Lewis Acid-Catalyzed Cascade Ring Expansion and Intramolecular Friedel-Crafts Type Cyclization of α-Dithioacetyl Propargyl Alcohols: Access to <i>S</i>,<i>S</i>-Heterocycle-Fused Benzofulvenes and 3-Benzylidene-1-indanones. [PDF]
Turhan YE +10 more
europepmc +1 more source
A highly electron‑accepting derivative of cyclobisbiphenylenecarbonyl (CBBC‐TIC) is reported. CBBC‐TIC functions as an electron‐transport layer for perovskite solar cells, achieving a power conversion efficiency of 20.6%. Furthermore, the enantiomers of CBBC‐TIC exhibited spin‐selective electron transport with high enantiospecific magnetic conductance ...
Yuki Sakamoto +15 more
wiley +1 more source
Docking-Based Virtual Screening Identifies a Small-Molecule Inhibitor of the Translesion Synthesis REV7/REV3 Protein-Protein Interaction. [PDF]
Harrahill NJ +10 more
europepmc +1 more source
TADF‐Active Tetrazole Luminophores for Visible‐Light Functionalization of Nanoparticles and Surfaces
A series of tetrazoles are reported that undergo 1,3‐dipolar cycloadditions with alkene and alkyne substrates, generating (dihydro)pyrazole products that exhibit thermally activated delayed fluorescence (TADF). The “photo‐click” reactivity of these tetrazoles is leveraged to functionalize nanoparticles and surfaces with TADF‐active chromophores ...
Ryoga Hojo +11 more
wiley +1 more source
Photooxidative Molecular Rearrangement of Vouacapane Diterpenes Generates Proapoptotic Spirocaesalmins. [PDF]
Hernández-Padilla L +11 more
europepmc +1 more source
σ‐Decoupled C9 fluorene‐framework topology control enables narrowband red MR emitters. SF‐BNO and PF‐BNO share the same BNO core, but differ in closed/open fluorene ring closure. SF‐BNO improves steric shielding and stability, while PF‐BNO enhances PLQY, orientation, and efficiency. Ex‐PSF and TE‐OLED architectures deliver ultra‐low efficiency roll‐off
Aradhya Rajput +7 more
wiley +1 more source
Nitrosonium Ion-Catalyzed Oxidative Chlorination of Arenes. [PDF]
Hsu JC, Chen YS, Hsiao CH, Hou DR.
europepmc +1 more source
Large-Scale Amino-Hydroxylation Using Tethered Nitreniums. [PDF]
Sathyamoorthi S.
europepmc +1 more source
Unified Synthesis of Unconventional α‐Polyhalogenated Amines Through Hydroaminoalkylation
A unified, redox‐neutral method that transforms alkenes and alkynes into α‐polyhalomethyl amines using stable hemiaminal reagents is reported. This approach enables access to CF3, CF2H, CF2Cl, and CFClH motifs, expanding halogenated amine space with broad substrate scope, functional group tolerance, and applicability to late‐stage modification of drug ...
Angela K. Hofmeister +9 more
wiley +1 more source
Reactions of diazoboranes with oxygen enables the synthesis and isolation of dioxaboriranes. [PDF]
Zhang C +5 more
europepmc +1 more source

