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Addition Reactions of Phosphorus‐Centered Radicals onto Olefins: Interplay Between Stability and Reactivity

Chemistry – A European Journal, EarlyView.
The energetics of the addition reaction of P‐centered radicals onto alkenes are primarily ruled by the stability of the attacking radical, as outlined by the computational screening of a wide range of reactions. In addition, donor‐acceptor substituents at the olefin have an important tuning role.
Meng Yang, Julianna Oláh, Zoltán Benkő   +2 more
wiley   +1 more source

Combination of Hydrogen and Halogen Bonds in the Crystal Structures of 5-Halogeno-1H-isatin-3-oximes: Involvement of the Oxime Functionality in Halogen Bonding. [PDF]

Molecules
Meier E, Seichter W, Mazik M.
europepmc   +1 more source

Hybrid 2D Supramolecular Organic Frameworks (SOFs) Assembled by the Cooperative Action of Hydrogen and Halogen Bonding and π⋯π Stacking Interactions. [PDF]

Int J Mol Sci
Baykov SV, Semenov AV, Presnukhina SI, Tarasenko MV, Shetnev AA, Frontera A, Boyarskiy VP, Kukushkin VY.   +7 more
europepmc   +1 more source

Selective sodium halide over potassium halide binding and extraction by a heteroditopic halogen bonding [2]catenane. [PDF]

Chem Sci
Tay HM, Docker A, Hua C, Beer PD.
europepmc   +1 more source

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Halogen Bonding: A New Platform for Achieving Multi-Stimuli-Responsive Persistent Phosphorescence.

Angewandte Chemie, 2022
Monotonous luminescence has always been a major factor limiting the application of organic room-temperature phosphorescence (RTP) materials. Enhancing and regulating the intermolecular interactions between the host and guest is an effective strategy to ...
Wenbo Dai, Xiaowei Niu, Xinghui Wu, Yue Ren, Yongfeng Zhang, Gengchen Li, Han Su, Y. Lei, Jiawen Xiao, Jianbing Shi, B. Tong, Zhengxu Cai, Yuping Dong   +12 more
semanticscholar   +1 more source

Constructing a Stable and Efficient Buried Heterojunction via Halogen Bonding for Inverted Perovskite Solar Cells

Advanced Energy Materials, 2022
The inverted perovskite solar cell has made great progress in recent years and the quality of the heterojunction has played a key role. Here, a series of halide‐substituted benzoic acid molecules are investigated as the bridge between nickel oxide and ...
Caiyi Zhang, Xiangqian Shen, Mengjiong Chen, Yan Zhao, Xuesong Lin, Zhenzhen Qin, Yanbo Wang, Liyuan Han   +7 more
semanticscholar   +1 more source

Can Counter-Intuitive Halogen Bonding Be Coulombic?

ChemPhysChem, 2021
We use the term "counter-intuitive" to describe an intermolecular interaction in which the electrostatic potentials of the interacting regions of the ground-state molecules have the same sign, both positive or both negative.
J. Murray, P. Politzer
semanticscholar   +1 more source

Role of Charge Transfer in Halogen Bonding.

Journal of Physical Chemistry A, 2021
Halogen bonding has received intensive attention recently for its applications in the construction of supramolecular assemblies and crystal engineering and its implications and potentials in chemical and biological processes and rational drug design ...
Brandon L. Inscoe, H. Rathnayake, Y. Mo
semanticscholar   +1 more source

Boosting Quantum Efficiency of Ultralong Organic Phosphorescence up to 52% via Intramolecular Halogen Bonding.

Angewandte Chemie, 2020
Ultralong organic phosphorescence (UOP) has attracted increasing attention due to its potential applications in optoelectronics, bioelectronics, and security protection.
Zhan Yang, Chao Xu, Wenlang Li, Z. Mao, Xiangyu Ge, Qiuyi Huang, Huangjun Deng, Juan Zhao, F. Gu, Yi Zhang, Zhenguo Chi   +10 more
semanticscholar   +1 more source