in Deuterocohnia (Bromeliaceae: Pitcairnioideae)

open access: yesAmerican Journal of Botany, EarlyView.
Abstract Premise Species of Deuterocohnia (17 spp.) show extraordinary variation in elevation (0–3900 m a.s.l.) and growth forms, and many have narrow geographic distributions in the west‐central Andes and the Peru‐Chile coast. Previous research using few plastid and nuclear loci failed to produce well‐resolved or supported phylogenies.
Bing Li   +5 more
wiley   +1 more source

Multidirectional Charge Separation in Self‐Assembled Aggregates of Perylenebisimide‐Porphyrin Bola‐Supra‐Amphiphiles

open access: yesAngewandte Chemie, EarlyView.
Stable aggregates of a new hydrogen‐bond mediated porphyrin‐perylenebisimide (PBI) bola‐type supra‐amphiphile have been synthesized by lyophilization of solutions of both single molecules in THF/water mixtures, followed by redispersion in pure water. Cryogenic transmission electron microscopy verifies the spherical morphology.
Erik J. Schulze   +6 more
wiley   +2 more sources

Dual Modality Semiconducting Polymer Nanoparticles for Use in Optical and Magnetic Resonance Imaging

open access: yesAdvanced NanoBiomed Research, EarlyView.
Well‐defined dual‐modality semiconducting polymer nanoparticles composed of red‐emitting conjugated polymers functionalized with novel gadolinium‐based contrast agents have been prepared. The assemblies show a greatly enhanced relaxivity performance compared to the clinical standard, Dotarem, while offering ultrabright fluorescence, ideal for optical ...
Faysal A. Farah   +5 more
wiley   +1 more source

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