Synthesis of Thioxanthone 10,10-Dioxides and Sulfone-Fluoresceins via Pd-Catalyzed Sulfonylative Homocoupling. [PDF]
Org LettOur report describes the facile and scalable preparation of 9H-thioxanthen-9-one 10,10-dioxides via Pd-catalyzed sulfonylative homocoupling of the appropriately substituted benzophenones. This transformation provides a straightforward route to previously
Knorr G +3 more
europepmc +2 more sources
Synthesis of Rhodamines from Fluoresceins Using Pd-Catalyzed C–N Cross-Coupling [PDF]
Organic Letters, 2011 A unified, convenient, and efficient strategy for the preparation of rhodamines and N,N′-diacylated rhodamines has been developed. Fluorescein ditriflates were found to undergo palladium-catalyzed C–N cross-coupling with amines, amides, carbamates, and ...
J. Grimm, L. Lavis
semanticscholar +3 more sources
Cell-trappable quinoline-derivatized fluoresceins for selective and reversible biological Zn(II) detection. [PDF]
Inorganic Chemistry, 2010 The synthesis and spectroscopic characterization of two new, cell-trappable fluorescent probes for Zn(II) are presented. These probes, 2-(4,5-bis(((6-(2-ethoxy-2-oxoethoxy)quinolin-8-yl)amino)methyl)-6-hydroxy-3-oxo-3H-8 xanthen-9-yl)benzoic acid (QZ2E ...
Lindsey E. McQuade, S. Lippard
semanticscholar +3 more sources
Balanced Intersystem Crossing in Iodinated Silicon-Fluoresceins Allows New Class of Red Shifted Theranostic Agents [PDF]
, 2021 © 2021 The Authors. Published by American Chemical Society.Iodination of the silicon-fluorescein core revealed a new class of highly cytotoxic, red-shifted and water-soluble photosensitizer (SF-I) which is also fairly emissive to serve as a theranostic ...
Cetin, Sultan +5 more
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Red-Emitting Tetracoordinate Organoboron Chelates: Synthesis, Photophysical Properties, and Fluorescence Microscopy [PDF]
, 2016 Seven tetracoordinate organoboron fluorophores with heterobiaryl N,O- or N,N-chelate ligands were prepared and photophysically characterized (in toluene).
Collado, Daniel +9 more
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Mechanically switchable polymer fibers for sensing in biological conditions [PDF]
, 2016 The area of in vivo sensing using optical fibers commonly uses materials such as silica and polymethyl methacrylate, both of which possess much higher modulus than human tissue. The mechanical mismatch between materials and living tissue has been seen to
Foster, E. Johan +4 more
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General Synthetic Method for Si-Fluoresceins and Si-Rhodamines
ACS Central Science, 2017 The century-old fluoresceins and rhodamines persist as flexible scaffolds for fluorescent and fluorogenic compounds. Extensive exploration of these xanthene dyes has yielded general structure–activity relationships where the development of new probes is ...
J. Grimm +3 more
semanticscholar +1 more source
Advanced optical imaging in living embryos [PDF]
, 2010 Developmental biology investigations have evolved from static studies of embryo anatomy and into dynamic studies of the genetic and cellular mechanisms responsible for shaping the embryo anatomy.
A Aman +90 more
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Protective roles of ascorbic acid in oxidative stress induced by depletion of superoxide dismutase in vertebrate cells. [PDF]
, 2013 Superoxide dismutases (SODs) are antioxidant proteins that convert superoxide to hydrogen peroxide. In vertebrate cells, SOD1 is mainly present in the cytoplasm, with small levels also found in the nucleus and mitochondrial intermembrane space, and SOD2 ...
Enomoto, Takemi +9 more
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