Results 91 to 100 of about 15,609 (285)

Radical asymmetric intramolecular α-cyclopropanation of aldehydes towards bicyclo[3.1.0]hexanes containing vicinal all-carbon quaternary stereocenters

Nature Communications, 2018
Synthesis of cyclopropanes bearing vicinal all-carbon quaternary stereocenters poses synthetic challenges. Here, the authors report an intramolecular radical cyclopropanation with a copper/amine cooperative catalytic system for the efficient construction
Liu Ye, Qiang-Shuai Gu, Yu Tian, Xiang Meng, Guo-Cong Chen, Xin-Yuan Liu   +5 more
doaj   +1 more source

Additively Manufactured Porous Ceramics as Tunable Dielectrics for Passive Temperature Sensing

Advanced Materials Technologies, EarlyView.
Porous ceramic lattices, 3D‐printed from a multicomponent oxide ink, are integrated with LC resonators for passive wireless temperature sensing. By tuning porosity, the dielectric properties and RF response are engineered to produce distinct resonant frequency shifts with temperature. The results establish a structure‐driven approach to customizing the
Sogol Heidarishahrivar, Aminul Islam, Chang Woo Gal, Insup Kim, Yeong‐Jin Choi, Woo Soo Kim   +5 more
wiley   +1 more source

Antioxidant potential of rice bran oil prepared from red and white rice

Tropical Agricultural Research, 2015
The focus of the present study was to determine the total phenolic content (TPC) and antioxidant potential of Rice Bran Oil (RBO). The bran of two rice varieties was obtained and stabilized and subsequently RBO was extracted into hexanes.
Dilini Bopitiya, Terrence Madhujith
doaj   +1 more source

Turning Water Into a Tool: From Degradation Pathways to Functional Engineering in Halide Perovskites

Advanced Materials Technologies, EarlyView.
Water exhibits a threshold‐dependent dual role in lead halide perovskites, acting either as a degradation trigger or as a powerful tool for defect passivation, recrystallization, and structural engineering. This review discusses how controlled water‐mediated interactions govern stability, dimensionality, and optoelectronic performance, providing ...
Raphaella T. S. Gonçalves, Gabriela O. Gera, Aryane Tofanello, Jose A. Souza, Andre L. M. Freitas   +4 more
wiley   +1 more source

Revealing Mechanofluorochromism and Intricate Long‐lived Decay Pathways in Keto‐Coumarin‐Based Molecular Crystals

Advanced Optical Materials, EarlyView.
Donor–acceptor organic emissive materials show great promise in cutting‐edge optical applications. Herein, the photophysical properties of two keto‐coumarin organic materials are studied in detail. Both show mechanofluorochromism, but a diphenylamine donor derivative exhibits intricate decay pathways in the crystal form, including decays ranging from ...
Peter W. McDonald, Subhadeep Das, Arnab Mandal, Gilles Clavier, Clémence Allain, Abhijit Patra, Rémi Métivier   +6 more
wiley   +1 more source

Organocatalytic enantioselective [2π + 2σ] cycloaddition reactions of bicyclo[1.1.0]butanes with α,β-unsaturated aldehydes

Nature Communications
Bicyclo[2.1.1]hexanes (BCHs), three-dimensional benzene bioisosteres characterized by high sp3-carbon content, hold great promise for diverse applications in medicinal chemistry.
Yi-Xiang Geng, Teng-Fei Xiao, Dong Xie, Ming-Ming Li, Pan-Pan Zhou, Guo-Qiang Xu, Peng-Fei Xu   +6 more
doaj   +1 more source

Halide Defect Passivation in CsPbBr3 Nanocrystals Mediated by the Friedel–Crafts Reaction: Enhanced PLQY and Structural Stability Without Bandgap Modulation

Advanced Optical Materials, EarlyView.
Post‐treatment of CsPbBr3 nanocrystals with an AlBr3/CH2Br2 solution does not induce Al3+ substitution at Pb2+ sites. Instead, a Friedel–Crafts reaction generates Br− ions that passivate halide defects, markedly increasing PLQY and improving structural stability without bandgap modulation.
Hyunsoo Oh, Dokyum Kim, Sang‐Youp Yim, Ha Sul Kim, Chang‐Lyoul Lee   +4 more
wiley   +1 more source

In Situ Photopolymerization of Smectic B Liquid‐Crystalline Electrolytes from Mesogenic Phosphate–Diacrylate/Ionic Liquid Complexes for High‐Performance Soft Ionic Actuators

Advanced Robotics Research, EarlyView.
A flexible liquid‐crystalline electrolyte membrane via in situ photopolymerization of a phosphate‐functionalized mesogen, ionic liquid, and diacrylate monomer is developed. The resulting smectic B (SmB)‐phase structure enables 2D ion transport with high conductivity (10−4 S cm−1).
Chengyang Liu, Masafumi Yoshio
wiley   +1 more source

Facile access to bicyclo[2.1.1]hexanes by Lewis acid-catalyzed formal cycloaddition between silyl enol ethers and bicyclo[1.1.0]butanes

Nature Communications
Saturated three-dimensional carbocycles have gained increasing prominence in synthetic and medicinal chemistry. In particular, bicyclo[2.1.1]hexanes (BCHs) have been identified as the molecular replacement for benzenes.
Sai Hu, Yuming Pan, Dongshun Ni, Li Deng
doaj   +1 more source

UJI ANTIOKSIDAN EKSTRAK HEKSANA, ETIL ASETAT, ETANOL, METANOL 80% DAN AIR DAUN KELOR (Moringa oleifera, Lamk)

Sains Natural, 2017
Antioxidant Test of  Hexane, Etil Asetat, Ethanol, Methanol 80% and   Water Extract in Moringa oleifera            Antioxidant is a substance that can protect a materials from its destruction.
Agung Abadi Kiswandono, Mamay Maslahat
doaj   +1 more source