Results 81 to 90 of about 78,014 (255)
Operando Raman Spectroscopy Reveals Backpressure‐Controlled Dynamics in Diluted CO2 Electrolysis
Advanced Science, EarlyView.High backpressure operation governs the CO2 reduction reaction (eCO2RR) kinetics and selectivity, as well as the CO2 and water dynamics, as revealed through operando Raman spectroelectrochemical measurement. Operating eCO2RR near diffusion‐limited conditions provides a platform for investigating the competition between eCO2RR and the hydrogen evolution
Muhammad Adib Abdillah Mahbub +7 more
wiley +1 more source
Advanced Science, EarlyView.A new data‐efficient framework combining DFT calculations, a neural network model, and automated graph analysis of catalytic reaction networks is proposed and applied to CO2 hydrogenation on transition metal nanoparticles. The analysis shows how efficient C2 oxygenate production requires a balance between CHx formation, C–C coupling, protonation, and ...
Mikhail V. Polynski, Sergey M. Kozlov
wiley +1 more source
Modulating Activity through Defect Engineering of Tin Oxides for Electrochemical CO2 Reduction
Advanced Science, 2019 The large‐scale application of electrochemical reduction of CO2, as a viable strategy to mitigate the effects of anthropogenic climate change, is hindered by the lack of active and cost‐effective electrocatalysts that can be generated in bulk.
Rahman Daiyan +9 more
doaj +1 more source
Allosteric Inhibition of Polycomb Repressive Complex 2 by an EZH2‐Selective Small Molecule Inhibitor
Advanced Science, EarlyView.The study characterizes C36, a highly selective EZH2/PRC2 inhibitor that acts via a novel allosteric mechanism. Unlike previous inhibitors, C36 inhibits EZH2/PRC2 by disrupting the allosteric communication between EZH2 and EED in a SAM‐noncompetitive manner.
Ting Cao +11 more
wiley +1 more source
Small StructuresThe electrochemical reduction of CO2 faces challenges and increased costs owing to the short lifetime of its gas diffusion electrodes (GDEs). Bi‐based GDEs appear promising for converting CO2 to formate, achieving high current density and Faradaic ...
Yakov Shitrit +9 more
doaj +1 more source
Adaptive Coordination Engineering for Efficient and Robust H2 Release
Advanced Science, EarlyView.β‐H elimination is a pivotal but challenging step in homogeneous formic acid dehydrogenation reactions due to strict hydride‐metal matching. By using a rationally designed Pd1Ag2 bimetallic system with adaptive Pd1‐Ag2/L2 coordination and formate bridges, it enables boosted formic acid dehydrogenation under ambient air (7.7 times higher than a Pd ...
Xiaolin Jiang +8 more
wiley +1 more source
Advanced Science, EarlyView.Early life adversity triggers persistent social subordination and brain‐wide molecular dysregulation. Pharmacological inhibition of the stress‐mediator FKBP51 during the adversity period prevents these long‐term deficits and restores normative social hierarchy.
Joeri Bordes +15 more
wiley +1 more source
Dialogues in Clinical Neuroscience, 2016 Habits, both good ones and bad ones, are pervasive in animal behavior. Important frameworks have been developed to understand habits through psychological and neurobiological studies. This work has given us a rich understanding of brain networks that promote habits, and has also helped us to understand what constitutes a habitual behavior as opposed to
Smith, Kyle S., Graybiel, Ann M
openaire +4 more sources
Advanced Science, EarlyView.This study uncovers a metabolic‐epigenetic axis licensing zygotic genome activation (ZGA) in mouse embryos. A developmental decline in NAD+ levels activates PARP7, which mono‐ADP‐ribosylates and stabilizes UHRF1. This modification promotes the establishment of permissive histone acetylation marks, thereby facilitating timely ZGA.
Guangyi Cao +13 more
wiley +1 more source