Results 41 to 50 of about 22,450 (237)
Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors
Nature Communications, 2019 Halogen bonding can be exploited for the design of functional supramolecular materials, but heavier elements that are known to accept a halogen bond remain limited.
Katarina Lisac +8 more
doaj +1 more source
Molecular Adsorbing Host•Guest (MAHG) Crystals: A New Paradigm for Porous Materials?
Advanced Functional Materials, EarlyView.Networking! Introduction of guest molecules in macrocycles before crystallization profoundly influences the material obtained in terms of structure and function. Beside simplicity and porous space improvement, this approach is endowed with a huge potential given the myriad of potential guest molecules that can be used to tune this burgeoning class of ...
Ingrid Suzana +4 more
wiley +1 more source
IUCrJ, 2015 As halogen bonds gain prevalence in supramolecular synthesis and materials chemistry, it has become necessary to examine more closely how such interactions compete with or complement hydrogen bonds whenever both are present within the same system.
Christer B. Aakeröy +4 more
doaj +1 more source
Cell Reports Physical Science, 2022 Summary: Halogen···halogen (X···X) short contacts, especially halogen bonds (XBs), have been widely used in multifarious fields because of their bridging function among luminophores, as well as their well-known heavy atom effect.
Zihao Zhao +7 more
doaj +1 more source
Spin Injection Of Exciton–Polaritons With Halide Perovskites At Room Temperature
Advanced Functional Materials, EarlyView.A monolithic Tamm‐plasmon microcavity embedding a two‐dimensional halide perovskite enables room‐temperature spin injection of exciton‐polaritons under quasi‐resonant optical excitation. Polarization‐resolved spectroscopy reveals partial preservation of the injected spin in the lower polariton branch, while bare excitons remain fully depolarized.
Elena Sendarrubias Arias‐Camisón +8 more
wiley +1 more source
Skeletal metalation of lactams through a carbonyl-to-nickel-exchange logic
Nature Communications, 2023 Classical metalation reactions such as the metal-halogen exchange have had a transformative impact on organic synthesis owing to their broad applicability in building carbon-carbon bonds from carbon-halogen bonds.
Hongyu Zhong +7 more
doaj +1 more source
Nature of the Hydrogen Bond Enhanced Halogen Bond
Molecules, 2021 The factors responsible for the enhancement of the halogen bond by an adjacent hydrogen bond have been quantitatively explored by means of state-of-the-art computational methods. It is found that the strength of a halogen bond is enhanced by ca.
Susana Portela, Israel Fernández
doaj +1 more source
Advanced Functional Materials, EarlyView.Programmable 2D magnetic clusterphenes are realized through a ligand‐mediated cluster‐assembly strategy. Direct linking of magnetic superatomic clusters enhances electron delocalization and symmetry breaking, enabling the concurrent strengthening of magnetic exchange interactions and spin–orbit coupling.
Junxiang Fu +13 more
wiley +1 more source
Halogen-Bonded Photoresponsive Materials
, 2014 The aim of the present review is to illustrate to the reader the state of the art on the construction of supramolecular azobenzene-containing materials formed by halogen bonding. These materials include several examples of polymeric, liquid crystalline or crystalline species whose performances are either superior to the corresponding performances of ...
Saccone, Marco +5 more
openaire +7 more sources
Halogen Bond Asymmetry in Solution [PDF]
Journal of the American Chemical Society, 2018 Halogen bonding is the noncovalent interaction of halogen atoms in which they act as electron acceptors. Whereas three-center hydrogen bond complexes, [D···H···D]+ where D is an electron donor, exist in solution as rapidly equilibrating asymmetric species, the analogous halogen bonds, [D···X···D]+, have been observed so far only to adopt static and ...
Sofia Lindblad +5 more
openaire +4 more sources