Results 91 to 100 of about 94,466 (209)

Measuring Local Exothermic Effects During the Oxidative Coupling of Methane Using Operando Luminescence Thermometry

open access: yesAngewandte Chemie, EarlyView.
Operando luminescence thermometry shows that the local catalyst temperature can exceed the set oven temperature by almost 250°C during the exothermic oxidative coupling of methane process. We demonstrate how the reactor dimensions, catalyst grain size, and reactant feed mixture affect the local temperature.
Daniël W. Groefsema   +5 more
wiley   +2 more sources

Uncovering renewable energy policy impact channels on land values, the local farm structure, and farmland heterogeneity

open access: yesAmerican Journal of Agricultural Economics, EarlyView.
Abstract Germany's Renewable Energy Sources Act (REA), enacted in 2000 and subsequently amended, subsidized national renewable energy production with fixed feed‐in tariffs for renewable energy sources (RE) from wind, solar, and biogas. Empirical studies suggest that the policy was creating windfall effects for landowners and attribute farmland use ...
Lars Isenhardt   +6 more
wiley   +1 more source

Ketal Protection of Glycerol for Selective Electrosynthesis of Glyceric Acid in Highly Alkaline Media

open access: yesAngewandte Chemie, EarlyView.
Using a ketal‐protected glycerol derivative (solketal) as the oxidation substrate enables site‐selective electrooxidation that suppresses C–C cleavage on non‐noble catalysts. Highly alkaline conditions promote reactive solketal alkoxide formation, weaken the Cα─H bond to facilitate dehydrogenation, and buffer local acidification, enabling a record‐high
Jiamin Wang   +6 more
wiley   +2 more sources

Taxonomic reassessment of fossil Sequoia and Protosequoia from the Upper Miocene of Central Honshu, Japan, with implications for leaf morphological variation in extant S. sempervirens

open access: yesAmerican Journal of Botany, EarlyView.
Abstract Premise Since its emergence in the Mesozoic, Sequoia (Cupressaceae) has been considered to possess conserved leaf morphology. However, recent studies have shown that the leaves of extant S. sempervirens become smaller, with a scale form, with increasing tree height.
Shun Ikeda, Arata Momohara
wiley   +1 more source

Enhanced Formation of Dicarboxylic Acids in the Catalytic Oxidation of Polyethylene With O2 and NOx

open access: yesAngewandte Chemie, EarlyView.
The oxidation of polyethylene in the presence of a mixture of O2 and NOx and with Cu2+/V5+ as catalyst yields ∼51 mol% diacids, while retaining ∼80 mol% of the carbon in the oil fraction. The developed method is robust and tolerates several polymer types as well as impurities.
Tom J. Smak   +3 more
wiley   +2 more sources

New records of extinct Icacinaceae from Paleocene rainforests of northwestern South America

open access: yesAmerican Journal of Botany, EarlyView.
Abstract Premise This study describes three new records of Icacinaceae—Punctiuga bachue gen. et sp. nov., Palaeophytocrene paramoae sp. nov., and Goweria bacatana sp. nov. from the Paleocene (Selandian–Thanetian) Bogotá Formation in Colombia—improving understanding of the distribution and evolution of this family in the Neotropics.
Laura M. Puente‐Santos   +3 more
wiley   +1 more source

Inverse Vulcanization Through Epoxide Chemistry: A Low Temperature Non‐Olefin Route to Sulfur‐Rich Polymer Networks

open access: yesAngewandte Chemie, EarlyView.
Epoxide monomers undergo base‐catalyzed ring‐opening copolymerization with elemental sulfur to afford sulfur‐rich polymers under mild conditions. The resulting materials exhibit excellent mechanical performance, strong adhesion (up to 10 MPa on stainless steel), and outstanding reprocessability.
Pan Yang   +5 more
wiley   +2 more sources

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