The Role of Torsional Dynamics on Hole and Exciton Stabilization in π‐Stacked Assemblies: Design of Rigid Torsionomers of a Cofacial Bifluorene [PDF]
, 2018 Exciton and charge delocalization across π‐stacked assemblies is of importance in biological systems and functional polymeric materials. To examine the requirements for exciton and hole stabilization, cofacial bifluorene (F2) torsionomers were designed ...
Cai, Jin-Zhe +6 more
core +2 more sources
Unraveling the Coulombic Forces in Electronically Decoupled Bichromophoric Systems during Two Successive Electron Transfers [PDF]
, 2017 Coulombic forces are vital in modulating the electron transfer dynamics in both synthetic and biological polychromophoric assemblies, yet quantitative studies of the impact of such forces are rare, as it is difficult to disentangle electrostatic forces ...
Ivanov, Maxim V. +3 more
core +2 more sources
Assessment and Characterization of Alkylated PAHs in Selected Sites across Canada
Atmosphere, 2022 Alkylated polycyclic aromatic hydrocarbons (alkyl-PAHs), dibenzothiophenes (DBTs), and unsubstituted polycyclic aromatic hydrocarbons (PAHs) are naturally present in fossil fuels.
Andrzej Wnorowski +5 more
doaj +1 more source
(Sila)Difluoromethylation of Fluorenyllithium with CF3H and CF3TMS
SynOpen, 2018 Difluoromethylation of the C9-H site of the fluorene ring using lithium base and fluoroform (CF3H), which is one of the most cost-effective difluoromethylating reagents, is attained to give difluoromethylated fluorenes with an all-carbon quaternary ...
Kenichi Maruyama +2 more
doaj +1 more source
Revue Marocaine des Sciences Agronomiques et Vétérinaires, 2023 Le lac Nokoué (Sud Bénin) est la pêcherie continentale la plus productive de l’Afrique de l’Ouest avec une très forte biodiversité, mais qui malheureusement il perd progressivement ses ressources à cause de sa pollution.
Prudencio AGBOHESSI +3 more
doaj +1 more source
The influence of spin-labeled fluorene compounds on the assembly and toxicity of the aβ peptide. [PDF]
PLoS ONE, 2012 The deposition and oligomerization of amyloid β (Aβ) peptide plays a key role in the pathogenesis of Alzheimer's disease (AD). Aβ peptide arises from cleavage of the membrane-associated domain of the amyloid precursor protein (APP) by β and γ secretases.
Jitka Petrlova +11 more
doaj +1 more source
Molecular Actuators in Action: Electron-Transfer-Induced Conformation Transformation in Cofacially Arrayed Polyfluorenes [PDF]
, 2018 There is much current interest in the design of molecular actuators, which undergo reversible, controlled motion in response to an external stimulus (light, heat, oxidation, etc.).
Cai, Sheng +7 more
core +3 more sources
Spreading Electron Density Thin: Increasing the Chromophore Size in Polyaromatic Wires Decreases Interchromophoric Electronic Coupling [PDF]
, 2018 The development of novel polychromophoric materials using extended polycyclic aromatic hydrocarbons as a single large chromophore holds promise for long-range charge-transfer applications in photovoltaic devices and molecular electronics.
Hossain, Mohammad Mosharraf +4 more
core +4 more sources
Palladium-Catalysed Coupling and Acid-Mediated Cyclisation: Synthesis of Fluorenones and Fluorenes
SynOpen, 2018 Palladium-catalysed sequential one-pot synthesis of fluorenones is described. The reaction comprises intermolecular Suzuki coupling and intramolecular acid-mediated cyclisation in a one-pot procedure.
Devarapalli Ravi Kumar +2 more
doaj +1 more source
A facile synthesis of novel indole derivatives as potential antitubercular agents
Journal of Taibah University for Science, 2017 A novel series of 5,5-dimethyl-11-phenyl-4b,5,5a,10,10a,11,11a,12-octahydro-10,11,12-triaza-indeno[2,1-b]fluorenes 3aâ3l were prepared by reacting oxindole, aryl amines and acetone using dibutylamine as an organocatalyst via simultaneous Knoevenagel ...
Gulzar A. Khan +5 more
doaj +1 more source