Results 31 to 40 of about 469,475 (238)
Frontiers in Chemistry, 2020 The pnicogen, chalcogen, and halogen bonds between 6-OXF2-fulvene (X = As, Sb, Se, Te, Br, and I) and three nitrogen-containing bases (FCN, HCN, and NH3) are compared.
Na Liu +2 more
doaj +1 more source
Comparison of Bifurcated Halogen with Hydrogen Bonds
Molecules, 2021 Bifurcated halogen bonds are constructed with FBr and FI as Lewis acids, paired with NH3 and NCH bases. The first type considered places two bases together with a single acid, while the reverse case of two acids sharing a single base constitutes the ...
Steve Scheiner
doaj +1 more source
, 2022 Six novel halogen-bonded cocrystals of 1,3,5-triiodo-2,4,6-trifluorobenzene with three structural isomers of benzoylpyridine have been synthesized mechanochemically and by crystallization from solution, five of which were structurally characterized.
Nea Baus Topić (12557492) +4 more
core +1 more source
Astatine Facing Janus: Halogen Bonding vs. Charge-Shift Bonding
Molecules, 2021 The nature of halogen-bond interactions was scrutinized from the perspective of astatine, potentially the strongest halogen-bond donor atom. In addition to its remarkable electronic properties (e.g., its higher aromaticity compared to benzene), C6At6 can
Serigne Sarr +4 more
doaj +1 more source
NX∙∙Y Halogen Bonds. Comparison with NH∙∙Y H-bonds and CX∙∙Y Halogen Bonds [PDF]
, 2016 Quantum calculations examine how the NH∙∙Y H-bond compares to the equivalent NX∙∙Y halogen bond, as well as to comparable CH/CX donors. Succinimide and saccharin, and their corresponding halogen-substituted derivatives, are chosen as the prototype NH/NX ...
Scheiner, Steve, Nepal, Binod
core +1 more source
Halogen Bonding in Two‐Dimensional Crystal Engineering
ChemistryOpen, 2020 Halogen bonds, which provide an intermolecular interaction with moderate strength and high directionality, have emerged as a promising tool in the repertoire of non‐covalent interactions.
Dr. Joan Teyssandier +2 more
doaj +1 more source
Anion Transport with Halogen Bonds
, 2014 This review covers the application of halogen bonds to transport anions across lipid bilayer membranes. The introduction provides a brief description of biological and synthetic transport systems.
Andreas Vargas Jentzsch +5 more
core +1 more source
Halogen Bonds: Benchmarks and Theoretical Analysis [PDF]
, 2013 This article describes an extensive survey of wave function and DFT methods to test their accuracy on geometries and dissociation energies of halogen ...
Kozuch, Sebastian +3 more
core +1 more source
In silico and in vitro exploration of a tyrosinase for biocatalytic production of catechols
FEBS Open Bio, EarlyView.Tyrosinase from Ralstonia pseudosolanacearum is a promising biocatalyst for producing valuable catechols from monophenol substrates. This tyrosinase is uniquely suited to this due to its high monophenolase : diphenolase ratio. We combined in silico docking and in vivo kinetic characterisation of this tyrosinase with 11 industrially relevant monophenols,
James Britton +6 more
wiley +1 more source
Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors
Nature Communications, 2019 Halogen bonding can be exploited for the design of functional supramolecular materials, but heavier elements that are known to accept a halogen bond remain limited.
Katarina Lisac +8 more
doaj +1 more source