Results 31 to 40 of about 19,687 (245)

Diatom aggregation when exposed to crude oil and chemical dispersant: Potential impacts of ocean acidification.

open access: yesPLoS ONE, 2020
Diatoms play a key role in the marine carbon cycle with their high primary productivity and release of exudates such as extracellular polymeric substances (EPS) and transparent exopolymeric particles (TEP). These exudates contribute to aggregates (marine
Jennifer L Genzer   +6 more
doaj   +1 more source

Spiro‐Phenothiazine Hole‐Transporting Materials: Unlocking Stability and Scalability in Perovskite Solar Cells

open access: yesAdvanced Materials, EarlyView.
Fluorene‐functionalized spiro‐phenothiazine (PTZ‐Fl) exhibits strong Li+ affinity and thermal stability, enabling a PCE of 25.75% in small‐area cells and 22.07% in 25 cm2 modules. Under ISOS‐L3 conditions, PTZ‐Flbased devices retain over 80% efficiency after 1000 hours, demonstrating superior stability and scalability compared to spiro‐OMeTAD for next ...
Javier Urieta‐Mora   +17 more
wiley   +1 more source

Transformation of Substituted Fluorenes and Fluorene Analogs by Pseudomonas sp. Strain F274 [PDF]

open access: yesApplied and Environmental Microbiology, 1995
Pseudomonas sp. strain F274, previously shown to catabolize fluorene via fluorenone and its angular dioxygenation, 2(prm1),3(prm1)-dihydroxy-2-carboxybiphenyl, phthalate, and protocatechuate, was examined for its ability to transform substituted fluorenes and S- and N-heterocyclic analogs.
M, Grifoll, S A, Selifonov, P J, Chapman
openaire   +2 more sources

Role of the Recombination Zone in Organic Light‐Emitting Devices

open access: yesAdvanced Materials, EarlyView.
This review summarizes the critical role of the recombination zone in organic light‐emitting diodes (OLEDs). We highlight that broadening the recombination zone in OLEDs based on emissive layers with balanced charge transport and high photoluminescence quantum yields provides a promising route toward achieving both long operational lifetime and high ...
Yungui Li, Karl Leo
wiley   +1 more source

Origin of Dark Current Robustness in Photomultiplication Organic Photodetectors Enabled by Ionic Conjugated Electron‐Blocking Layers

open access: yesAdvanced Materials, EarlyView.
Ionic conjugated polyelectrolyte electron‐blocking layers enable photomultiplication organic photodetectors with dark current robustness up to −10 V and external quantum efficiencies exceeding 3000%. Fowler–Nordheim tunneling, interfacial dipole, trap density of states, and noise analyses reveal how ionic conjugated polyelectrolytes suppress electron ...
Yelim Kang   +12 more
wiley   +1 more source

Tunable Synthesis of Multi‐Responsive NH‐Containing Helical Nanographenes With a Chiroptical Switching Function

open access: yesAngewandte Chemie, EarlyView.
The Scholl reaction of 1,3,6,8‐tetrakis(oligophenyl)‐appended carbazoles afforded stable NH‐containing helical nanographenes, which showed significant redshift and reversible on/off switching of CPL upon the addition of base and acid, respectively. Furthermore, excited‐state proton transfer occurred in dimethyl sulfoxide to generate anionic species ...
Chihiro Maeda   +7 more
wiley   +2 more sources

C(sp3)–H hydroxylation of fluorenes, oxindoles and benzofuranones with a Mg(NO3)2-HP(O)Ph2 oxidation system

open access: yesOrganic Chemistry Frontiers, 2019
A novel oxidation system in which magnesium nitrate [Mg(NO3)2] is used as an oxidant in the presence of diphe-nylphosphine oxide [HP(O)Ph2] permits the C(sp3)–H hydroxylation of fluorenes, oxindoles, and benzofuranones.
Cheng Hu   +6 more
semanticscholar   +1 more source

Metal Oxide Nano‐Interface Boosting the Deep Ultraviolet Adjustable Noise‐Filtering In‐Sensor Computing

open access: yesAdvanced Materials, EarlyView.
We show that sol‐gel‐fractured indium–magnesium oxide combines deep‐ultraviolet responsivity, high carrier mobility, and an excellent memory dynamic range. This unique materials platform enables deep‐ultraviolet long‐afterglow light‐emitting devices with multifunctional integration.
Zhongshi Ju   +9 more
wiley   +1 more source

Adsorption‐Engineered Hydrocarbon Ionomers for Durable Proton‐Exchange Membrane Fuel Cells

open access: yesAdvanced Materials, EarlyView.
Hydrocarbon ionomers suffer from oxidation‐driven interfacial degradation in PEM fuel cell cathodes, leading to catalyst instability. Here, adsorption‐engineered poly(fluorene) ionomers decouple interfacial anchoring from oxidative degradation, enabling strong catalyst–ionomer interactions while resisting electrochemical oxidation.
Heemin Park   +14 more
wiley   +1 more source

Visible‐Light‐Induced Carbon–Hydrogen Phosphonylation of Conjugated Polymers via Electron Donor–Acceptor Complex Activation

open access: yesAngewandte Chemie, EarlyView.
Electron donor–acceptor (EDA) complex activation enabled the efficient transformation of conjugated polymers. Compared with the small‐molecule model compound, the polymers reacted more efficiently, achieving quantitative conversion of PFO. This result demonstrates a new platform for incorporating conjugated polymers into EDA‐mediated photochemical ...
Tomohiro Tamano   +4 more
wiley   +2 more sources

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