Results 221 to 230 of about 244,082 (296)

[Evidence generation and methodological consultation by the project "EVAluation research based on data from routine clinical care 4 the Medical Informatics Initiative" (EVA4MII)]. [PDF]

Bundesgesundheitsblatt Gesundheitsforschung Gesundheitsschutz
Pfaffenlehner M, Kesselmeier M, Günther K, Ungethüm K, Rücker V, Remo F, Binder H, Scherag A, Heuschmann P, Binder N, EVA4MII-Projekt.   +10 more
europepmc   +1 more source

Coordination‐Driven Direct C─H Metalation of N‐Heterocycles With a Superbasic Co(II) Amide Co(TMP)2

Angewandte Chemie, EarlyView.
By enabling regioselectivities that are inaccessible with conventional bases, this study introduces a Co(II) amide platform for the deprotonative C─H metalation of sensitive N‐heterocycles. Subsequent interception of the resulting Co(II) intermediates with external oxidants affords a family of sterically congested, TMP‐substituted heterocycles via C─N ...
Na Jin, Manting Mu, Max García‐Melchor, Eva Hevia   +3 more
wiley   +1 more source

Pyrene-Conjugated, 2-Pyridinecarboxaldehyde Derivatives as N-Terminus-Specific Tags for MALDI- and LALDI-MS. [PDF]

Rapid Commun Mass Spectrom
Li MJ, Kucukdisli M, Braun F, Will DW, Meier N, Wehrle B, Meyer LC, Föll MC, Schilling O.   +8 more
europepmc   +1 more source

Unlocking a Nitrosuccinate Lyase for Decarboxylative Enzymatic Hydronitration

Angewandte Chemie, EarlyView.
The nitrosuccinate lyase CreD catalyzes C–NO2 bond formation using nitrite in water and shows synthetic practicality with high turnover numbers up to 102,000. A combination of protein engineering and computational methods helped to reveal the mechanistic principles that underpin this unique enzymatic activity.
Matteo Aleotti, Hannah Dreisbach, Rémi Corlay, Clara Weber, Tamara Reiter, Wael Elaily, Bastian Daniel, Klaus Zangger, Pedro A. Sánchez‐Murcia, Mélanie Hall   +9 more
wiley   +1 more source

Fusion Molecules Between the STAT5b Inhibitor Stafib-2-CR and a Cereblon Ligand. [PDF]

ChemistryOpen
Münzel T, Seidenstücker KC, Protzel C, Berg A, Berg T.   +4 more
europepmc   +1 more source

Räumliche Entwicklung von Koks in ZSM‐5‐Katalysatoren während der Umwandlung von Methanol in Kohlenwasserstoffe, aufgezeigt durch in‐situ‐Röntgen‐Photoelektronenspektroskopie

Angewandte Chemie, EarlyView.
Oberfläche enthüllt: Verkokung ist die zentrale Ursache für die Deaktivierung von Zeolithkatalysatoren. Mithilfe von In‐situ‐XPS in Verbindung mit ergänzenden Methoden identifizieren wir Unterschiede in der Bildungskinetik und Zusammensetzung von Oberflächenkoks auf industriell relevanten ZSM‐5‐Katalysatoren während der MTH‐Umwandlung und zeigen damit ...
Luca Artiglia, Hannes Frey, Loïc Bénariac‐Doumal, Sung Sik Lee, Przemyslaw Rzepka, Jeroen A. van Bokhoven, Vladimir Paunović   +6 more
wiley   +1 more source

Ventricular Fibrillation Without Hemodynamic Deterioration: An Electrocardiographic Paradox Explained by Heterotopic Heart Transplantation. [PDF]

JACC Case Rep
Zernikow J, Hintz I, Spethmann S, Gröschel J, Dagres N, Schoenrath F, Hindricks G, Knosalla C, Koehler F, Haverkamp W.   +9 more
europepmc   +1 more source

Kooperative Redox‐Katalyse der N2O‐Zersetzung mittels auf Co3O4 geträgerten RhOx‐ und CeOx‐Spezies mit kurzreichweitiger Wechselwirkung

Angewandte Chemie, EarlyView.
A short‐range Rh‐O‐Co‐O‐Ce interfacial moiety drives low‐temperature N2O decomposition via a cooperative redox cycle. Operando modulated‐excitation XAS with phase‐sensitive detection (ME‐XAS+PSD) tracks rapid, reversible Rh oxidation coupled to Co reduction. Combined kinetics and DFT rationalize the activity trends and identify the Rh‐O‐Co interface as
Daniel C. Cano‐Blanco, Silvio Bellomi, Daniele Bonavia, Ivo Alxneit, Kirill A. Lomachenko, Karin Föttinger, Oliver Kröcher, Davide Ferri   +7 more
wiley   +1 more source

The Quantum Optimization Benchmarking Library. [PDF]

Nat Comput Sci
Koch T, Bernal Neira DE, Chen Y, Cortiana G, Egger DJ, Heese R, Hegade NN, Gomez Cadavid A, Huang R, Itoko T, Kleinert T, Maciel Xavier P, Mohseni N, Montanez-Barrera JA, Nakano K, Nannicini G, O'Meara C, Pauckert J, Proissl M, Ramesh A, Schicker M, Shimada N, Takeori M, Valls V, Van Bulck D, Woerner S, Zoufal C.   +26 more
europepmc   +1 more source

The Role of Zn–Hf Site Proximity and Oxygen Vacancies for Methanol Formation Over ZnHfOx Catalysts Under CO2 Hydrogenation Conditions

Angewandte Chemie, EarlyView.
ZnHfOx catalysts enable highly selective hydrogenation of CO2 to methanol over a wide range of Zn contents, as the Zn‐VO‐Hf active motif (VO = oxygen vacancy) exists not only in solid solution‐type ZnHfOx for low Zn contents (≤ 35 mol%), but also as HfOx cluster/single atom decorated ZnO surfaces for Zn contents > 95 mol%.
Alexander Oing, Diana Piankova, Jean C. Villa‐Arpi, Muhammad Helmi Risansyauqi, Hector Prats, Felix Donat, Paula M. Abdala, Aleix Comas‐Vives, Christoph R. Müller   +8 more
wiley   +1 more source