Results 41 to 50 of about 19,687 (245)

A denitrogenative palladium-catalyzed cascade for regioselective synthesis of fluorenes

Chemical Science, 2019
We herein report a denitrogenative palladium-catalyzed cascade for the modular and regioselective synthesis of polysubstituted fluorenes. Hydrazone facilitates the Pd(ii) to Pd(iv) oxidative addition in a Catellani pathway and is also the methylene ...
Wai Chung Fu, F. Kwong
semanticscholar   +1 more source

Tailoring Amine Substitution in Fluorene and Dibenzothiophene: A Molecular Strategy for Ultralong Organic Phosphorescence

Advanced Optical Materials, EarlyView.
Tailored amine substitution in fluorene and dibenzothiophene derivatives enables systematic control of excited‐state properties and triplet population. Combined photophysical studies, TD‐DFT calculations and time‐resolved EPR reveal how charge‐transfer character, sulfur‐induced spin–orbit coupling and triplet manifold engineering cooperate to promote ...
Francesco Ruighi, Gianluca Accorsi, Eduardo Fabiano, Lorenzo Franco, Alessandro Agostini, Samuel Zatta, Leonard E. Cleve, Federica Angilè, Francesco Paolo Fanizzi, Gustavo Fernández, Agostina L. Capodilupo   +10 more
wiley   +1 more source

Molecularly Templated Buried Interfaces for Inverted Perovskite Solar Cells

Angewandte Chemie, EarlyView.
We demonstrate a molecularly matched buried interface between SAM and perovskite, enhancing adhesion and passivating defects. This optimized interface achieves 26.58% power conversion efficiency and 86.72% fill factor with exceptional operational stability in both large‐area and wide‐bandgap devices, thereby increasing efficiency and prolonging ...
Songyang Yuan, Quanrun Qiu, Huaiman Cao, Chengda Ge, Yiting Jiang, Gengyang Su, Lingyi Ke, Gengxin Du, Guangruixing Zou, Hui Liu, Guanhua Ren, Jing Wang, Nan Zhang, Yidan An, Qingduan Li, Ze Yu, Tao Jia, Yue‐Peng Cai, Shengjian Liu, Hin‐Lap Yip   +19 more
wiley   +2 more sources

High Free‐Volume Imidazole‐Based Ionomers for High‐Temperature Proton Exchange Membrane Fuel Cells

Advanced Science, EarlyView.
High free‐volume imidazole‐based ionomers (PF4IM‐72) enable enhanced phosphoric acid uptake and efficient proton transport, delivering peak power densities of 0.645 W cm−2 at 160 °C and 0.838 W cm−2 at 200 °C in HT‐PEMFCs. This work highlights a promising platform for next‐generation ionomers with improved high‐temperature performance and stability ...
Ge Chao, Hyeon Keun Cho, Chang Yeon Hyun, Shirong Li, Jong Geun Seong, So Young Lee, Nanwen Li, Young Moo Lee   +7 more
wiley   +1 more source

Synthesis of UV-resistant and colorless polyimide films for optoelectrical applications

npj Materials Degradation
Due to their excellent mechanical properties and intrinsic flexibility, polyimides (PIs) are promising candidates for optoelectrical applications under harsh conditions such as flexible organic solar cells as well as flexible smart windows, etc.
Le Xi, Yadong Lv, Jiabao Feng, Yanyan Huang, Yajiang Huang, Qi Yang, Guangxian Li, Miqiu Kong   +7 more
doaj   +1 more source

Computation‐Guided Control of Excited‐State Deactivation through Modulation of Conical‐Intersection Accessibility by Donor–Acceptor Asymmetry in Bridged Stilbene AIE Luminogens

Advanced Science, EarlyView.
Donor–acceptor asymmetry modulates conical‐intersection accessibility and topology in bridged stilbenes, providing mechanistic insight into excited‐state deactivation and aggregation‐induced emission (AIE). ABSTRACT A computation‐guided investigation of asymmetric donor–acceptor bridged stilbenes reveals structure–property relationships governing ...
Takuya Tanaka, Satoshi Suzuki, Hirosato Koyanagi, Kiyoshi Miyata, Riki Iwai, Kazunobu Igawa, Ken Onda, Ben Zhong Tang, Gen‐ichi Konishi   +8 more
wiley   +1 more source

Functionalized fluorenes via dicationic electrophiles

Tetrahedron Letters, 2019
Dicationic fluorenyl cations are shown to react with nitriles to provide amide-functionalized fluorenes. A similar reaction with alcohols gives ether derivatives.
Michael R. Stentzel, D. Klumpp
semanticscholar   +1 more source

Donor Extended Blue TADF Dendrimer for High‐Performance Solution‐Processed OLEDs

Advanced Science, EarlyView.
A dendronized MR‐TADF emitter, DOBNA‐SpAc‐DCz, was designed to improve solubility, hole transport, and exciton dynamics for solution‐processed OLEDs. Incorporation of ter(tert‐butylcarbazole) dendrons decreases ΔEST and accelerates RISC, yielding short delayed lifetimes (∼2 µs).
Mahni Fatahi, Yuka Yasuda, Ryo Kondo, Hironori Kaji, Eli Zysman‐Colman   +4 more
wiley   +1 more source

Interface‐Directed High Fluorescence Efficiency Two‐Dimensional Molecular Crystals With Surface‐Exposed Active Sites

Advanced Science, EarlyView.
Here, we designed the Me‐FBSe molecule and prepared a two‐dimensional molecular crystal via liquid‐liquid interface assembly. The crystal preserves the high photoluminescence quantum while simultaneously ensuring the high‐density surface exposure of active sites.
Shuya Liu, Yueqiang Zhang, Chuanqin Cheng, Jin Wang, Feiyong Chen, Yonglei Wang, Yanjun Gong   +6 more
wiley   +1 more source

Beyond Traditional Phenolics: Disulfide Bonds for Performance Enhancement of Aerospace Ablation‐Resistant Materials from Processing to Recycling

Advanced Science, EarlyView.
The dynamic disulfide bonds facilitated the development of high‐performance aerospace ablation‐resistant materials. At moderate temperature, the dissociation and recombination of disulfide bonds ensured excellent processability, mechanical properties, and recycling ability of phenolic resin; at high temperature, cleavage of disulfide bonds produced ...
Yu Li, Boyuan Hu, Xiaolong Xing, Huan Yang, Ziqi Zhang, Cheng Bian, Ruixue Bai, Ling Yue, Chengshuang Zhang, Xinli Jing   +9 more
wiley   +1 more source