Results 71 to 80 of about 765 (211)

Pretreatment Effects of Conventional and Reactive Extrusion on LLDPE Waste Pyrolysis

Polymer Engineering &Science, EarlyView.
Schematic overview of the pyrolysis study using original and pretreated LLDPE waste samples. Pretreatment was performed via twin‐screw extrusion at 450°C: without additives (REX), with peroxide (REX‐RO2), or with polypropylene (REX–PP). All four samples underwent pyrolysis at 450°C–475°C for 15–45 min.
Yasmin Fialho Siqueira, Débora M. V. Miranda, Larissa L. A. Carvalho, Natasha K. Sitton, Ana Paula de Azeredo, Regina F. Nonemacher, Raquel S. Mauler, Luiz Eduardo P. Borges, José Carlos Pinto   +8 more
wiley   +1 more source

Unsaturated biobased polyesters from bicyclic α‐pinene‐based diols

Polymer International, EarlyView.
We present the synthesis of four biosourced unsaturated polyesters made from chiral terpene‐based diols and esters of renewable diacids. The resulting materials harbor a bicyclic pinene ring in their backbones which leads to enhanced thermal properties while still conferring susceptibility to enzyme hydrolysis for chains having a cis alkene.
Ganapathy Ranjani, Shengwei Sun, Erik Sundén, Diana Bernin, Per‐Olof Syrén   +4 more
wiley   +1 more source

Synthesis of Poly(Itaconate)s With High Monomer Conversion Applying Emulsion Polymerization

Journal of Polymer Science, Volume 63, Issue 6, Page 1284-1296, 15 March 2025.
Itaconic acid and its derivatives are a promising and bio‐based substitute for oil‐based polymers such as acrylates. In this study, the optimization of polymerization of itaconic acid esters is described by applying emulsion polymerization leading to high reaction conversions and low residual monomer contents. ABSTRACT Itaconic acid and its derivatives
S. Charlotte Fischer von Mollard, Nico Ueberschaar, Martin Schreiber, Frank Kamphuis, Stefan Zechel, Martin D. Hager   +5 more
wiley   +1 more source

Synthesis of Carboxyl Terminated Polymyrcene by Anionic Polymerization Using CO2 as a Terminating Agent

Journal of Polymer Science, EarlyView.
The anionic polymerization of myrcene and termination with carbon dioxide to produce carboxyl terminated chains were investigated. The highest degree of functionalization was obtained in the batch reactor by headspace addition of the CO2 to the unstirred reactor at −78°C.
Trishna K. Chengappa, Juan Marin Angel, Kevin A. Cavicchi   +2 more
wiley   +1 more source

Characterization of Structure, Properties, and Energetic Performance of a 1:1 Ammonium Dinitramide‐3,4‐Diaminofurazan Cocrystal

Propellants, Explosives, Pyrotechnics, EarlyView.
Ammonium dinitramide (ADN) and 3,4‐Diaminofurazan (DAF) form a 1:1 energetic cocrystal. We report its crystal structure and spectroscopic signature and evaluate thermal stability, decomposition behavior, hygroscopicity, and combustion properties. Propellant performance calculations benchmark the material against guanylurea dinitramide (GuDN) and ...
Peter Schultz, Uwe Schaller, Thomas Heintz   +2 more
wiley   +1 more source

The continuing significance of chiral agrochemicals

Pest Management Science, Volume 81, Issue 4, Page 1697-1716, April 2025.
In the time frame 2018–2023, around 43% of the 35 chiral agrochemicals introduced to the market (herbicides, fungicides, insecticides, acaricides, and nematicides) contain one or more stereogenic centers in the molecule, and almost 69% of them have been marketed as racemic mixtures of enantiomers or stereoisomers.
Peter Jeschke
wiley   +1 more source

Fluorinated copolymer resists for high‐resolution negative‐tone lithography: Preparation and patterning performance

Smart Molecules, EarlyView.
Electron‐beam induced C–F cleavage in –CF3 generates F−, which abstracts a proton to form the acid that catalyzes tBMA deprotection during post‐exposure baking. This self‐sensitization mechanism enables the precise formation of high‐resolution negative‐tone patterns with enhanced sensitivity and resolution.
Yuting Tang, Wenzheng Li, Xinyan Huang, Min Zhang, Han Han, Jialong Zhang, Qinyu Luo, Jiangli Fan, Pengzhong Chen, Xiaojun Peng   +9 more
wiley   +1 more source

Perfluorohexanone for Clean Fire Suppression: Mechanisms, System Design, Applications, and Future Directions

Safety Science and Technology, EarlyView.
Driven by halon and high GWP agent phase out, perfluorohexanone is increasingly deployed in enclosures such as data centers, marine machinery spaces, and industrial process lines. This review summarizes application performance, discharge and distribution design, material compatibility, and byproduct control and maps practical gaps for large volume and ...
Zhilei Yu, Haibin Dong, Yanfeng Sheng, Xuelei Xian, Dehua Zhang, Feiran Li, Liang Liu, Junchao Zhao, Heping Zhang   +8 more
wiley   +1 more source

Photochemical Intermolecular [3σ + 2σ]-Cycloaddition for the Construction of Aminobicyclo[3.1.1]heptanes. [PDF]

J Am Chem Soc, 2022
Zheng Y, Huang W, Dhungana RK, Granados A, Keess S, Makvandi M, Molander GA.   +6 more
europepmc   +1 more source

Polar Lipid and Fatty Acid Profiles of Oat Groats Substantially Influenced by Field Management: A Comparison of Cultivars, Sowing Times and Fertilizer Composition

Plant, Cell &Environment, EarlyView.
ABSTRACT The polar lipids in oat grains are crucial due to their biological functions, nutritional quality, potential use in food flavour and processing, the protection they provide against biotic and abiotic stresses, and their ability to act as cellular signalling molecules.
Syed Rehmat Ullah Shah, Lena Engström, Carl Grey, Anders Jonsson, Johanna Wetterlind, Cecilia Tullberg   +5 more
wiley   +1 more source