Results 121 to 130 of about 469,475 (238)

Halogen bonds in 2,5-dihalopyridine-copper(II) chloride complexes

open access: yes, 2018
Ten coordination complexes obtained through a facile reaction between 2,5-dihalopyridines and copperIJII) chloride (CuCl2) are characterized using single crystal X-ray diffraction.
Peuronen, Anssi   +9 more
core   +1 more source

Multifunctional Ionic Liquid Enabling Cation Homogenization and Lead Chelation for Pure‐Iodide Wide‐Bandgap Perovskite Solar Cells

open access: yesAdvanced Science, EarlyView.
This work presents a multifunctional ionic liquid, [SO3H‐PMIm][OTf], that addresses A‐site cation inhomogeneity and lead toxicity in pure‐iodide wide‐bandgap perovskite solar cells. The additive enables homogeneous cation distribution, achieving 22.02% efficiency with 90% retention after 3000 h and reducing lead leakage by over 58%, thereby ...
Kai Wu   +8 more
wiley   +1 more source

Two-Dimensional Inorganic Cationic Network of Thorium Iodate Chloride with Unique Halogen–Halogen Bonds

open access: yes, 2016
A unique two-dimensional inorganic cationic network with the formula [Th3O2(IO3)5(OH)2]Cl was synthesized hydrothermally. Its crystal structure can best be described as positively charged slabs built with hexanuclear thorium clusters connected by iodate ...
Lanhua Chen (1507306)   +8 more
core   +1 more source

Self‐Healing Pd(II) Cage Metallogels for Iodine Capture in Water and Heterogeneous Photocatalysis

open access: yesAdvanced Science, EarlyView.
Two carbazole‐derived metal‐organic cages hierarchically self‐assemble into supramolecular metallogels that integrate autonomous self‐healing, reversible stimuli responsiveness, high‐capacity aqueous iodine capture, and visible‐light‐driven photocatalytic sulfide oxidation within a single multifunctional platform.
Monotosh Dalapati   +3 more
wiley   +1 more source

Enrichment of anchoring sites by introducing supramolecular halogen bonds for the efficient perovskite nanocrystal LEDs. [PDF]

open access: yesLight Sci Appl, 2023
Lu P   +13 more
europepmc   +1 more source

Halogen-Bonded Supramolecular Parallelograms: From Self-Complementary Iodoalkyne Halogen-Bonded Dimers to 1:1 and 2:2 Iodoalkyne Halogen-Bonded Cocrystals

open access: yes
The formation of supramolecular parallelograms utilizing iodoalkyne–pyridine halogen bonding is described. The crystal structures of four iodoalkynyl-substituted (phenylethynyl)pyridines demonstrate the feasibility of discrete self-complementary dimer ...
Nathan P. Bowling (1628467)   +2 more
core   +1 more source

Structure energy relationship of biological halogen bonds [PDF]

open access: yes, 2012
2012 Summer.Includes bibliographical references.The primary goal of the studies in this thesis is to derive a set of mathematical models to describe the anisotropic atomic nature of covalent bound halogens and by extension their molecular interactions ...
Ross, Eric, committee member   +4 more
core  

Influence of substituent effects on the formation of P⋯Cl pnicogen bonds or halogen bonds

open access: yes, 2014
Ab initio MP2/aug′-cc-pVTZ calculations have been carried out in search of equilibrium structures with P⋯Cl pnicogen bonds or halogen bonds on the potential energy surfaces H2FP:ClY for Y = F, NC, Cl, CN, CCH, CH3, and H. Three different types of halogen-
Elguero, José   +2 more
core   +1 more source

Decoding Biomolecular Phase Separation: From Physiological Roles to Pathological Mechanisms and Therapeutic Biomaterials Design

open access: yesAdvanced Science, EarlyView.
This review systematically elaborates on the mechanisms underlying physiological regulation and pathological dysregulation of biomolecular phase separation. It also summarizes advances in phase‑separation‑targeted therapeutic strategies and the design of functional biomaterials inspired by this process.
Jiawei Zhu   +5 more
wiley   +1 more source

Crystal Structure Survey and Theoretical Analysis of Bifurcated Halogen Bonds. [PDF]

open access: yesCryst Growth Des, 2022
Michalczyk M, Zierkiewicz W, Scheiner S.
europepmc   +1 more source

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