Results 121 to 130 of about 12,872 (188)

New Insights into Poly(Dichlorophosphazene) Synthesis via Me3Si─N═PCl3 Polymerization: An Experimental and Theoretical Study

open access: yesChemistry – A European Journal, EarlyView.
Poly(dichlorophosphazene) synthesis via Me3Si─N═PCl3 polymerization was reinvestigated using quantum chemical calculations and experiments. A cationic initiator (Ph3PCl2) enables ambient‐temperature polymerization through chloride‐catalyzed cationic pathways involving dissociation, nucleophilic chloride attack, and chain‐propagating species formation ...
Cornelius Knuth   +6 more
wiley   +1 more source

Multimodal Fluorescent MOF@BODIPY Platform: Bridging Sensing and Mechanistic Insight

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Hybrid metal–organic frameworks (MOFs) that integrate organic chromophores constitute powerful platforms for optical sensing by combining structural order with tunable photophysics. Incorporating photoresponsive chromophores into MOFs enables sensitive probing of guest–framework interactions through well‐defined luminescent signatures. Herein,
Alejandro Cortés‐Villena   +8 more
wiley   +1 more source

Synthesis and Structures of Novel Chiral Cyclic Hypervalent Iodine(III) Reagents for Metal‐Free Ligand‐Transfer Reactions

open access: yesChemistry – A European Journal, EarlyView.
Several new chiral cyclic hypervalent iodine(III) reagents have been synthesized and characterized. Carbon‐based ligands were successfully installed onto the hypervalent iodine centers, giving thus access to novel chiral cyano‐, trifluoromethyl‐ or alkynyl‐bearing λ3‐iodanes.
Emmanuel Valzer   +4 more
wiley   +1 more source

Dual‐Stabilized Single‐Site Fe(II) for Catalytic Conversion of CO2 to Propiolic Acid Under Ambient Condition

open access: yesEcoEnergy, EarlyView.
We develop a highly cost‐effective heterogeneous catalyst for efficient CO2 conversion to propiolic acid under mild conditions via a nano‐confined approach with porous MIL support. ABSTRACT Efficient conversion of carbon dioxide to organics has been a promising outlet for value‐added carbon dioxide consumption.
Bin Lei   +6 more
wiley   +1 more source

New‐Generation Integrated Devices: Multiple‐Energy Utilization and Integration Systems Based on Perovskite Photovoltaics

open access: yesEcoEnergy, EarlyView.
This review highlights emerging integrated energy systems based on perovskite photovoltaics, including PSC–thermoelectric, photovoltaic–electrochemical, self‐charging, and building‐integrated architectures. By coupling multiple energy conversion and storage pathways, these multifunctional platforms enable enhanced solar utilization, improved stability,
Yihuai Huang   +10 more
wiley   +1 more source

Active Bromine Cycling Enables Bromate as an Oxidant of Mn(II) on the Low-Temperature Martian Surface. [PDF]

open access: yesInorg Chem
Qu SY   +8 more
europepmc   +1 more source

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