Dehydrative formation and biological evaluation of allylic sulfonamides from allylic alcohols using recyclable silica-supported acid catalysts. [PDF]
RSC AdvBrandeburg ZC +8 more
europepmc +1 more source
Synthesis of functionalized polyolefins in a new continuous bench‐scale reactor apparatus
AIChE Journal, EarlyView.Abstract In‐reactor functionalized polyolefins (FPOs), produced by molecular catalysts, are a new class of polymer materials with applications ranging from high performance adhesives to bitumen compatibilization. In this work, we disclose a procedure for the synthesis of FPOs in a new Continuous Bench‐scale Reactor Apparatus (COBRA).
Miloud Bouyahyi +7 more
wiley +1 more source
Formation of Gallium Monofluoride in the Coordination Sphere of Nickel
Angewandte Chemie, EarlyView.The elusive gas‐phase species gallium monofluoride forms selectively in the coordination sphere of a nickel(II) centre as a product of C(sp3)–F bond activation, with a weakly coordinating anion as the fluorine source. The herein reported gallium monofluoride ligand acts as a very strong σ‐donor ligand at nickel and serves as a fluorine donor towards ...
Johannes Stephan +6 more
wiley +2 more sources
Structural Tuning of Inefficient <i>C</i> <sub>1</sub>‑Symmetric Iodoarene for Efficient Enantioselective Oxidative Organocatalysis. [PDF]
ACS OmegaPavankumar K +4 more
europepmc +1 more source
Advancements in Graphdiyne‐Based Multiscale Catalysts for Green Hydrogen Energy Conversion
Advanced Intelligent Discovery, EarlyView.This review systematically explores the fundamental characteristics of graphdiyne (GDY), cutting‐edge field of GDY‐based multiscale catalysts within sustainable energy conversion systems.Special emphasis is placed on the structure‒property relationships in different reactions.
Qian Xiao, Lu Qi, Siao Chen, Yurui Xue
wiley +1 more source
Angewandte Chemie, EarlyView.This work reports a new metal–ester bonding strategy for anchoring molecular catalysts to metal oxide supports, achieving exceptionally high surface loadings. Catalyst reactivity is predictably tuned by the support's properties, enabling control over electronic behavior and reaction pathways, thus opening new possibilities for designing highly ...
Joseph J. Kuchta III +7 more
wiley +2 more sources
From Discovery to Clinical Trial: YCT-529, an Oral NonHormonal Male Contraceptive Targeting the Retinoic Acid Receptor Alpha. [PDF]
J Med ChemShi R +12 more
europepmc +1 more source
Smart Bioinspired Material‐Based Actuators: Current Challenges and Prospects
Advanced Intelligent Systems, Volume 7, Issue 3, March 2025.This work gathers, in a review style, an extensive and comprehensive literature overview on the development of autonomous actuators based on synthetic materials, bringing together valuable knowledge from several studies. Furthermore, the article identifies the fundamental principles of actuation mechanisms and defines key parameters to address the size
Alejandro Palacios +4 more
wiley +1 more source
Catalytic Hydrophosphorylation of Propiolates and Three-Component Phosphorylation of Aldehydes. [PDF]
J Org ChemDelgado-Hernández S +5 more
europepmc +1 more source
Angewandte Chemie, EarlyView.Using a ketal‐protected glycerol derivative (solketal) as the oxidation substrate enables site‐selective electrooxidation that suppresses C–C cleavage on non‐noble catalysts. Highly alkaline conditions promote reactive solketal alkoxide formation, weaken the Cα─H bond to facilitate dehydrogenation, and buffer local acidification, enabling a record‐high
Jiamin Wang +6 more
wiley +2 more sources