Results 191 to 200 of about 65,330 (266)

Molecular Design Strategies for High‐Voltage Organic Cathodes

open access: yesAdvanced Energy Materials, EarlyView.
This work proposes molecular engineering strategies for high‐voltage organic cathode materials for Li‐ion batteries: (1) increase Li‐O coordination number (CN), (2) achieve a greater increase in aromaticity upon reduction (∆Aromaticity), and (3) add an electron‐withdrawing group (EWG), through a combined experimental and computational study on reported
Sungil Hong   +8 more
wiley   +1 more source

Accelerated Formation of CsPbI3 through Controlled Amidation of Intermediate Phases

open access: yesAdvanced Energy Materials, EarlyView.
This study presents a reaction‐guided crystallization strategy for phase‐pure CsPbI3 thin films. In this strategy, the additive 2,2,2‐trifluoroethyl trifluoroacetate (TFTF) undergoes a rapid ester‐amine amidation reaction with dimethylammonium iodide (DMAI), converting both species into highly volatile byproducts that are eliminated during annealing ...
Yitian Du   +12 more
wiley   +1 more source

Deoxyradiofluorination of Phenols via a Difluoromethoxy Nucleofuge Enabled by Organic Photoredox Catalysis. [PDF]

open access: yesACS Cent Sci
Mungalpara MN   +12 more
europepmc   +1 more source

Linking DSC/TGA to Cell Levels: Energetics, Evolved Gases, and Thermal Safety of NMC811‐Graphite Micro‐Cell

open access: yesAdvanced Energy Materials, EarlyView.
A bottom‐up, component‐resolved framework combining DSC/TGA, evolved gas analysis, and in situ XRD reveals how decomposition pathways control energy release in partial and micro‐cell configurations. Separator‐free assemblies are dominated by cathode‐O2${\rm O}_2$/anode‐Li reactions, while the separator restricts oxygen transport, reshapes the reaction ...
Ayrton M. Yanyachi   +8 more
wiley   +1 more source

Electrolyte Confinement Enables a Continuous Transition From Battery‐Like to Capacitor‐Like Na+ Storage via Solvent Co‐Intercalation

open access: yesAdvanced Energy Materials, EarlyView.
Layered titanates with expanded interlayer galleries reveal how nanoconfinement and electrolyte solvation control Na+ storage kinetics. In diglyme electrolyte, solvent co‐intercalation and strongly reduced interfacial impedance enable increasingly capacitor‐like behavior with increasing interlayer spacing, whereas carbonate electrolytes form resistive ...
Yoga Trianzar Malik   +11 more
wiley   +1 more source

Tracking Dynamic Sulfur Electrochemistry by Operando Techniques in Alkali Metal‐Sulfur Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Dynamic sulfur electrochemistry in alkali metal‐sulfur batteries is tracked through operando spectroscopy, scattering, imaging, and modelling. This Review connects sulfur reaction pathways, polysulfide transport, electrolyte/interphase evolution, anode chemistry, and quantitative mechanistic analysis across Li‐S, Na‐S, and K‐S batteries, providing ...
Fangli Zhang   +3 more
wiley   +1 more source

Molecular Interfacial Regulators Enable Stable Sulfide Electrolytes for High‐Performance All‐Solid‐State Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Molecular surface regulation enabled by fluoropyridines stabilizes sulfide electrolyte interfaces across both reductive and oxidative regimes. By suppressing interfacial decomposition, the modified LPSClBr enables high‐voltage operation, stable stripping/plating of Li metal, and long‐life full cells with uncoated cathodes.
Laras Fadillah   +9 more
wiley   +1 more source

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