Non-Innocent Ligands as Mediators for Visible-Light-Initiated Element-Carbon Bond Homolysis in Main Group Chemistry. [PDF]
Wenzel JO, Werner J, Breher F.
europepmc +1 more source
Diaryl Bismuthides and Acyl Bismuthanes Enable Visible-Light-Induced Reversible Carbon Monoxide Insertion and Extrusion. [PDF]
Geist F +6 more
europepmc +1 more source
Dinickel-catalyzed enantioselective reductive addition of imines with vinyl halides. [PDF]
Zhou P +5 more
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Thermometer Ions, Internal Energies, and In‐Source Fragmentation in Ambient Ionization
ABSTRACT Ionization and fragmentation are at the core of mass spectrometry. But they are not necessarily separated in space, as in‐source fragmentation can also occur. Here, we survey the literature published since our 2005 review on the internal energy and fragmentation in electrospray ionization sources.
Emilie Bertrand, Valérie Gabelica
wiley +1 more source
Realization of a Heteroatom-Transfer-Ligand (HTL) Platform: Oxy Insertion at a Titanium-Alkyl Bond Facilitated by a Hydroxylaminato Ligand Framework. [PDF]
Cheisson T +4 more
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We report the results from a kinetic and mechanistic investigation of an inverse‐electron‐demand Diels–Alder (IEDDA) cycloaddition involving an oxazole‐type diene synthesized via an Ugi–Zhu multicomponent reaction (UZ‐3CR). ABSTRACT Pyridines are a crucial class of heterocycles with widespread applications in natural products, pharmaceuticals, and ...
Galdina V. Suárez‐Moreno +6 more
wiley +1 more source
Substrate‐Selective Temperature‐Controlled Synthesis of Thiophene Derivatives at Interfaces
The deposition of a dithiophene derivative on Ag(111) at room temperature followed by annealing gives rise to molecular wires, whereas the adsorption of the same precursor on a hot substrate affords the formation of benzotrithiophene species. Abstract The temperature‐controlled transformation of organic molecules at interfaces is an incipient yet ...
Elena Pérez‐Elvira +16 more
wiley +2 more sources
Stereoselective palladium-catalyzed carboetherification of cyclopropenes <i>via</i> a tethering strategy. [PDF]
Brownsey DK, Schoepfer AA, Waser J.
europepmc +1 more source
Advanced Electrochemical C-C Bond Formation Using a Michael-Type Nozaki-Hiyama-Kishi (NHK) Reaction. [PDF]
Torabi S, Jamshidi M, Khazalpour S.
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Amido‐Imidazolin‐2‐imine Zinc Complexes: Facile Preparation by Mild In Situ Deprotonation
A representative amino‐imidazolin‐2‐imine ligand enables the preparation of stable zinc N,N´‐chelate complexes via in situ deprotonation. This mild method generates only volatile side products and affords both zinc(I) and zinc(II) complexes in good yield and high purity.
Leo Wessel +5 more
wiley +1 more source

