Results 41 to 50 of about 4,019 (241)
Donor strength governs the excited‐state character and TADF behavior of donor‐acceptor‐donor borondifluoride curcuminoid derivatives. Increasing donor strength drives a transition from charge‐transfer TADF to a zwitterionic polymethine structure with predominantly local excited‐state emission and suppressed TADF.
Anthony D'Aléo +13 more
wiley +1 more source
The dynamic disulfide bonds facilitated the development of high‐performance aerospace ablation‐resistant materials. At moderate temperature, the dissociation and recombination of disulfide bonds ensured excellent processability, mechanical properties, and recycling ability of phenolic resin; at high temperature, cleavage of disulfide bonds produced ...
Yu Li +9 more
wiley +1 more source
In this review, the classification and development history of the volatile solid and solvent additives are comprehensively summarized, the underlying mechanisms of morphology optimization are discussed, and a summary of volatile additive‐induced improvements in interfacial layer performance is provided.
Jianqiang Qin +7 more
wiley +1 more source
Dihydrobenzo[a]fluorene derivatives have been prepared by a formal intramolecular [3 + 3] cycloaddition of o-alkynylstyrenes bearing a secondary alkyl group at the β-position of the styrene moiety.
Roberto Sanz (1508221) +4 more
core +1 more source
This work employs a hybrid hole transport layer to enhance hole transport efficiency, resulting in improved performance for the final device. It achieves an external quantum efficiency of 6.68%, a circularly polarized electroluminescence asymmetry factor of 0.026, and a high luminance of 14,370 cd/cm2, representing the highest luminance reported to ...
Fengqi Qiu +8 more
wiley +1 more source
Photochemical Radical Bicyclization of 1,5-Enynes: Divergent Synthesis of Fluorenes and Azepinones. [PDF]
A dual nickel- and iridium-photocatalyzed radical cascade bicyclization reaction for the synthesis of highly complex molecular structures in an atom- and step-economic manner has been described.
Gore BS, Chen CC, Lin PY, Wang JJ.
europepmc +2 more sources
Direct seawater electrolysis using anion exchange membranes is emerging as a promising route for sustainable hydrogen production. This review summarizes multiscale design strategies from seawater chemistry and OER–ClER selectivity to catalysts, membranes, MEAs, cells, stacks, and system integration, providing a roadmap toward selective, durable, and ...
Chiho Kim +7 more
wiley +1 more source
Functionalization of azafullerene C59N. Radical reactions with 9-substituted fluorenes
An efficient reaction between the azafullerene dimer, (C 59N)2 and 9-substituted fluorenes leads to the formation of four new azafullerene monoadducts.
Michael Orfanopoulos +1 more
core +1 more source
Durch einen stabilisierten Intermediatkomplex vermittelte Friedel‐Crafts‐Alkylierung auf Oberflächen
Einblicke in eine Csp3${\rm C}_{sp^{3}}$‐Csp2${\rm C}_{sp^{2}}$‐Kupplung an Edelmetalloberflächen werden anhand einer oberflächenvermittelten Friedel‐Crafts‐Alkylierung auf Ag(111) gegeben. STM, XPS und DFT‐Rechnungen klären den Reaktionsmechanismus auf Einzelmolekülebene und die Stabilisierung des zentralen Intermediats auf.
Paul Schweer +5 more
wiley +1 more source
Fluorenes and Styrenes by Au(I)-Catalyzed Annulation of Enynes and Alkynes
Intermolecular annulation of enynes and propargyl esters to selectively produce styrenes or fluorenes is reported. The divergent arene syntheses involve a Au-catalyzed, two-pot, multistep process proceeding by cis-diastereoselective cyclopropanation ...
David J. Gorin (1266720) +2 more
core +1 more source

