Results 81 to 90 of about 9,318 (208)

Ligand architecture and secondary‐sphere effects in a well‐defined cobalt(IV)–oxo complex

open access: yesBulletin of the Korean Chemical Society, Volume 47, Issue 4, Page 484-492, April 2026.
A well‐defined cobalt(IV)–oxo complex supported by a neutral tetraazamacrocyclic ligand is generated and fully characterized. The cobalt(IV)–oxo species exhibits electrophilic oxygen‐atom and hydrogen‐atom transfer reactivity, strongly modulated by protonation and secondary coordination sphere effects, providing new insight into structure–reactivity ...
Ying Xing   +3 more
wiley   +1 more source

Spectral correlation, antimicrobial and insect antifeedant activities of some 1-naphthyl keto-oxiranes

open access: yesJournal of Saudi Chemical Society, 2014
Thirteen optically active (αS,βR) 1-naphthyl keto-oxiranes (1-naphthyl-4-yl[3-(substituted phenyl)oxiran-2-yl]methanones) have been synthesised by phase transfer catalysed epoxidation of 1-naphthyl chalcones. The yields of oxiranes are more than 95%. The
G. Thirunarayanan
doaj   +1 more source

Predictive Model for Corrosion Inhibition of Mild Steel by Thiophene and Its Derivatives Using Artificial Neural Network

open access: yesInternational Journal of Electrochemical Science, 2012
Corrosion inhibition performance of thiophene and its derivatives were studied using potentiodynamic polarization. The study used the artificial neural network analysis effectively generalized correct responses that broadly resemble the data in the ...
K.F. Khaled, N.A. Al-Mobarak
doaj   +1 more source

The role of pressure anisotropy in the turbulent intracluster medium

open access: yes, 2012
In low-density plasma environments, such as the intracluster medium (ICM), the Larmour frequency is much larger than the ion-ion collision frequency. In such a case, the thermal pressure becomes anisotropic with respect to the magnetic field orientation ...
Barakat A R   +18 more
core   +1 more source

Landau Damping in a Turbulent Setting

open access: yes, 2012
To address the problem of Landau damping in kinetic turbulence, the forcing of the linearized Vlasov equation by a stationary random source is considered.
Frisch U.   +6 more
core   +1 more source

Solvent-free one-pot cyclization and acetylation of chalcones: Synthesis of some 1-acetyl pyrazoles and spectral correlations of 1-(3-(3,4-dimethylphenyl)-5-(substituted phenyl)-4,5-dihydro-1H-pyrazole-1-yl) ethanones

open access: yesJournal of Saudi Chemical Society, 2016
One-pot synthesis of some 1N-acetyl pyrazoles including 1-(3-(3,4-dimethylphenyl)-5-(substituted phenyl)-4,5-dihydro-1H-pyrazole-1-yl) ethanones has been achieved via solvent-free microwave irradiation using substituted chalcones, hydrazine hydrate and ...
G. Thirunarayanan, K.G. Sekar
doaj   +1 more source

Preparation and characterization of protein-nanotube conjugates [PDF]

open access: yes, 2009
This chapter describes methods of immobilizing proteins on carbon nanotubes, using two different routes—physical adsorption and covalent attachment.
Asuri, Prashanth   +8 more
core   +1 more source

Relationship between electrophilicity index, Hammett constant and nucleus-independent chemical shift

open access: yesJournal of Chemical Sciences, 2005
Inter-relationships between the electrophilicity index (Ω), Hammett constant (op@#@) and nucleusindependent chemical shift (NICS (1) — NICS value one angstrom above the ring centre) have been investigated for a series of meta- and para-substituted benzoic acids. Good linear relationships between Hammett constant vs electrophilicity and Hammett constant
M. Elango   +7 more
openaire   +2 more sources

Equilibrium constants and protonation site for N-methylbenzenesulfonamides

open access: yesBeilstein Journal of Organic Chemistry, 2011
The protonation equilibria of four substituted N-methylbenzenesulfonamides, X-MBS: X = 4-MeO (3a), 4-Me (3b), 4-Cl (3c) and 4-NO2 (3d), in aqueous sulfuric acid were studied at 25 °C by UV–vis spectroscopy.
José A. Moreira   +3 more
doaj   +1 more source

Picolinic acid promoted oxidative decarboxylation of phenylsulfinylacetic acid by Cr(VI)

open access: yesBulletin of the Chemical Society of Ethiopia, 2016
The kinetics and mechanism of picolinic acid promoted reaction of phenylsulfinylacetic acid (PSAA) with Cr(VI) was carried out in aqueous acetonitrile medium under pseudo first order conditions. The reaction follows Michaelis-Menten type of kinetics with
P. Subramaniam, N. T. Selvi
doaj   +1 more source

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