Results 61 to 70 of about 925,488 (170)

Diamond-Shaped Heterometallic Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups

, 2016
Diamond-Shaped Heterometallic Complexes of Iron(II) and Copper(I) Bridged by Cyanide ...
M. Jason Adams (2729965), Donald J. Darensbourg (1317624), Way-Zen Lee (1329498), Joseph H. Reibenspies (1407388), David L. Larkins (2962854)   +4 more
core   +2 more sources

Structural characterization of heterometallic platinum complexes with non-transition metals. Part II: heterotrimeric complexes

Main Group Metal Chemistry, 2013
We analyzed and classified almost 100 heterotrimers of platinum with non-transition metals of the composition Pt2M (42 examples), PtM2 (48 examples), and PtMM' (6 examples). These trimers crystallized in five crystal classes: rhombohedral and tetragonal,
Melník Milan, Mikuš Peter
doaj   +1 more source

Two binuclear cyanide-bridged Cr(III)-Mn(III) complexes based-on [Cr(2,2’-bipy)(CN)4]- building block: synthesis, crystal structures and magnetic properties

Acta Chimica Slovenica, 2015
Tetracyanide building block [Cr(2,2’-bipy)(CN)4]- and two bicompartimental Schiff-base based manganese(III) compounds have been employed to assemble cyanide-bridged heterometallic complexes, resulting in two cyanide-bridged CrIII-MnIII complexes: [Mn(L1)(
Daopeng Zhang, Lingqian Kong, Hongyan Zhang   +2 more
doaj   +1 more source

Scaling Up Molecular Electron Spin Qubits Around a Core‐Shell Quantum Dot

Chemistry – A European Journal, EarlyView.
Making assemblies of molecular nanomagnet (MNM) qubits is an essential step toward scalable quantum devices. Here, SH‐functionalized {Cr7Ni} antiferromagnetic rings with ability as MNM qubits were successfully grafted to the surface of fluorescent CdSe/ZnS quantum dots (QD).
Simon G. McAdams, Jesus Ferrando‐Soria, Paul D. McNaughter, Edward A. Lewis, Sarah J. Haigh, David J. Lewis, Richard E. P. Winpenny, Paul O'Brien, Floriana Tuna   +8 more
wiley   +1 more source

Hexakis(dimethylformamide-κO)manganese(II) (dimethylformamide-κO)pentakis(thiocyanato-κN)chromate(III)

Acta Crystallographica Section E, 2012
The title compound, [Mn(C3H7NO)6][Cr(NCS)5(C3H7NO)], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes based on Reineckes anion using manganese powder, Reineckes salt and 1-(2-hydroxyethyl)tetrazole as ...
Valentyna V. Semenaka, Oksana V. Nesterova, Vladimir N. Kokozay, Irina V. Omelchenko, Oleg V. Shishkin   +4 more
doaj   +1 more source

Large Magnetocaloric Effect in a Ferromagnetically Coupled [Mn3Gd] Complex With a Spin Ground State of S = 11

Chemistry – A European Journal, EarlyView.
Systematic studies of a series of new 3d–4f tetranuclear complexes revealed that the ferromagnetically coupled [Mn3Gd] complex exhibits large magnetic entropy changes, especially at higher temperatures and under lower magnetic fields. ABSTRACT A series of 3d‐4f heterometallic tetranuclear complexes, (TEA)[Mn3Gd(L)3(NO3)4(CH3CN)2] ([Mn3Gd]), (TEA)[Mn3La(
Takuya Shiga, Haruka Miyamoto, Honami Ito, Yukiko Okamoto, Hiroki Oshio, Nozomi Mihara, Masayuki Nihei   +6 more
wiley   +1 more source

Heterogeneous Single/Dual‐Atom Electrocatalysts in Lithium–Sulfur Batteries

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review summarizes recent advances in single‐atom and dual‐atom electrocatalysts for high‐performance lithium–sulfur batteries. The text systematically covers the classification of catalysts by active metal centers, key synthesis methods, in situ characterization for mechanistic insights, and electrocatalytic mechanisms.
Wenbin Li, Ying Xin, Zhaoliang Zhang, Jin Wang   +3 more
wiley   +1 more source

Synthesis, Updated Characterization, and Reactivity of Low‐Valent Titanocene Complexes

European Journal of Inorganic Chemistry, EarlyView.
Syntheses and characterizations are provided for a series of low‐valent titanocene complexes including halotitanocene(III) dimers, [Cp2Ti(κ2‐DME)][BAr4] cations, and heterobimetallic [Cp2Ti(μ‐Cl)2AlR2]. Additionally, a monomeric titanacyclopropene complex featuring a pendent phosphine was prepared, and C─F bond activation upon reduction of [Cp{η5:κ2F2 ...
Griffin J. LaChapelle, James F. Britten, David J. H. Emslie   +2 more
wiley   +1 more source

Heterometallic iron and iridium nitrido complexes

, 2022
The nitrido group (N3-) is a strong π donor ligand that can stabilize metal ions in high oxidation states. Recent studies have shown that diiron μ-nitrido phthalocyanine complexes can catalyze the oxidation of hydrocarbons, including methane, with ...
Ng, Rain
core  

Modulating Local Coordination in Single‐Atom Catalysts: From Fundamental Concepts to Emerging Breakthroughs in Electrocatalysis

Angewandte Chemie, Volume 138, Issue 40, 28 September 2026.
This review summarizes atomic‐level design strategies for single‐atom catalysts, emphasizing modulation of the local coordination environment, active‐site geometry, and metal‐support interactions to optimize catalytic activity and stability in electrocatalytic energy conversion applications.
Ashwani Kumar, Harun Tüysüz
wiley   +2 more sources