Results 1 to 10 of about 545,058 (211)

Two Coexisting Pathways to Volatility in Valence‐Change Memory Devices

open access: yesAdvanced Functional Materials, EarlyView.
Volatile VCM‐type memristive devices exhibit current relaxation after resistive switching, but their microscopic origin remains debated. Using pulsed measurements and a new Tunnel‐DLTS approach on Pt/SrTiO3/Nb:SrTiO3 devices, we show that post‐SET volatility is predominantly ionic, while electronic contributions—arising from quasi‐Fermi‐level ...
Johannes Hellwig   +3 more
wiley   +1 more source

Unusual Temperature‐Enhanced Bulk Photovoltaic Effect Beyond the Centrosymmetric Phase in CuCrP2S6 van der Waals Crystals

open access: yesAdvanced Functional Materials, EarlyView.
Contrary to conventional expectations, the bulk photovoltaic effect in CuCrP2S6 is enhanced rather than suppressed upon transitioning into the crystallographically centrosymmetric phase. Dynamic Cu‐ion disorder creates transient polar states, which substantially amplifies zero‐bias photocurrent (shift‐current) generation, establishing dynamic symmetry ...
Ryoga Murata, Takao Sasagawa
wiley   +1 more source

Meniscus‐Guided Soft‐Lithographic Assembly of Grid‐Type Molecular Martensite Films for Single‐Crystal‐Like Actuation

open access: yesAdvanced Functional Materials, EarlyView.
A meniscus‐guided microtransfer molding strategy enables scalable fabrication of grid‐type molecular martensite films with b‐axis‐correlated preferential texture. Sequential growth across microchannel intersections creates structurally continuous grids and robust thermoelastic actuation (∼11% strain, > 50 cycles, maximum force density: 7.1 × 109 N m−3).
Sooyeon Ra   +15 more
wiley   +1 more source

Interaction‐Driven Assembly Pathways in Heterogeneous Active Microrobotic Systems

open access: yesAdvanced Functional Materials, EarlyView.
Peanut‐ and cube‐shaped light‐powered microrobots exhibit distinct magnetic and photocatalytic responses that determine their heterogeneous self‐assembly. In the dark, magnetic dipole interactions drive colloidal copolymerization with cubes acting as nucleation centers, whereas under light irradiation, phoretic interactions compete with magnetic ...
Domenico Calabrò   +5 more
wiley   +1 more source

Electrostatic Superlattices Beyond 1:1 Stoichiometry

open access: yesAdvanced Functional Materials, EarlyView.
Polymer‐mediated charge regulation drives two hierarchical routes to higher‐stoichiometry nanoparticle superlattices. Tuning the polymer's molecular weight promotes progressive interstitial filling, transforming ZnS into the fully occupied CaF2${\rm CaF}_2$ lattice. Exchanging polymer assignment between large and small nanoparticles instead breaks CsCl
Binay P. Nayak   +7 more
wiley   +1 more source

Sulfur‐Free Ultrahigh‐Refractive‐Index Polymers Enabled by Densely Packed Oxygen‐Bridged Dibenzofuran‐Cardo Architectures

open access: yesAdvanced Functional Materials, EarlyView.
A new class of sulfur‐free, oxygen‐bridged dibenzofuran‐based polymers is developed for ultrahigh‐refractive‐index applications. The rigid π‐extended architecture and enhanced molecular polarizability enable exceptional optical performance, combining refractive indices up to 1.848 with high Abbe numbers and full visible transparency. This work offers a
Hend A. Hegazy   +5 more
wiley   +1 more source

An Edible Chitosan‐Based Acoustic Sensor for Sound‐Responsive Actuation in Edible Robots

open access: yesAdvanced Functional Materials, EarlyView.
This study introduces an edible acoustic sensor for robotic food and edible robotics. Built from a chitosan piezoelectric film between gold electrodes, the sensor enables acoustic communication through ON/OFF keying. Integrated into an edible robot with pneumatically actuated arms and neck, it responds to high‐frequency tones.
Valerio Francesco Annese   +8 more
wiley   +1 more source

Charge‐Tunable Coacervate Micelles for Separator Engineering in Lithium‐Sulfur Batteries

open access: yesAdvanced Functional Materials, EarlyView.
A separator engineering strategy based on charge‐tunable complex coacervate core micelles (C3Ms) is presented to form an ion‐selective layer regulating polysulfide transport in Li–S batteries. The micelles enable uniform adsorption onto commercial polypropylene separators and infiltration throughout the internal pore network, suppressing polysulfide ...
Yongsheng Zhang   +11 more
wiley   +1 more source

3D Hydrodynamic Flow Lithography

open access: yesAdvanced Functional Materials, EarlyView.
ABSTRACT Continuous‐ and stop‐flow lithography are widely used to fabricate multi‐dimensional microstructures whose cross‐sectional morphology is dictated by the flow profile of multiple co‐flowing streams. Here, we introduce three‐dimensional hydrodynamic flow lithography (3D HFL), a platform for programmable generation of multi‐layered flow profiles ...
Yiying Zou   +5 more
wiley   +1 more source

Chemical Control of Space Charge Barriers and Grain Boundary Resistances in Polycrystalline Ionic Conductors

open access: yesAdvanced Functional Materials, EarlyView.
Grain boundaries (GBs) in polycrystalline materials often block charge transport and drive degradation. Using Gd‐doped CeO2 as a model electrolyte used in fuel/electrolysis cells, we developed a core‐shell infiltration method to selectively modify GB chemistry and space charge potential, achieving orders‐of‐magnitude ionic conductivity changes.
Z. Sha   +5 more
wiley   +1 more source

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