Results 171 to 180 of about 17,263 (255)

Unveiling the role of local temperature gradients in individual zeolites containing metal active sites. [PDF]

open access: yesChem Sci
Zhao B   +10 more
europepmc   +1 more source

Polypyridyl Coordination Motifs as Precursors for Ordered Carbonaceous Frameworks Toward High‐Density Ru Single‐Atom Catalysts

open access: yesAngewandte Chemie, EarlyView.
Here, we introduce a molecular design principle that fundamentally expands the bottom‐up synthesis of single‐atom catalysts (SACs). Coordinatively flexible polypyridyl units enable bottom‐up formation of ordered carbonaceous frameworks containing atomically dispersed Ru (∼11 wt%) by simple carbonization.
Koki Chida   +13 more
wiley   +1 more source

Epitaxial Oxide Interfaces Create Poison‐Resistant CuO Sites for Environmental Catalysis

open access: yesAngewandte Chemie, EarlyView.
An epitaxially stabilized CuO overlayer on Ti1−xInxO2 creates electron‐poor, high‐symmetry Cu–O sites that activate interfacial lattice‐oxygen redox. This interface promotes NOx reduction through an Eley–Rideal pathway, diverts sulfate formation, and sustains CH3SH deep oxidation via a Mars–van Krevelen cycle, offering a route to poison‐resistant ...
Lupeng Han   +14 more
wiley   +1 more source

Axial Boron Coordination Reconstructs Stereostructure of Cu Single‐Atom Nanozymes for Efficient Water‐Phase Chemical Sensing

open access: yesAngewandte Chemie, EarlyView.
Sun et al. proposed an axial boron coordination strategy to reconstruct the stereostructure of Cu SAzymes and enable them to serve as efficient laccase mimics for high‐throughput smart sensor array detection of phenolic pollutants in water phases. ABSTRACT Developing single‐atom nanozymes with stereoconfigurations is a new paradigm for biomimetic ...
Qijun Sun   +8 more
wiley   +1 more source

In Situ Converted High-Loading Membranes With Molecularly Dispersed Porous Organic Cages for Superior CO<sub>2</sub>/N<sub>2</sub> Separation. [PDF]

open access: yesAngew Chem Int Ed Engl
Yu L   +14 more
europepmc   +1 more source

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