Results 41 to 50 of about 1,028 (203)
Three-Component Glycolate Michael Reactions of Enolates, Silyl Glyoxylates, and α,β-Enones [PDF]
, 2012 Silyl glyoxylates react with enolates and enones to afford either glycolate aldol or Michael adducts. Product identity is controlled by the countercation associated with the enolate.
Johnson, Jeffrey +2 more
core +1 more source
Binuclear Copper‐Dependent Oxidative Enzymes Involved in Fungal Natural Product Modifications
Journal of the Chinese Chemical Society, EarlyView.This article summarizes recent biochemical characterizations of a new enzyme family named by the authors as binuclear copper‐dependent oxidative enzymes (BiNCOs). Found in fungal natural product biosynthesis, BiNCOs catalyze diverse CH functionalization reactions, including C(sp3)H halogenation, C(sp3)H hydroxylation, C(sp3)O macrocyclization, and ...
Chen‐Yu Chiang, Masao Ohashi, Yi Tang
wiley +1 more source
, 2016 Three-component coupling reactions of sulfonylimidates, silyl glyoxylates and N-tert-butanesulfinyl aldimines efficiently provide cyclic N-sulfonylamidines containing free endocyclic N–H.
Chong-Dao Lu (1393924) +1 more
core +3 more sources
Journal of Chemical Technology &Biotechnology, EarlyView.Abstract BACKGROUND Recombinant protein expression in Escherichia coli frequently results in the formation of inclusion bodies (IBs), which provide high protein accumulation but often require additional steps to recover functional protein. Although culture conditions strongly influence IB physicochemical and structural characteristics, the impact of ...
Ximena Gómez‐Gil +7 more
wiley +1 more source
A systematic 15N‐amino‐acid tracer framework to identify sources of pelagic marine organic matter
Limnology and Oceanography: Methods, EarlyView.Abstract Accurately tracing organic matter sources in marine systems remains challenging, particularly where natural and anthropogenic inputs coexist. Compound‐specific stable isotope analysis of amino acids (CSIA‐AA) offers strong potential for organic matter source discrimination, but its application is limited by the small number of validated δ15N ...
E. Cepeda +5 more
wiley +1 more source
Remote Stereoinduction in the Acylation of Fully Substituted Enolates: Tandem Reformatsky/Quaternary Claisen Condensations of Silyl Glyoxylates and β-Lactones [PDF]
, 2010 Reformatsky reagents react sequentially with silyl glyoxylates and β-lactones to give highly functionalized Claisen condensation products. A heretofore undocumented instance of stereochemical 1,4-induction results in efficient transmission of β-lactone ...
Jeffrey S. Johnson +5 more
core +1 more source
XXVI.—On the constitution of glyoxylic acid [PDF]
J. Chem. Soc.n ...
Perkin, W. H., Duppa, B. F.
openaire +1 more source
Medicine Bulletin, EarlyView.ABSTRACT β‐Aminoisobutyric acid (BAIBA) is an exercise‐responsive myokine/metabolite released by skeletal muscle and has attracted increasing interest as a potential exercise mimetic and therapeutic candidate in preclinical research. BAIBA acts locally in skeletal muscle and can also reach distal organs through the circulation, contributing to the ...
Hao‐Zhe Wang +5 more
wiley +1 more source
From wild to tamed: Reimagining novel crops through omics and local plant diversity
PLANTS, PEOPLE, PLANET, EarlyView.The global food system faces growing pressure from climate change, biodiversity loss, and rising nutritional demands. Agriculture has increased yields but reduced crop diversity, flavor, and nutritional quality, leaving societies vulnerable and dependent on a narrow set of staple species.
Alexandra Sanfeliu Meliá +1 more
wiley +1 more source
Pest Management Science, EarlyView.This review bridges the gap between understanding resistance mechanisms and applying them in weed management, highlighting how mechanistic insights reveal vulnerabilities that can guide more effective control strategies. Abstract Herbicide resistance remains one of the most intensively studied areas in weed science because of its direct consequences ...
Luan Cutti +3 more
wiley +1 more source