Results 81 to 90 of about 9,318 (208)
Ligand architecture and secondary‐sphere effects in a well‐defined cobalt(IV)–oxo complex
A well‐defined cobalt(IV)–oxo complex supported by a neutral tetraazamacrocyclic ligand is generated and fully characterized. The cobalt(IV)–oxo species exhibits electrophilic oxygen‐atom and hydrogen‐atom transfer reactivity, strongly modulated by protonation and secondary coordination sphere effects, providing new insight into structure–reactivity ...
Ying Xing +3 more
wiley +1 more source
Thirteen optically active (αS,βR) 1-naphthyl keto-oxiranes (1-naphthyl-4-yl[3-(substituted phenyl)oxiran-2-yl]methanones) have been synthesised by phase transfer catalysed epoxidation of 1-naphthyl chalcones. The yields of oxiranes are more than 95%. The
G. Thirunarayanan
doaj +1 more source
Corrosion inhibition performance of thiophene and its derivatives were studied using potentiodynamic polarization. The study used the artificial neural network analysis effectively generalized correct responses that broadly resemble the data in the ...
K.F. Khaled, N.A. Al-Mobarak
doaj +1 more source
The role of pressure anisotropy in the turbulent intracluster medium
In low-density plasma environments, such as the intracluster medium (ICM), the Larmour frequency is much larger than the ion-ion collision frequency. In such a case, the thermal pressure becomes anisotropic with respect to the magnetic field orientation ...
Barakat A R +18 more
core +1 more source
Landau Damping in a Turbulent Setting
To address the problem of Landau damping in kinetic turbulence, the forcing of the linearized Vlasov equation by a stationary random source is considered.
Frisch U. +6 more
core +1 more source
One-pot synthesis of some 1N-acetyl pyrazoles including 1-(3-(3,4-dimethylphenyl)-5-(substituted phenyl)-4,5-dihydro-1H-pyrazole-1-yl) ethanones has been achieved via solvent-free microwave irradiation using substituted chalcones, hydrazine hydrate and ...
G. Thirunarayanan, K.G. Sekar
doaj +1 more source
Preparation and characterization of protein-nanotube conjugates [PDF]
This chapter describes methods of immobilizing proteins on carbon nanotubes, using two different routes—physical adsorption and covalent attachment.
Asuri, Prashanth +8 more
core +1 more source
Relationship between electrophilicity index, Hammett constant and nucleus-independent chemical shift
Inter-relationships between the electrophilicity index (Ω), Hammett constant (op@#@) and nucleusindependent chemical shift (NICS (1) — NICS value one angstrom above the ring centre) have been investigated for a series of meta- and para-substituted benzoic acids. Good linear relationships between Hammett constant vs electrophilicity and Hammett constant
M. Elango +7 more
openaire +2 more sources
Equilibrium constants and protonation site for N-methylbenzenesulfonamides
The protonation equilibria of four substituted N-methylbenzenesulfonamides, X-MBS: X = 4-MeO (3a), 4-Me (3b), 4-Cl (3c) and 4-NO2 (3d), in aqueous sulfuric acid were studied at 25 °C by UV–vis spectroscopy.
José A. Moreira +3 more
doaj +1 more source
Picolinic acid promoted oxidative decarboxylation of phenylsulfinylacetic acid by Cr(VI)
The kinetics and mechanism of picolinic acid promoted reaction of phenylsulfinylacetic acid (PSAA) with Cr(VI) was carried out in aqueous acetonitrile medium under pseudo first order conditions. The reaction follows Michaelis-Menten type of kinetics with
P. Subramaniam, N. T. Selvi
doaj +1 more source

