Results 51 to 60 of about 449,459 (150)

Anion Transport with Halogen Bonds

, 2014
This review covers the application of halogen bonds to transport anions across lipid bilayer membranes. The introduction provides a brief description of biological and synthetic transport systems.
Andreas Vargas Jentzsch, Stefan Matile, Matile, Stefan, Vargas Jentzsch, Rodrigo Andreas   +3 more
core   +1 more source

The Role of Halogen Bonding in Controlling Assembly and Organization of Cu(II)-Acac Based Coordination Complexes

Crystals, 2017
In order to explore the use of non-covalent interactions in the deliberate assembly of metal-supramolecular architectures, a series of β-diketone based ligands capable of simultaneously acting as halogen-bond donors and chelating ligands were synthesized.
Janaka C. Gamekkanda, Abhijeet S. Sinha, John Desper, Marijana Ðaković, Christer B. Aakeröy   +4 more
doaj   +1 more source

Single-Crystal NMR Characterization of Halogen Bonds

, 2019
Oxygen-17-enriched triphenylphosphine oxide and three of its halogen-bonded cocrystals featuring 1,4-diiodotetrafluorobenzene and 1,3,5-trifluoro-2,4,6-triiodobenzene as halogen bond donors have been characterized by 31P and 17O single-crystal NMR ...
Bulat Gabidullin (4455532), David L. Bryce (1236090), Yijue Xu (1236093)   +2 more
core   +2 more sources

Isostructural Halogen Exchange and Halogen Bonds: The Case of N(4-Halogenobenzyl)-3-halogenopyridinium Halogenides

, 2022
Six N-(4-halogenobenzyl)-3-halogenopyridinium cations were prepared by reacting meta-halogenopyridines (Cl, Br, and I) with (4-halogenobenzyl) bromides (Br and I) and were isolated as bromide salts, which were further used to obtain iodides and chlorides.
Luka Fotović, Vladimir Stilinović, Nikola Bedeković, Vladimir Stilinović (1645084), Nikola Bedeković (4509187), Luka Fotović (4575664)   +5 more
core   +1 more source

Crystal structure of 7-iodo-4-oxo-4H-chromene-3-carbaldehyde

Acta Crystallographica Section E: Crystallographic Communications, 2016
In the title compound, C10H5IO3, an iodinated 3-formylchromone derivative, the non-H atoms are essentially coplanar (r.m.s. deviation = 0.0344 Å), with the largest deviation from the least-squares plane [0.101 (3) Å] being found for the formyl O atom. In
Yoshinobu Ishikawa
doaj   +1 more source

Open Frameworks Formed from Iodoalkyne∙∙∙Halide Halogen Bonds [PDF]

Despite the apparently attractive characteristics of halogen bonds for preparing open/porous framework structures, very few such materials containing substantial void space have been reported.
Jordan, Smith, Nicholas, White
core   +2 more sources

Mechanochemical Preparations of Anion Coordinated Architectures Based on 3‐Iodoethynylpyridine and 3‐Iodoethynylbenzoic Acid

ChemistryOpen, 2019
The halogen bond has previously been explored as a versatile tool in crystal engineering and anion coordination chemistry, with mechanochemical synthetic techniques having been shown to provide convenient routes towards cocrystals. In an effort to expand
Vincent M. Morin, Dr. Patrick M. J. Szell, Estelle Caron‐Poulin, Dr. Bulat Gabidullin, Prof. Dr. David L. Bryce   +4 more
doaj   +1 more source

Using beryllium bonds to change halogen bonds from traditional to chlorine-shared to ion-pair bonds [PDF]

, 2015
Ab initio MP2/aug′-cc-pVTZ calculations have been carried out to investigate the structures, binding energies, and bonding characteristics of binary complexes HFBe:FCl, R2Be:FCl, and FCl:N-base, and of ternary complexes HFBe:FCl:N-base and R2Be:FCl:N ...
Elguero, José, Mó, Otilia, Alkorta, Ibon, Del Bene, Janet E.   +3 more
core   +1 more source

Crystal structure and Hirshfeld surface analysis of 2,5-dibromoterephthalic acid ethylene glycol monosolvate

Acta Crystallographica Section E: Crystallographic Communications, 2019
The title compound, C8H4Br2O4·C2H6O2, crystallizes with one-half of a 2,5-dibromoterephthalic acid (H2Br2tp) molecule and one-half of an ethylene glycol (EG) molecule in the the asymmetric unit.
Kenika Khotchasanthong, Siripak Jittirattanakun, Suwadee Jiajaroen, Chatphorn Theppitak, Kittipong Chainok   +4 more
doaj   +1 more source

Aggregation‐enabled alkene insertion into carbon–halogen bonds

Aggregate, 2023
Molecular aggregation affects the electronic interactions between molecules and has emerged as a powerful tool in material science. Aggregate effect finds wide applications in the research of new physical phenomena; however, its value for chemical ...
Meng‐Yao Li, Xiao‐Mei Nong, Han Xiao, Ao Gu, Shuyang Zhai, Jiatong Li, Ge Zhang, Ze‐Jian Xue, Yingbin Liu, Chunsen Li, Guo‐Qiang Lin, Chen‐Guo Feng   +11 more
doaj   +1 more source