Results 61 to 70 of about 19,687 (245)

Atom Swapping Reaction on Diborylcarbenoid: Synthesis and Electronic Structure of Inorganic Chalcogenophene Analogues

Chemistry – A European Journal, EarlyView.
ABSTRACT Inorganic analogues of aromatic compounds, wherein C═C bonds are replaced with B─N bonds, are isoelectronic with the original aromatic compounds, however, they can show different properties. While borazine, an inorganic analogue of benzene, has been well‐studied, inorganic analogues of chalcogenophene have been less explored.
Yuki Shibutani, Momoko Inaoka, Shuhei Kusumoto, Kyoko Nozaki   +3 more
wiley   +1 more source

Geochemical characteristics and significance of aromatic hydrocarbons in the Upper Carboniferous mud shales from the Ermahu Sag, Wuwei Basin

Open Geosciences
The Carboniferous is a potential oil-bearing layer in Wuwei Basin, west China. The research on the related parameters of source rocks is relatively weak, which directly restricts the oil-gas exploration in the basin.
Liu Hongjun, Ma Kun, Ma Ge, Lin Yanhua, Zhang Yunbo   +4 more
doaj   +1 more source

One‐Shot Pd(II)‐Catalyzed Multiple C–H Activation Enables Modular Construction of Fluorenylidene Oxindole‐Based Multi(Polycyclic) Aromatic Enes

Chemistry – A European Journal, EarlyView.
A one‐shot Pd(II)‐catalyzed C─H activation strategy enables the rapid conversion of simple linear propiolamides into structurally diverse mono‐, di‐, and tri‐olefin‐bridged MPAEs. This cascade process orchestrates up to six sequential C–H activations in a single operation, providing streamlined access to highly conjugated architectures.
Haiyu Wang, Kouki Sakata, Takuma Sato, Masahiro Terada, Tienan Jin   +4 more
wiley   +1 more source

Lysosome‐Targeted Squaramide Anion Transporters

Chemistry – A European Journal, EarlyView.
Lysosome‐targeted squaramide anion transporters elicit different biological effects depending on the targeting group employed. ABSTRACT Targeting anion transporters to specific organelles has previously been shown to be an effective strategy to enhance their cytotoxicities against cancerous cell lines.
Elba Feo, Edward York, Anthony Thai, William G. Ryder, Daniel A. McNaughton, Philip A. Gale   +5 more
wiley   +1 more source

Thermally Activated Delayed Fluorescence: An Extended Study of Peripherally Substituted DMAC‐TRZ Analogues

Chemistry – A European Journal, EarlyView.
A comprehensive experimental and theoretical study is presented of a family of TADF dyes. Comparing the behavior of structurally related dyes, we uncover the subtle and somewhat unexpected role of conformational degrees of freedom associated with peripheral groups that affect the delicate interplay of excited states that governs spin–orbit coupling ...
Andrea Landi, Ottavia Racchi, D. K. Andrea Phan Huu, Shohei Fukushima, Katsuaki Suzuki, Hironori Kaji, Cristina Sissa, Anna Painelli   +7 more
wiley   +1 more source

β‐Ketonitrile‐Modified Prodan Derivatives as Large‐Stokes‐Shift Solvatochromic Fluorophores With Enhanced Brightness and Ratiometric Thermometric Response

Chemistry – A European Journal, EarlyView.
We report a systematic study of β‐ketonitrile–modified Prodan‐type solvatochromic fluorophores. The β‐ketonitrile substitution induces marked bathochromic shifts in absorption and emission and significantly enhances fluorescence quantum yields in nonpolar solvents.
Hiroaki Asakawa, Takuya Tanaka, Kensei Konishi, Gen‐ichi Konishi   +3 more
wiley   +1 more source

Machine Learning–Enhanced Fluorescence Cryptography with NADH‐Responsive Polymer Dots

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This study presents a smart anticounterfeiting system using semiconducting polymer dots (Pdots) that exhibit tunable fluorescence responses to NADH. By integrating these dynamic optical signals with machine learning–based decoding, the work establishes a secure and intelligent encryption platform, showing a novel strategy that links chemical sensing ...
Zhengkun Zhan, Mingyue Gong, Zirui Zeng, Hangyu Liu, Xiaoliang Li, Zhuxin Dong, Xiaoju Men, Haobin Chen   +7 more
wiley   +1 more source

Modular π‐Extended IF‐TTF Systems: Tuning Redox and Optical Properties in Donor–Acceptor and Donor–Donor Frameworks

European Journal of Organic Chemistry, EarlyView.
Donor–acceptor and donor–donor systems incorporating an indeno[1,2‐b]fluorene‐extended tetrathiafulvalene (IF‐TTF) donor motif were prepared by Suzuki coupling reactions. The compounds were studied for their optical and redox properties. The compounds showed multiredox behavior with several accessible redox states. A series of π‐extended donor–acceptor
Cecilie Rindom, Mogens Brøndsted Nielsen   +1 more
wiley   +1 more source

Competing Charge Transport Pathways: A Spirobifluorene‐Based Molecular Loop

European Journal of Organic Chemistry, EarlyView.
A rigid molecular loop integrating a spirobifluorene (SBF) core with a cycloparaphenylene (CPP) moiety provides two distinct transport channels. Through‐space spiroconjugation and radial π‐conjugation along a CPP backbone coexist within a single molecule.
Brian Ogi, Riccardo Conte, Salome L. Heim, Herre S. J. van der Zant, Marcel Mayor   +4 more
wiley   +1 more source

Spirobifluorene fusion in multiple resonance frameworks enables efficient pure‐red OLEDs with narrowband emission and suppressed efficiency roll‐off

FlexMat, EarlyView.
An orthogonal spirobifluorene‐fusion strategy is introduced for B/N/O‐alternated MR frameworks, enabling improved kRISC (5.46 × 103 s−1), high ΦPL (97%), and narrow‐band pure‐red emission. Vacuum‐evaporated OLEDs incorporating this emitter achieve an EQEmax >40% (FWHM = 36 nm) and exhibit exceptionally low efficiency roll‐off at high luminance ...
Yan‐Yun Jing, Han Wu, Xiaoling Xu, Sijie Xian, Jingsheng Miao, Xiaojun Yin, Chuluo Yang, Xiaosong Cao   +7 more
wiley   +1 more source