Results 91 to 100 of about 15,108 (284)

Enantioselective homogeneous catalysts for the synthesis of fluorinated organic compounds

open access: yes, 2012
This thesis is divided into three main results chapters that reflect the path my research took. In the first results chapter, the first organocatalyst for the carbonyl-ene reaction was discovered and found to give high conversion using 1,3-bis(3,5-bis ...
Jones, Charlotte E. S.
core  

Sensitive and Spatially‐Resolved Electrochemiluminescence via Micropatterning

open access: yesAdvanced Materials Interfaces, EarlyView.
The use of a simple silica nanoparticle surface coating and patterning process can transform ordinary gold electrodes into multiplexed ECL sensing electrodes. Through spatially confined droplet formation and local ECL emission, it is possible to perform multiple analyses simultaneously from individual locations as well as intensify the ECL signal by as
Yuliang Shao   +12 more
wiley   +1 more source

Facile access to bicyclo[2.1.1]hexanes by Lewis acid-catalyzed formal cycloaddition between silyl enol ethers and bicyclo[1.1.0]butanes

open access: yesNature Communications
Saturated three-dimensional carbocycles have gained increasing prominence in synthetic and medicinal chemistry. In particular, bicyclo[2.1.1]hexanes (BCHs) have been identified as the molecular replacement for benzenes.
Sai Hu, Yuming Pan, Dongshun Ni, Li Deng
doaj   +1 more source

Hexanes as Deterrents in Tribolium [PDF]

open access: yes, 2017
Citation: Hamblin, M. (2017). Hexanes as Deterrents in Tribolium . 1st Annual Undergraduate Research Experience in Entomology Symposium, November 16, 2016.
Hamblin, Matt, Phillips, Thomas W.
core  

Facet‐Specific PbS Quantum Dot Passivation Using Halide Perovskites for SWIR Photodetectors

open access: yesAdvanced Materials Interfaces, EarlyView.
PbS quantum dots (QDs) are emerging as powerful short‐wave infrared photodetectors, yet the passivation mechanism of large QDs by perovskites ‐ critical for their stability ‐ remains unexplained. Here, we unveil the ligand structure of CH3NH3PbI3 (MAPI)‐passivated 4‐nm PbS QDs using FTIR, XPS, SEM, NMR, and DFT.
L. Paillardet   +13 more
wiley   +1 more source

Two‐Way Shape Memory Polymer Composite Gripper for Adaptive Robotic Applications

open access: yesAdvanced Materials Technologies, EarlyView.
A two‐way shape memory polymer (SMP) composite is developed with intrinsic shape‐changing capability driven solely by temperature, eliminating external actuation loads. Embedding the SMP in a low‐stiffness elastomeric matrix enabled reversible transformations during heating and cooling cycles.
Aamna Hameed, Kamran Ahmed Khan
wiley   +1 more source

Organocatalytic enantioselective [2π + 2σ] cycloaddition reactions of bicyclo[1.1.0]butanes with α,β-unsaturated aldehydes

open access: yesNature Communications
Bicyclo[2.1.1]hexanes (BCHs), three-dimensional benzene bioisosteres characterized by high sp3-carbon content, hold great promise for diverse applications in medicinal chemistry.
Yi-Xiang Geng   +6 more
doaj   +1 more source

Additively Manufactured Porous Ceramics as Tunable Dielectrics for Passive Temperature Sensing

open access: yesAdvanced Materials Technologies, EarlyView.
Porous ceramic lattices, 3D‐printed from a multicomponent oxide ink, are integrated with LC resonators for passive wireless temperature sensing. By tuning porosity, the dielectric properties and RF response are engineered to produce distinct resonant frequency shifts with temperature. The results establish a structure‐driven approach to customizing the
Sogol Heidarishahrivar   +5 more
wiley   +1 more source

Crystal structure, computational study, and Hirshfeld analysis of exo-1,2,3,5-tetraphenyl-1a',9b'-dihydrospiro[bicyclo[3.1.0]hexane-6,1′-cyclopropa[l]phenanthren]-2-en-4-one

open access: yesActa Crystallographica Section E: Crystallographic Communications
The reaction of dibenzonorcarynyliden(e/oid) with phencyclone was recently reported to give a congested spiropentane with endo stereochemistry. Herein we report that, in sharp contrast, an analogous reaction using tetracyclone, instead of phencyclone ...
Alexander D. Roth, Dasan M. Thamattoor
doaj   +1 more source

UJI ANTIOKSIDAN EKSTRAK HEKSANA, ETIL ASETAT, ETANOL, METANOL 80% DAN AIR DAUN KELOR (Moringa oleifera, Lamk)

open access: yesSains Natural, 2017
Antioxidant Test of  Hexane, Etil Asetat, Ethanol, Methanol 80% and   Water Extract in Moringa oleifera            Antioxidant is a substance that can protect a materials from its destruction.
Agung Abadi Kiswandono, Mamay Maslahat
doaj   +1 more source

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