Results 211 to 220 of about 97,501 (249)

Recent Advances in Variable‐Stiffness Robotic Systems Enabled by Phase‐Change Materials

open access: yesAdvanced Robotics Research, EarlyView.
Phase‐change materials (PCMs), such as shape memory alloys, hydrogels, shape memory polymers, liquid crystal elastomers, and low‐melting‐point alloys, are driving advancements in stiffness‐tunable robotic systems across a wide range of applications. This review highlights recent progress in PCM‐enabled robotics, focusing on their underlying mechanisms,
Sukrit Gaira   +5 more
wiley   +1 more source

Dual Lewis Acid Promoted/Visible Light Driven Preparation of Aryl Diazenyl Oxazoles from Isocyanoacetamides and Arylazo Sulfones

open access: yesAdvanced Synthesis &Catalysis, Volume 367, Issue 5, March 4, 2025.
Abstract While arylazo sulfones have been widely applied as arylating agents, their exploitation for diazenylation reactions has been previously limited to electron‐rich alkenes such as styrenes and silyl enol ethers. Herein we optimized a synthetic one‐pot protocol to access oxazolyl azo compounds via a selective domino ring‐closing/aryldiazenylation ...
Enzo Delalande   +5 more
wiley   +1 more source

Chemoselective Synthesis of α‐Chloro and α,α‐Dichloro Acetamidines via the Carbenoids Addition to Inherently Low Electrophilic Carbodiimides

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Carbodiimides act as competent electrophilic synthons for the chemoselective addition of lithium mono‐ and di‐halocarbenoids. The transformation is provided through a single synthetic operation—hitherto elusive—halogenated acetamidines. Interestingly, the constitutively tamed electrophilicity of the starting materials is effectively counterbalanced by ...
Davide Castiglione   +4 more
wiley   +1 more source

Gold‐Catalyzed Synthesis of Fluorenones via Intramolecular C–H Arylation

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Starting from 2‐diazobenzophenones, a straightforward synthesis of valuable fluorenones via a gold‐catalyzed one‐pot oxidation, C–H activation, and cyclization is described. The addition of ascorbic acid, the correct selection of the counteranion of the 2‐diazobenzophenones, and the use of terpyridine as an auxiliary ligand are crucial for the reaction
Osvaldo Felipe López‐Saladino   +5 more
wiley   +1 more source

Home - About - Disclaimer - Privacy