Results 11 to 20 of about 449,459 (150)
Macromolecular halogen bonds [PDF]
The halogen bond is a non-covalent, stabilizing interaction analogous to a hydrogen bond in which an anisotropically polarized halogen atom interacts electrostatically with a Lewis base.
Voth, Andrea Regier
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Real-space Imaging of the Multiple Halogen Bonds by Ultrahigh-resolution Scanning Probe Microscopy [PDF]
, 2021 Understanding the physical origin of STM/AFM image contrast is of significance for not only promoting surface characterization techniques, but also probing surface nanostructures with the atomic/sub-molecular resolution.
Dingguan, Wang +5 more
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Probing Halogen Bonds by Scalar Couplings. [PDF]
J Am Chem Soc, 2021 As halogen bonding is a weak, transient interaction, its description in solution is challenging. We demonstrate that scalar coupling constants (J) are modulated by halogen bonding.
Jimmink B +4 more
europepmc +2 more sources
Activation of a Metal-Halogen Bond by Halogen Bonding [PDF]
, 2020 In recent years, the non-covalent interaction of halogen bonding (XB) has found increasing application in organocatalysis. However, reports of the activation of metal-ligand bonds by XB have so far been limited to a few reactions with elemental iodine or
Claude, Legault +7 more
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Molecules, 2021 The formation of a pair of extended networks sustained by halogen bonds based upon two regioisomers of a photoproduct, namely rctt-1,3-bis(4-pyridyl)-2,4-bis(phenyl)cyclobutane (ht-PP) and rctt-1,2-bis(4-pyridyl)-3,4-bis(phenyl)cyclobutane (hh-PP), that ...
Taylor J. Dunning +3 more
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Catalytic Activation via π –Backbonding in Halogen Bonds? [PDF]
, 2021 The role of halogen bonding (XB) in chemical catalysis has largely involved using XB donors as Lewis acid activators to modulate the reactivity of partner Lewis bases.
Andrew, Wang, Pierre, Kennepohl
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Molecules, 2020 Periodic local vibrational modes were calculated with the rev-vdW-DF2 density functional to quantify the intrinsic strength of the X-I⋯OA-type halogen bonding (X = I or Cl; OA: carbonyl, ether and N-oxide groups) in 32 model systems originating from 20 ...
Yunwen Tao +5 more
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IUCrJ, 2018 Halogen bonds have emerged as noncovalent forces that govern the assembly of molecules in organic solids with a degree of reliability akin to hydrogen bonds.
Michael A. Sinnwell +3 more
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Leveraging Halogen Interactions for a Supramolecular Nanotube [PDF]
, 2023 Supramolcular nanotubes in a single crystal were produced from halogenated macrocycles by balancing hydrogen bonds and halogen interactions. A new iodinated macrocycle was prepared, crystallized, and a bonding analysis was performed to evaluate the ...
Lorraine, Malaspina +6 more
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The Tetrel Bonds of Hypervalent Halogen Compounds
Molecules, 2023 The tetrel bond between PhXF2Y(TF3) (T = C and Si; X = Cl, Br, and I; Y = F and Cl) and the electron donor MCN (M = Li and Na) was investigated at the M06-2X/aug-cc-pVDZ level of theory.
Zhihao Niu +2 more
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