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The microwave spectrum of formamide–water and formamide–methanol complexes
Journal of Chemical Physics, 1988The microwave spectra of the formamide–water and formamide–methanol complexes have been investigated with a pulsed beam Fabry–Perot cavity Fourier transform microwave spectrometer. The observed hyperfine structure due to the 14N nuclear quadrupole interaction was used to assign the rotational transitions for both species.
Gerald Fraser, Fraser G T, Lovas F J
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2021
This thesis was scanned from the print manuscript for digital preservation and is copyright the author. Researchers can access this thesis by asking their local university, institution or public library to make a request on their behalf. Monash staff and postgraduate students can use the link in the References field.
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This thesis was scanned from the print manuscript for digital preservation and is copyright the author. Researchers can access this thesis by asking their local university, institution or public library to make a request on their behalf. Monash staff and postgraduate students can use the link in the References field.
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Pulse Radiolysis of Formamide and Formamide–Water Mixtures
Canadian Journal of Chemistry, 1971From the optical absorption spectrum observed by a sub-nanosecond pulse radiolysis method it is concluded that irradiated pure liquid formamide (dielectric constant = 109) does not yield solvated electrons with lifetimes >10−11 s. In formamide–water mixtures the hydrated electron is formed in low yield and the position of the absorption band of eaq−
D. C. Walker, S. C. Wallace
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Journal of Molecular Spectroscopy, 1987
Abstract A reanalysis of vibration-rotation spectral data of formamide using the semi-rigid-bender technique adopted for unsymmetrical 1 large-amplitude motions (LAM) reveals that formamide has a very shallow single-minimum inversion potential. During inversion the amino group rotates around the CN bond with the syn -hydrogen staying closer to the ...
R.D. Brown, P.D. Godfrey, B. Kleibömer
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Abstract A reanalysis of vibration-rotation spectral data of formamide using the semi-rigid-bender technique adopted for unsymmetrical 1 large-amplitude motions (LAM) reveals that formamide has a very shallow single-minimum inversion potential. During inversion the amino group rotates around the CN bond with the syn -hydrogen staying closer to the ...
R.D. Brown, P.D. Godfrey, B. Kleibömer
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Electric-dipole moments of H2O-formamide and CH3OH-formamide
Journal of Molecular Structure, 1988Abstract Electric-dipole moments have been determined for H 2 O-formamide and CH 3 OH-formamide by pulsed-nozzle Fourier-transform microwave spectroscopy. For H 2 O-formamide μ a =1.050(1) D and μ b =2.135(3) D while for CH 3 OH-formamide μ a =1.066(1) D and μ b =2.091(2) D. The corresponding complexation-induced moments are estimated as 0.55
G.T. Fraser, R.D. Suenram, F.J. Lovas
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International Journal of Quantum Chemistry, 2005
AbstractThe basis set superposition error (BSSE) influence in the geometry structure, interaction energies, and intermolecular harmonic and anharmonic vibrational frequencies of cyclic formamide–formamide and formamide–water dimers have been studied using different basis sets (6‐31G, 6‐31G**, 6‐31++G**, D95V, D95V**, and D95V++**).
A. Bende, S. Suhai
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AbstractThe basis set superposition error (BSSE) influence in the geometry structure, interaction energies, and intermolecular harmonic and anharmonic vibrational frequencies of cyclic formamide–formamide and formamide–water dimers have been studied using different basis sets (6‐31G, 6‐31G**, 6‐31++G**, D95V, D95V**, and D95V++**).
A. Bende, S. Suhai
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Imidazolsynthesen mit Formamid (Formamid‐Reaktionen, I. Mitteil.)
Chemische Berichte, 1953AbstractAus α‐Oxy‐, α‐Halogen‐, α‐Amino‐ und unter reduzierenden Bedingungen auch aus α‐Isonitroso‐ketonen entstehen mit Formamid 4.5‐substituierte Imidazole. Formamid dient im Überschuß gleichzeitig als Lösungsmittel.
Hellmut Bredereck, Gerhard Theilig
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