Results 191 to 200 of about 78,014 (255)

Rhodium‐Catalyzed Synthesis of Enantioenriched α‐Substituted Primary Amines Through Asymmetric Transfer Hydrogenation

Chemistry – A European Journal, EarlyView.
Enantioenriched α‐substituted primary amines are efficiently prepared by rhodium‐catalyzed asymmetric transfer hydrogenation of ortho‐hydroxyaryl N─H imines under mild conditions using a low catalyst loading and ammonium formate as the hydrogen source in high yields (up to 99%) and enantioselectivities (up to 99% ee).
Chonghuo Liu, Guillaume Lefèvre, Qin Yin, Phannarath Phansavath, Virginie Ratovelomanana‐Vidal   +4 more
wiley   +1 more source

An interfacial-intramolecular electron highway for accelerated electrocatalytic CO₂ reduction by an O₂-tolerant formate dehydrogenase. [PDF]

Nat Commun
Liu W, Zhang P, Wang X, Zhang K, Yang W, Cui H, Liu J, Sun J, You C, Cui H, Zhu Z, Zhang L.   +11 more
europepmc   +1 more source

Photoinduced ROS Production by Poly(3‐hexylthiophene) (P3HT) is due to Autoxidation Rather Than Catalysis

Chemistry – A European Journal, EarlyView.
P3HT is widely treated as a photocatalyst that generates ROS under light. We show otherwise: ROS production comes at the expense of the polymer itself. Photoexcited P3HT acts as a self‐sacrificial photosubstrate, undergoing irreversible autoxidation during light‐driven oxygen reduction—a distinction critical for interpreting its behavior in emerging ...
Roman Gańczarczyk, Renata Rybakiewicz‐Sekita, Eric D. Głowacki   +2 more
wiley   +1 more source

A Stable Isopterin Mimic of a Potent Bacterial Stimulant of T Cells

Chemistry – A European Journal, EarlyView.
A microbial metabolite covalently binds immunological protein MR1 to potently activate specific lymphocytes called MAIT cells, but it is too unstable for biological applications. Here, using synthesis, assays, protein crystallography, and computer modelling, we report a water‐stable analogue that activates reporter cells expressing the MAIT T cell ...
Jeffrey Y. W. Mak, Huy N. Hoang, Wael Awad, Xin Yi Lim, Damica D. Laurie, Ryan J. D. Rivero, James McCluskey, Alexandra J. Corbett, Jamie Rossjohn, David P. Fairlie   +9 more
wiley   +1 more source

Synergistic Effects of Mesoporous Structure and Oxygen Vacancies in SnO₂ for Enhanced CO₂ Electroreduction. [PDF]

Small Sci
Zhao Y, Huang S, Yan Y, Boyd R, Liu Z, Fahlman M, Vagin M, Odén M, Björk EM.   +8 more
europepmc   +1 more source

Protocol for untargeted lipidomics of human serum using LC-TIMS-PASEF. [PDF]

STAR Protoc
Monteiro FS, Buzatto AZ.
europepmc   +1 more source

Sulfur vacancy-confined Co-Mo sites in MoS₂ for high-efficiency CO₂ hydrogenation to formate. [PDF]

Nat Commun
Wang Z, Kang Y, Chen G, Ji Q, Zhang Y, Qi Y, Zhu J, Zhou W, Huang R, Hu J, Yu L, Tian ZQ, Deng D.   +12 more
europepmc   +1 more source

Bridging-patching <i>c</i>-pores with tetrafluorosuccinate in a <i>csq</i>-type mesoporous Zr-MOF with different crystal dimensions: cycling stability and adsorption kinetics for in-door humidity control. [PDF]

Chem Sci
Lin H, Lin H, Zhang M, Jiang Y, Liu Y, Du L, Lu Z.   +6 more
europepmc   +1 more source

Determination and Validation of Standard Enthalpies of Formation and Sublimation of Potassium Salts Using Solution Calorimetry and Quantum-Chemical Calculations. [PDF]

ChemistryOpen
Amanollahi Z, Zaitsau DH, Müller K, Bokareva OS, Siewert R.   +4 more
europepmc   +1 more source

Electrocatalytic CO₂ Reduction Coupled to Formate Fermentation: An Electro-Bio Cascade Approach in Biocompatible Electrolytes. [PDF]

Chemistry
Vieira L, Fabarius JT, Piton GR, Bohlen B, Pangotra D, Speck M, Sagstetter C, Sieber V, Roth A.   +8 more
europepmc   +1 more source