Results 41 to 50 of about 4,019 (241)

Donor‐Strength‐Driven Evolution From Charge‐Transfer to Polymethine Excited States in CurcBF2 Derivatives

open access: yesAdvanced Optical Materials, EarlyView.
Donor strength governs the excited‐state character and TADF behavior of donor‐acceptor‐donor borondifluoride curcuminoid derivatives. Increasing donor strength drives a transition from charge‐transfer TADF to a zwitterionic polymethine structure with predominantly local excited‐state emission and suppressed TADF.
Anthony D'Aléo   +13 more
wiley   +1 more source

Beyond Traditional Phenolics: Disulfide Bonds for Performance Enhancement of Aerospace Ablation‐Resistant Materials from Processing to Recycling

open access: yesAdvanced Science, EarlyView.
The dynamic disulfide bonds facilitated the development of high‐performance aerospace ablation‐resistant materials. At moderate temperature, the dissociation and recombination of disulfide bonds ensured excellent processability, mechanical properties, and recycling ability of phenolic resin; at high temperature, cleavage of disulfide bonds produced ...
Yu Li   +9 more
wiley   +1 more source

Volatile Additives Engineering: A Trustworthy Morphology Control Strategy in Non‐Fullerene Organic Solar Cells

open access: yesAdvanced Science, EarlyView.
In this review, the classification and development history of the volatile solid and solvent additives are comprehensively summarized, the underlying mechanisms of morphology optimization are discussed, and a summary of volatile additive‐induced improvements in interfacial layer performance is provided.
Jianqiang Qin   +7 more
wiley   +1 more source

Straightforward Synthesis of Dihydrobenzo[a]fluorenes through Au(I)-Catalyzed Formal [3 + 3] Cycloadditions

open access: yes, 2016
Dihydrobenzo[a]fluorene derivatives have been prepared by a formal intramolecular [3 + 3] cycloaddition of o-alkynylstyrenes bearing a secondary alkyl group at the β-position of the styrene moiety.
Roberto Sanz (1508221)   +4 more
core   +1 more source

High‐Brightness and Ultra‐Long‐Lifetime Spin Quantum Dot Light‐Emitting Diodes Enabled by Efficient Injection of Spin‐Polarized Holes Through a Hybrid Hole Transport Layer

open access: yesAdvanced Science, EarlyView.
This work employs a hybrid hole transport layer to enhance hole transport efficiency, resulting in improved performance for the final device. It achieves an external quantum efficiency of 6.68%, a circularly polarized electroluminescence asymmetry factor of 0.026, and a high luminance of 14,370 cd/cm2, representing the highest luminance reported to ...
Fengqi Qiu   +8 more
wiley   +1 more source

Photochemical Radical Bicyclization of 1,5-Enynes: Divergent Synthesis of Fluorenes and Azepinones. [PDF]

open access: yesOrg Lett
A dual nickel- and iridium-photocatalyzed radical cascade bicyclization reaction for the synthesis of highly complex molecular structures in an atom- and step-economic manner has been described.
Gore BS, Chen CC, Lin PY, Wang JJ.
europepmc   +2 more sources

Multiscale Design of Anion Exchange Membrane‐Based Seawater Electrolysis for Sustainable Hydrogen Production

open access: yesAdvanced Energy Materials, EarlyView.
Direct seawater electrolysis using anion exchange membranes is emerging as a promising route for sustainable hydrogen production. This review summarizes multiscale design strategies from seawater chemistry and OER–ClER selectivity to catalysts, membranes, MEAs, cells, stacks, and system integration, providing a roadmap toward selective, durable, and ...
Chiho Kim   +7 more
wiley   +1 more source

Functionalization of azafullerene C59N. Radical reactions with 9-substituted fluorenes

open access: yes, 2003
An efficient reaction between the azafullerene dimer, (C 59N)2 and 9-substituted fluorenes leads to the formation of four new azafullerene monoadducts.
Michael Orfanopoulos   +1 more
core   +1 more source

Durch einen stabilisierten Intermediatkomplex vermittelte Friedel‐Crafts‐Alkylierung auf Oberflächen

open access: yesAngewandte Chemie, EarlyView.
Einblicke in eine Csp3${\rm C}_{sp^{3}}$‐Csp2${\rm C}_{sp^{2}}$‐Kupplung an Edelmetalloberflächen werden anhand einer oberflächenvermittelten Friedel‐Crafts‐Alkylierung auf Ag(111) gegeben. STM, XPS und DFT‐Rechnungen klären den Reaktionsmechanismus auf Einzelmolekülebene und die Stabilisierung des zentralen Intermediats auf.
Paul Schweer   +5 more
wiley   +1 more source

Fluorenes and Styrenes by Au(I)-Catalyzed Annulation of Enynes and Alkynes

open access: yes, 2016
Intermolecular annulation of enynes and propargyl esters to selectively produce styrenes or fluorenes is reported. The divergent arene syntheses involve a Au-catalyzed, two-pot, multistep process proceeding by cis-diastereoselective cyclopropanation ...
David J. Gorin (1266720)   +2 more
core   +1 more source

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