Results 11 to 20 of about 1,415,920 (286)

Fine-tuning Substrate--Catalyst Halogen--Halogen Interactions for Boosting Enantioselectivity in Halogen-Bonding Catalysis.

open access: yesAngewandte Chemie, 2023
A new approach towards highly enantioselective halogen-bonding catalysis has been developed. In order to circumvent the intrinsic issues of the halogen-bond (XB) nature and consequent unresolved limitations in asymmetric catalysis, fine-tuned halogen ...
Alica C. Keuper   +5 more
semanticscholar   +1 more source

Astatine Facing Janus: Halogen Bonding vs. Charge-Shift Bonding

open access: yesMolecules, 2021
The nature of halogen-bond interactions was scrutinized from the perspective of astatine, potentially the strongest halogen-bond donor atom. In addition to its remarkable electronic properties (e.g., its higher aromaticity compared to benzene), C6At6 can
Serigne Sarr   +4 more
doaj   +1 more source

Halogen Bonding in Perovskite Solar Cells: A New Tool for Improving Solar Energy Conversion

open access: yesAngewandte Chemie, 2021
Hybrid organic–inorganic halide perovskites (HOIHPs) have recently emerged as a flourishing area of research. Their easy and low‐cost production and their unique optoelectronic properties make them promising materials for many applications. In particular,
P. Metrangolo   +4 more
semanticscholar   +1 more source

Direct arylation reaction of heteroarenes mediated by photoinduced electron transfer

open access: yesJournal of Photochemistry and Photobiology, 2023
Electron donor–acceptor (EDA) complexes are interesting chemical species that function as molecular complexes. In this context, chemists have actively studies the use of halogen bonding as a noncovalent interaction in photochemistry.
Eiji Yamaguchi, Oe Karin, Akichika Itoh
doaj   +1 more source

“Anti‐electrostatic” Halogen Bonding between Ions of Like Charge

open access: yesChemistry, 2021
Halogen bonding occurs between molecules featuring Lewis acidic halogen substituents and Lewis bases. It is often rationalized as a predominantly electrostatic interaction and thus interactions between ions of like charge (e.
Jana M. Holthoff   +3 more
semanticscholar   +1 more source

Halogen-bonded shape memory polymers

open access: yesNature Communications, 2022
Halogen bonding is widely adopted in organic synthesis and supramolecular crystal engineering but application of halogen bonding in the design of stimuli-responsive materials is challenging.
Hongshuang Guo   +6 more
doaj   +1 more source

Highly Active Halogen Bonding and Chalcogen Bonding Chloride Transporters with Non‐Protonophoric Activity

open access: yesChemistry, 2021
Synthetic anion transporters show much promise as potential anti‐cancer agents and therapeutics for diseases associated with mis‐regulation of protein anion channels.
L. Bickerton   +6 more
semanticscholar   +1 more source

Role of Halogen Substituents on Halogen Bonding in 4,5-DiBromohexahydro-3a,6-Epoxyisoindol-1(4H)-ones

open access: yesCrystals, 2021
A series of 4,5-dibromo-2-(4-substituted phenyl)hexahydro-3a,6-epoxyisoindol-1(4H)-ones were synthesized by reaction of the corresponding 2-(4-substituted phenyl)-2,3,7,7a-tetrahydro-3a,6-epoxyisoindol-1(6H)-ones with [(Me2NCOMe)2H]Br3 in dry chloroform ...
Atash V. Gurbanov   +9 more
doaj   +1 more source

Halogen bonding in polymer science: towards new smart materials

open access: yesChemical Science, 2021
The halogen bond is a special non-covalent interaction, which can represent a powerful tool in supramolecular chemistry. Although the halogen bond offers several advantages compared to the related hydrogen bond, it is currently still underrepresented in ...
Robin Kampes   +3 more
semanticscholar   +1 more source

Home - About - Disclaimer - Privacy