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Halogen bonding motifs for anion recognition

, 2020
The halogen bond is a powerful non-covalent interaction between the electron deficient sigma-hole region of a group 17 halogen element covalently bonded to electron withdrawing groups, and a Lewis base.
Jessica Pancholi, P. Beer
semanticscholar   +1 more source

Catalysis of Organic Reactions through Halogen Bonding

ACS Catalysis, 2019
Halogen bonding, the noncovalent interaction based on electrophilic halogen substituents, features very interesting properties, as illustrated by numerous applications continuously emerging in rece...
R. L. Sutar, S. Huber
semanticscholar   +1 more source

Halogen bonding in room-temperature phosphorescent materials

, 2020
Room-temperature phosphorescent materials have recently attracted much research interest due to their unique physicochemical properties and potential applications in many areas.
Weizhou Wang, Yu Zhang, W. Jin
semanticscholar   +1 more source

Halogen bonding for molecular recognition: new developments in materials and biological sciences.

Chemical Communications, 2020
Two decades ago, halogen bonding attracted considerable attention as a new type of non-covalent interaction and has now emerged as an important supramolecular tool for crystal engineering, demonstrating its ability to self-assemble low affinity entities.
Gilles Berger   +2 more
semanticscholar   +1 more source

Fixation of CO2 into cyclic carbonates by halogen bonding catalysis.

ChemSusChem, 2020
Halogen bonding, parallel to hydrogen bonding, was introduced into the catalytic cycloaddition of carbon dioxide into epoxide (CCE) reactions. A series of halogen bond donor (XBD) catalysts of N -iodopyridinium halide featured with N-I bond were ...
Rui Yan   +9 more
semanticscholar   +1 more source

Interaction Nature and Computational Methods for Halogen Bonding: A Perspective

Journal of Chemical Information and Modeling, 2020
Halogen bonds are noncovalent interactions that have been widely used in many fields, including drug design, crystal engineering and material sciences.
Zhengdan Zhu, Zhijian Xu, Weiliang Zhu
semanticscholar   +1 more source

Evidence for Halogen Bonding in Amorphous Solid Dispersions

, 2020
Carbon-bound halogen atoms (iodine, bromine, chlorine and occasionally fluorine) are known to act as electron acceptors and form interactions with different species capable of acting as electron do...
Chailu Que   +9 more
semanticscholar   +1 more source

Halogen bonding in halocarbon-protein complexes and computational tools for rational drug design

Expert Opinion on Drug Discovery, 2019
Introduction: Halogens have a prominent role in drug design. Often used as a mean to improve ADME properties, they are also becoming a tool in protein–ligand recognition given their ability to form a non-covalent interaction, termed halogen bond, where ...
Paulo J. Costa   +2 more
semanticscholar   +1 more source

Halogen Bonding in Dithiane/Iodofluorobenzene Mixtures: A New Class of Hydrophobic Deep Eutectic Solvents.

Angewandte Chemie, 2021
Andrew J. Peloquin   +3 more
semanticscholar   +1 more source

A Potent Halogen-Bonding Donor Motif for Anion Recognition and Anion Template Mechanical Bond Synthesis.

Angewandte Chemie, 2019
The covalent attachment of electron deficient perfluoroaryl substituents to a bis-iodotriazole pyridinium group produces a remarkably potent halogen bonding donor motif for anion recognition in aqueous media. Such a motif also establishes halogen bonding
Thanthapatra Bunchuay   +3 more
semanticscholar   +1 more source

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