CuH‐Catalyzed Asymmetric Desymmetrization of Cyclobutenes via Stereodivergent Hydroamination
The CuH‐catalyzed stereodivergent hydroamination through asymmetric desymmetrization of cyclobutenes has been achieved, yielding a range of trisubstituted aminocyclobutanes with excellent results. A series of subsequent transformations, including the first asymmetric synthesis of two pharmaceutically active molecules, have been realized, and density ...
Xiang Lei +8 more
wiley +1 more source
Green mycosynthesis of ZnO nanoparticles enhances antifungal defense against Fusarium equiseti through metabolic and gene expression modulation. [PDF]
El-Morsy EM, Elmalahy YS, Hafez EE.
europepmc +1 more source
Compatibility of Trichoderma asperellum with some selected fungicides, insecticides and weedicides [PDF]
Bharat G Karhade +6 more
openalex +1 more source
The convergent total synthesis of a candidate diastereomer of amphirionin‐5 was accomplished in 22 steps via the coupling of the C1‐C16 enone segment and the C17‐C28 aldehyde segment using Stetter reaction. The overall stereochemistry of amphirionin‐5 was fully assigned, based on the comparison of spectroscopic and chiroptical data between the ...
Yusuke Ogura +7 more
wiley +1 more source
A two-tiered methodology for the validation of promising plant growth promoting bacteria isolated from durum wheat rhizosphere. [PDF]
d'Amelio A +8 more
europepmc +1 more source
A one‐pot protocol to synthesize reactive benzyl‐ and allyl‐halide‐substituted (dihydro)naphthalenes from 2,3‐aryl‐1,3‐butadiene substrates and halogenated alkanes has been developed, using [Cp*RuCl(PPh3)2] as the catalyst. Mechanistic studies revealed an atom transfer radical addition and radical benzannulation sequence, followed by HCl elimination ...
Nicole S. van Leeuwen +9 more
wiley +1 more source
Exploring the potential of synthetic and biological fungicides for managing the fungus-farming ambrosia beetle Xylosandrus compactus. [PDF]
Costanzo MB +4 more
europepmc +1 more source
Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome +6 more
wiley +1 more source
Compatibility of Brazilian Strains of <i>Trichoderma afroharzianum</i> with Various Agricultural Inputs Under In Vitro Conditions. [PDF]
Marques E +6 more
europepmc +1 more source
Conversion of emestrin J (5) to emestrin (1) by three P450 enzymes from the cluster (eme) in Emericella quadrilineata. EmeO acts as a bifunctional enzyme for the construction of the 15‐membered lactone ring via an aryl‐aryl ether bond formation and simultaneous hydroxylation between phenolic and nonphenolic aromatic rings, while EmeE and EmeR install ...
Yu‐Chuan Chen +3 more
wiley +1 more source

