Reviewing Glycosyl‐Inositols: Natural Occurrence, Biological Roles, and Synthetic Techniques [PDF]
Overall, this comprehensive review underscores the significance of glycosyl inositols as versatile molecules with diverse biological functions and promising applications in scientific research and industry. Methods for their chemical and enzymatic synthesis are also reviewed, highlighting recent advances and challenges in the field.
Alfonso Miranda‐Molina+3 more
wiley +2 more sources
Elucidating reactive sugar-intermediates by mass spectrometry [PDF]
The stereoselective introduction of glycosidic bonds is one of the greatest challenges in carbohydrate chemistry. A key aspect of controlling glycan synthesis is the glycosylation reaction in which the glycosidic linkages are formed.
Chun-Wei Chang+8 more
doaj +2 more sources
Glycosyl Formates: Glycosylations with Neighboring-Group Participation [PDF]
Protected 2-O-benzyolated glycosyl formates were synthesized in one-step from the corresponding orthoester using formic acid as the sole reagent.
Liang Yang, Christian Marcus Pedersen
doaj +4 more sources
One‐Pot Hetero‐Di‐C‐Glycosylation of the Natural Polyphenol Phloretin by a Single C‐Glycosyltransferase With Broad Sugar Substrate Specificity [PDF]
Here, an efficient system for synthesizing high‐value polyphenol hetero‐di‐C‐glycosides with two distinct C‐glycosyl residues was established using a two‐step glycosylation catalyzed by C‐glycosyltransferase in one pot. The desired C‐β‐galactosyl‐C‐β‐glucosyl and C‐β‐glucosyl‐C‐β‐xylosyl phloretin were obtained at concentrations of 0.6 and 6 g/L ...
Tuo Li+4 more
wiley +2 more sources
Organic Functional Groups and Their Substitution Sites in Natural Flavonoids: A Review on Their Contributions to Antioxidant, Anti‐Inflammatory, and Analgesic Capabilities [PDF]
Analgesic flavonoids exhibit both antioxidant and anti‐inflammatory properties, with prenylated groups potentially enhancing their effects. In contrast, biflavonoids generally demonstrate either anti‐inflammatory or analgesic capabilities. Furthermore, key substitution sites in these compounds can be fully replaced by various organic functional groups,
Jingxian An+5 more
wiley +2 more sources
Genetic and transcriptomic analysis of lentil seed imbibition and dormancy in relation to its domestication [PDF]
Abstract Seed dormancy is an adaptation that delays germination to prevent the start of this process during unsuitable conditions. It is crucial in wild species but its loss was selected during crop domestication to ensure a fast and uniform germination. Water uptake, or imbibition, is the first step of germination.
Azalea Guerra‐García+5 more
wiley +2 more sources
In the present study, we created the weight gain models with Min and Yorkshire pigs and conducted the metagenomics and metabolomics of colon contents and transcriptomics of colon tissue. Further, we revealed the characteristics and functions of the colonic microbiota in Min and Yorkshire pigs and analyzed their interactions with the host. Overall, this
Xiaoyu Huang+6 more
wiley +1 more source
Osteocalcin is a bone matrix protein that acts like a hormone when it reaches the blood, and has different effects in mice and humans.
Harry C Blair, Paul H Schlesinger
openaire +4 more sources
Intramolecular glycosylation [PDF]
Carbohydrate oligomers remain challenging targets for chemists due to the requirement for elaborate protecting and leaving group manipulations, functionalization, tedious purification, and sophisticated characterization. Achieving high stereocontrol in glycosylation reactions is arguably the major hurdle that chemists experience.
Xiao G. Jia, Alexei V. Demchenko
openaire +3 more sources
Stereoselective glycosylations using oxathiane spiroketal glycosyl donors [PDF]
Novel oxathiane spiroketal donors have been synthesised and activated via an umpolung S-arylation strategy using 1,3,5-trimethoxybenzene and 1,3-dimethoxybenzene.
Fascione, MA+4 more
core +1 more source