A dual catalytic strategy for carbon-phosphorus cross-coupling via gold and photoredox catalysis. [PDF]
, 2014 A new method for the P-arylation of aryldiazonium salts with H-phosphonates via dual gold and photoredox catalysis is described. The reaction proceeds smoothly at room temperature in the absence of base and/or additives, and offers an efficient approach ...
He, Ying, TOSTE, F. Dean, Wu, Hongmiao
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Identification of single-site gold catalysis in acetylene hydrochlorination [PDF]
, 2017 There remains considerable debate over the active form of gold under operating conditions of a recently validated gold catalyst for acetylene hydrochlorination.
Catlow, C. Richard A. +14 more
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Reactivity of Gold Hydrides: O2 Insertion into the Au–H Bond [PDF]
, 2015 Dioxygen reacts with the gold(I) hydride (IPr)AuH under insertion to give the hydroperoxide, (IPr)AuOOH, a long-postulated reaction in gold catalysis and the first demonstration of O2 activation by Au-H in a well-defined system.
Barrio L. +28 more
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Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C–AuI Bonds in [AuRL] Complexes [PDF]
, 2018 Producción CientíficaThe protonolysis of C–Au bonds in [AuRL] organometallic complexes has been studied by calorimetry for twelve R groups. The experimental data have been combined with DFT calculations to obtain Bond Dissociation Energy values (BDE).
Casares González, Juan Ángel +2 more
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Designing hollow nano gold golf balls. [PDF]
, 2014 Hollow/porous nanoparticles, including nanocarriers, nanoshells, and mesoporous materials have applications in catalysis, photonics, biosensing, and delivery of theranostic agents.
Anzenberg, Paula +11 more
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Double layer charging driven carbon dioxide adsorption limits the rate of electrochemical carbon dioxide reduction on Gold. [PDF]
, 2020 Electrochemical CO[Formula: see text] reduction is a potential route to the sustainable production of valuable fuels and chemicals. Here, we perform CO[Formula: see text] reduction experiments on Gold at neutral to acidic pH values to elucidate the long ...
Chan, Karen +6 more
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Tailoring Gold Nanoparticle Characteristics and the Impact on Aqueous-Phase Oxidation of Glycerol [PDF]
, 2015 Poly(vinyl alcohol) (PVA)-stabilized Au nanoparticles (NPs) were synthesized by colloidal methods in which temperature variations (−75 to 75 °C) and mixed H2O/EtOH solvent ratios (0, 50, and 100 vol/vol) were used.
Catlow, CRA +12 more
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Molecular Valves for Controlling Gas Phase Transport Made from Discrete Angstrom-Sized Pores in Graphene [PDF]
, 2014 An ability to precisely regulate the quantity and location of molecular flux is of value in applications such as nanoscale 3D printing, catalysis, and sensor design.
A Cembran +40 more
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Construction of spirocarbocycles via gold-catalyzed intramolecular dearomatization of naphthols. [PDF]
, 2016 A highly efficient, gold-catalyzed intramolecular dearomatization reaction of naphthols via 5-endo-dig cyclization is described.
Wu, Wen-Ting +3 more
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Industrial Applications of Gold Catalysis
Angewandte Chemie International Edition, 2016 AbstractGold catalysis has recently found its first large‐scale applications in the chemical industry. This Minireview provides a critical analysis of the success factors and of the main obstacles that had to be overcome on the long way from the discovery to the commercialization of gold catalysts.
Rosaria Ciriminna +4 more
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