Aromatic Diester Anolytes for Nonaqueous Redox Flow Batteries
Owing to their extended π‐conjugation 2,2′‐bipyridyl aromatic diesters are stable in singly‐ and doubly‐reduced states. In a redox flow battery a high battery voltage of 2.82 V can be realized and a capacity a capacity retention of 99.5% per cycle for 260 cycles.
Nicolas Daub +2 more
wiley +1 more source
A Sustainable and Low‐Cost Zn‐Lignosulfonate Redox Flow Battery
A cost‐effective Zn/lignosulfonate (NaLS) hybrid flow battery using 20 kDa NaLS delivers 3.52 Ah L−1 at 30 mM, with an average discharge voltage of 1.01 V, outperforming smaller NaLS. This sustainable design leverages industrial and bio‐based lignosulfonates, cheaper size exclusion membrane, and abundant Zn for ecofriendly, scalable energy storage ...
Athul Seshadri Ramanujam +3 more
wiley +1 more source
Phosphine-porphyrin conjugates : a thesis presented in partial fulfilment of the requirements for the degree of Masterate of Science in Chemistry at Massey University, New Zealand [PDF]
The research carried out in this thesis comprises an investigation into the synthesis and characterisation of a variety of complexed phosphine-aldehydes, complexed phosphinoporphyrins, and phosphinoferrocene conjugates.
Lun, David James
core
ABSTRACT Biopharmaceutical manufacturing requires robust analytics and process controls throughout production to insure high yield of quality products. New methodologies for rapidly accessing and integrating data‐rich information from complex dynamic biological environments are of great interest.
Kayla Chun +8 more
wiley +1 more source
Enhanced Tunnelling in a Hybrid of Single-Walled Carbon Nanotubes and Graphene
Transparent and conductive films (TCFs) are of great technological importance. The high transmittance, electrical conductivity and mechanical strength make single-walled carbon nanotubes (SWCNTs) a good candidate for their raw material.
Kauppinen, Esko I. +11 more
core +1 more source
Advancing design strategies in smart stimulus‐responsive liposomes for drug release and nanomedicine
Schematic illustration of stimulus‐responsive liposomes designed for controlled drug release and nanomedicine. The innermost circle represents different liposomal structures, including unilamellar, multilamellar, and multivesicular liposomes. The middle layer illustrates the responsive phospholipid components.
Yuchen Guo +9 more
wiley +1 more source
Multielectron Redox Chemistry of Transition Metal Complexes Supported by a Non‐Innocent N3P2 Ligand: Synthesis, Characterization, and Catalytic Properties [PDF]
A new redox‐active, diarylamido‐based ligand (LN3P2) capable of κ5‐N,N,N,P,P chelation has been used to prepare a series of complexes with the general formula [MII(LN3P2)]X, where M = Fe (1; X = OTf), Co (2; X = ClO4), or Ni (3; X = ClO4).
Ekanayake, Danushka M. +4 more
core +1 more source
A modular synthetic approach enables the preparation of azulene‐fused heterocycles via nucleophilic aromatic substitution followed by intramolecular cyclization of alkynyl fluoroazulenes. The method allows the incorporation of various heteroatoms (N, O, S, Se, and Te), leading to structurally diverse heteroannulated azulenes.
Martin C. Dietl +8 more
wiley +1 more source
An Unusual Hydrogen Migration/C−H Activation Reaction with Group 3 Metals [PDF]
A novel hydrogen migration from the phenyl ring to the pyridine ring of an yttrium pyridyl complex supported by a 1,1′-ferrocene diamide ligand is reported.
Benitez, Diego +5 more
core +1 more source
Dipolar Molecular Motor Candidates with Planar Chirality
Two prototypes of molecular motors with simultaneous implementation of planar chirality and a permanent dipole have been designed and synthesized in 7 steps with overall yields of 2.8 to 5.5%. Abstract Two molecular motor candidates built around ruthenium(II) centers featuring both planar chirality and a permanent dipole have been synthesized in seven ...
Thomas A. Hector +5 more
wiley +1 more source

