Results 21 to 30 of about 47,943 (325)
The title compound, [Pd2(C13H8N2O2)(C15H11O2)2], crystallized from a mixture of ethanol and n-hexanes. The structure is the first example of β-diketonate in a dianionic κ2C-coordination complex containing a PdII—PdII bond ...
Simona Maggini, Peter S. White
doaj +1 more source
Isolating High Antimicrobial Ability Lignin From Bamboo Kraft Lignin by Organosolv Fractionation
Lignin from different biomasses possess biological antioxidation and antimicrobial activities, which depend on the number of functional groups and the molecular weight of lignin.
Jinyan Yun +9 more
doaj +1 more source
Alkoxyallene‐Based LANCA Three‐Component Synthesis of 1,2‐Diketones, Quinoxalines, and Unique Isoindenone Dimers and a Computational Study of the Isoindenone Dimerization [PDF]
A series of β‐alkoxy‐β‐ketoenamides was prepared by the well‐established LANCA three‐component reaction of lithiated 1‐(2‐trimethylsilylethoxy)‐substituted allenes, nitriles, and α,β‐unsaturated carboxylic acids.
Bera M. K. +6 more
core +1 more source
Synthesis of Simplified Azasordarin Analogs as Potential Antifungal Agents [PDF]
A new series of simplified azasordarin analogs was synthesized using as key steps a Diels–Alder reaction to generate a highly substituted bicyclo[2.2.1]heptane core, followed by a subsequent nitrile alkylation.
Dockendorff, Chris, Wu, Yibiao
core +4 more sources
Hydrogenative Cyclopropanation and Hydrogenative Metathesis
The unusual geminal hydrogenation of a propargyl alcohol derivative with [CpXRuCl] as the catalyst entails formation of pianostool ruthenium carbenes in the first place; these reactive intermediates can be intercepted with tethered alkenes to give either
Biberger, T. +3 more
core +1 more source
Hexane-1,6-diammonium dinitrate [PDF]
The hexane-1,6-diammonium cation of the title compound, C(6)H(18)N(2) (2+)·2NO(3) (-), lies across a crystallographic inversion centre and shows significant deviation from planarity in the hydro-carbon chain. This is evident from the torsion angle of -64.0°(2) along the N-C-C-C bond and thse torsion angle of -67.1°(2) along the C-C-C-C bonds.
Gert J. Kruger, Charmaine van Blerk
openaire +3 more sources
SPECTRUM AND KINETICS OF DIBROMDIBENZOTIOFEN PHOSPHORESCENCE IN N-HEXANES AT 77 K
Spectrum and kinetics of dibromdibenzotiofen phosphorescence in n- hexanes at 77 K have been studied. It has been shown that the visible multiplet structure of phosphorescence spectrum is determined of the superposition of spectra emitted by different ...
Natal’ya Vladimirovna Zhdanova +1 more
doaj
The asymmetric syntheses of two new spirolactones prepared in optically pure form from L-3-nitrotyrosine are described. The key step, an oxidative spiroannulation, was carried out on the optically active phenols 11a and 11b and afforded the new ...
Thomas W. Scully +3 more
doaj +1 more source
4,4′-(Hexane-1,6-diyldioxy)dianiline [PDF]
The complete molecule of the title compound, C(18)H(24)N(2)O(2), is generated by a crystallographic inversion centre. The torsion angles in the hexa-methyl-ene chain are consistent with an anti-periplanar conformation, whereas the conformation of the O-CH(2)-CH(2)-CH(2) unit is gauche.
Khan, Muhammad Saif Ullah +4 more
openaire +4 more sources
Remote functionalization by tandem radical chain reactions [PDF]
Normal radical relay chlorination of cholestan-3α-ol directed by an attached m-iodobenzoate ester group affords a 9α-chloro steroid, but when the same reaction is conducted in the presence of an excess of CBr4 the product is a 9α-bromo steroid ...
Wiedenfeld, David
core +1 more source

