Results 51 to 60 of about 925,488 (170)
This review reveals how electronic configuration engineering governs the entire electrocatalytic nitrogen cycle, providing structure‐informed insights into reaction selectivity, catalytic durability, and sustainable nitrogen utilization across energy and environmental systems. ABSTRACT The global nitrogen cycle is essential to food production, chemical
Jiamu Feng +7 more
wiley +1 more source
Three tetracyanide-containing building blocks K2[M(CN)4] (M = Ni, Pd, Pt) and one semi-closed macrocycle seven-coordinated manganese(II) compound have been employed to assemble cyanide-bridged heterometallic complexes, resulting in three cyanide-bridged ...
Jingwen Shi +3 more
doaj +1 more source
Six new complexes [Cd(tpy)(pfb)2] (1, tpy = 2,2′:6′,2″-terpyridine), [Ln2Cd2(tpy)2(pfb)10] (Ln = Eu (2Eu), Tb (2Tb)), [Ln2Cd2(tbtpy)2(pfb)10]·2MeCN (Ln = Eu (3Eu), Tb (3Tb), tbtpy = 4,4′,4″-tri-tert-butyl-2,2′:6′,2″-terpyridine), [Eu2Cd2(tppz)(pfb)10]n ...
Maxim A. Shmelev +8 more
doaj +1 more source
Heterovalent, Homometallic Rings: Synthesis, Optical, and EPR Studies of {TiIV7TiIII} Complexes
A new class of heterovalent, homometallic complexes is reported, based on cyclic {TiIV7TiIII} cores with oxide and carboxylate bridges between nearest neighbors. The clusters show Class II mixed‐valent behavior at room temperature, but are valence localized at low temperature.
Selena J. Lockyer +8 more
wiley +1 more source
The present work provides a brief summary review of the chemistry of luminescent gold(I) alkynyls and their ability to form heterometallic complexes. A series of luminescent heterometallic gold(I)-rhenium(I) alkynyl complexes has been synthesized and ...
Cheung, KL, Yip, SK, Yam, VWW
core +1 more source
White Phosphorus Activation with Cobalt–Zinc Complexes: Access to Phosphorus‐Rich Sandwich Compounds
The utilization of two electronically distinct elements for the cooperative activation of white phosphorus (P4) is a promising route to novel and reactive polyphosphido complexes.
Marco D. Fritz +3 more
doaj +1 more source
SYNTHESIS AND PHYSICO-CHEMICAL STUDIES OF HETEROMETALLIC NITRILOTRIACETATES OF CHROMIUM(III) WITH SOME 3d METALS [PDF]
Heterometallic complexes of chromium (III) with some 3d metals have been synthesized based on nitrilotriacetic acid (H3nta), like M(bpy)2Cr2(OH)2(nta)2·nH2O, where M = Mn2+, Co2+, Ni2+ and Zn2+; bpy = α,α′- bipyridine; n = 8 or 9.
Victor Ciorne, Aurelian Gulea
doaj
This review covers 90 heterodimeric Pt complexes with non-transition metals. There are 13 non-transition metals (Ge, Sn, Pb, Ga, In, Tl, Sb, Zn, Cd, Hg, Na, K and Ca).
Melník Milan, Mikuš Peter
doaj +1 more source
Hexakis(dimethylformamide-κO)manganese(II) μ-oxido-bis[trichloridoferrate(III)]
The title compound, [Mn(C3H7NO)6][Fe2Cl6O], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes with Schiff base ligands using manganese powder and FeCl3·6H2O as starting materials.
Eduard N. Chygorin +5 more
doaj +1 more source
A Cyclic {NiII8DyIII4} Cluster Where the DyIII Moments Are Organized by the Transition Metal Spins
The synthesis, structural characterisation, and magnetic properties of a cyclic Ni8Dy4 coordination cluster are reported. Ab initio CASSCF and DFT calculations help rationalize the shape of the microSQUID hysteresis and the competing magnetic interactions within the compound. ABSTRACT A series of [Ni8Ln4(CO3)4(L)8(NO3)2(H2O)8 (MeOH)4](NO3)2 (Ln = Dy (1)
Imon J. Dutta +7 more
wiley +1 more source

