Deazaflavin‐Catalyzed Arylation of White Phosphorus with Aryl Bromides and Chlorides
The 5‐aryldeazaflavin photocatalyst o‐Me‐dFl catalyzes the arylation of white phosphorus with aryl chlorides and bromides under near UV‐LED irradiation, affording triarylphosphines and tetraarylphosphonium salts. Nuclear magnetic resonance studies and density functional theory calculations offer insights into the reaction pathway.
Jannes Rückel+4 more
wiley +1 more source
Assessing the Efficacy of Pyrolysis-Gas Chromatography-Mass Spectrometry for Nanoplastic and Microplastic Analysis in Human Blood. [PDF]
Rauert C+5 more
europepmc +1 more source
Improved conditions for gas-liquid chromatography of triglycerides
A. Kuksis, W. C. Breckenridge
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The halide motif is ubiquitous in organic synthesis, facilitating fine‐tuning of molecular properties and functionalization using substitution and cross‐coupling reactions. Combination of different flavin‐dependent tryptophan halogenases enables the installation of novel halogenation patterns on l‐tryptophan, which can be orthogonally addressed in ...
Nicolai Montua+4 more
wiley +1 more source
A Novel Method to Determine the Carbon Isotopic Composition of Inositol Hexaphosphate (Phytate) in Soil by Gas Chromatography-Combustion-Isotope Ratio Mass Spectrometry. [PDF]
Sarangi V, Spohn M.
europepmc +1 more source
GA: Strained small motifs and SuFEx hubs are of increasing importance in drug discovery to enable efficient late‐stage functionalization. Here, the synthesis of bench‐stable azabicyclo[1.1.0]butyl‐substituted sulfonimidoyl fluoride as an electrophilic hub with dual activation mode is reported.
Defne Serbetci+5 more
wiley +1 more source
Serum metabolic profiling of patients with diabetic kidney disease based on gas chromatography-mass spectrometry. [PDF]
Bian X+11 more
europepmc +1 more source
THE DETERMINATION OF DIACETYL AND 2,3-PENTANEDIONE IN BEER HEAD SPACE BY GAS CHROMATOGRAPHY
G.A. Harrison+2 more
openalex +1 more source
Redrawing the Mannich‐Type Reaction through Carbonyl Umpolung Reactivity
GA: Herein, a conceptually novel one‐pot multicomponent strategy is reported for the streamlined construction of five‐membered imidazolidines from 1,2‐diaza‐1,3‐dienes (onefold), amines (twofold), and formaldehyde (twofold). This redesigned Mannich‐type reaction that exploits a carbene‐like activity of 1,2‐diaza‐1,3‐dienes (realized by “umpolung ...
Vittorio Ciccone+4 more
wiley +1 more source
Rapid micropropagation and chemical profiling of in vitro plantlets and agarwood of Gyrinops walla Gaertn. by gas-chromatography and mass-spectrometry. [PDF]
Selvaskanthan S+2 more
europepmc +1 more source