Results 21 to 30 of about 47,943 (325)

[μ-1,3-Dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κ2N,C2:κ2C2,N′]bis[(1,3-diphenylpropane-1,3-dionato-κ2O,O′)palladium(II)](Pd—Pd)

open access: yesActa Crystallographica Section E, 2011
The title compound, [Pd2(C13H8N2O2)(C15H11O2)2], crystallized from a mixture of ethanol and n-hexanes. The structure is the first example of β-diketonate in a dianionic κ2C-coordination complex containing a PdII—PdII bond ...
Simona Maggini, Peter S. White
doaj   +1 more source

Isolating High Antimicrobial Ability Lignin From Bamboo Kraft Lignin by Organosolv Fractionation

open access: yesFrontiers in Bioengineering and Biotechnology, 2021
Lignin from different biomasses possess biological antioxidation and antimicrobial activities, which depend on the number of functional groups and the molecular weight of lignin.
Jinyan Yun   +9 more
doaj   +1 more source

Alkoxyallene‐Based LANCA Three‐Component Synthesis of 1,2‐Diketones, Quinoxalines, and Unique Isoindenone Dimers and a Computational Study of the Isoindenone Dimerization [PDF]

open access: yes, 2020
A series of β‐alkoxy‐β‐ketoenamides was prepared by the well‐established LANCA three‐component reaction of lithiated 1‐(2‐trimethylsilylethoxy)‐substituted allenes, nitriles, and α,β‐unsaturated carboxylic acids.
Bera M. K.   +6 more
core   +1 more source

Synthesis of Simplified Azasordarin Analogs as Potential Antifungal Agents [PDF]

open access: yes, 2019
A new series of simplified azasordarin analogs was synthesized using as key steps a Diels–Alder reaction to generate a highly substituted bicyclo[2.2.1]heptane core, followed by a subsequent nitrile alkylation.
Dockendorff, Chris, Wu, Yibiao
core   +4 more sources

Hydrogenative Cyclopropanation and Hydrogenative Metathesis

open access: yes, 2019
The unusual geminal hydrogenation of a propargyl alcohol derivative with [CpXRuCl] as the catalyst entails formation of pianostool ruthenium carbenes in the first place; these reactive intermediates can be intercepted with tethered alkenes to give either
Biberger, T.   +3 more
core   +1 more source

Hexane-1,6-diammonium dinitrate [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2009
The hexane-1,6-diammonium cation of the title compound, C(6)H(18)N(2) (2+)·2NO(3) (-), lies across a crystallographic inversion centre and shows significant deviation from planarity in the hydro-carbon chain. This is evident from the torsion angle of -64.0°(2) along the N-C-C-C bond and thse torsion angle of -67.1°(2) along the C-C-C-C bonds.
Gert J. Kruger, Charmaine van Blerk
openaire   +3 more sources

SPECTRUM AND KINETICS OF DIBROMDIBENZOTIOFEN PHOSPHORESCENCE IN N-HEXANES AT 77 K

open access: yesНаука. Инновации. Технологии, 2022
Spectrum and kinetics of dibromdibenzotiofen phosphorescence in n- hexanes at 77 K have been studied. It has been shown that the visible multiplet structure of phosphorescence spectrum is determined of the superposition of spectra emitted by different ...
Natal’ya Vladimirovna Zhdanova   +1 more
doaj  

Diastereoselective Spiroannulation of Phenolic Substrates: Advances Towards the Asymmetric Formation of the Manumycin m-C7N Core Skeleton

open access: yesMolecules, 2007
The asymmetric syntheses of two new spirolactones prepared in optically pure form from L-3-nitrotyrosine are described. The key step, an oxidative spiroannulation, was carried out on the optically active phenols 11a and 11b and afforded the new ...
Thomas W. Scully   +3 more
doaj   +1 more source

4,4′-(Hexane-1,6-diyldioxy)dianiline [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2009
The complete molecule of the title compound, C(18)H(24)N(2)O(2), is generated by a crystallographic inversion centre. The torsion angles in the hexa-methyl-ene chain are consistent with an anti-periplanar conformation, whereas the conformation of the O-CH(2)-CH(2)-CH(2) unit is gauche.
Khan, Muhammad Saif Ullah   +4 more
openaire   +4 more sources

Remote functionalization by tandem radical chain reactions [PDF]

open access: yes, 1997
Normal radical relay chlorination of cholestan-3α-ol directed by an attached m-iodobenzoate ester group affords a 9α-chloro steroid, but when the same reaction is conducted in the presence of an excess of CBr4 the product is a 9α-bromo steroid ...
Wiedenfeld, David
core   +1 more source

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