Results 201 to 210 of about 24,206 (306)

Ultra‐Low‐Strain Calcium and Magnesium Ion Storage Enabled by Tunnel‐Structured MoO3 Positive Electrode

open access: yesAdvanced Energy Materials, EarlyView.
A hexagonal tunnel‐structured MoO3 is nanoparticulated via hydrothermal synthesis followed by ball‐milling. As a positive electrode in Ca and Mg batteries, it delivers superior capacity and structural reversibility, enabling divalent cation intercalation with minimal lattice distortion and no phase transitions.
Reona Iimura   +10 more
wiley   +1 more source

Unveiling the High‐Voltage Reactivity and Gas Evolution With Aluminum‐Based Chloride and Oxychloride Catholytes in Solid‐State Sodium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
The work examines the electrochemical and interfacial behaviors of crystalline NaAlCl4 and amorphous Na–Al–oxychloride solid electrolytes with NaNi0.5Mn0.5O2 cathodes. Operando gas evolution and ToF‐SIMS analyses highlight that pure chloride solid electrolytes offer greater interfacial stability and safety compared to the oxychloride solid electrolytes
Erick Ruoff   +2 more
wiley   +1 more source

Investigation Into the Electrochemical Performance of Micron‐ and Nanosized Tin in Diglyme and Carbonate Electrolytes in Sodium Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
This study compares Sn particles of different sizes in NIBs using carbonate‐ and diglyme‐based electrolytes. Diglyme electrolytes enable stable cycling despite large volume changes, while carbonate electrolytes degrade rapidly, especially with nanoparticles.
Chinnasamy Murugesan   +4 more
wiley   +1 more source

Silicon‐Based Anodes for Sulfide Solid‐State Batteries: Failure Mechanisms and Multiscale Design Strategies

open access: yesAdvanced Energy Materials, EarlyView.
Silicon anodes in sulfide SSBs face coupled electrochemo‐mechanical failure by interface instability. This review examined recent advances and proposed mitigation strategies via material‐, electrode/interface‐, and cell‐level‐ engineering. We further evaluate scalable synthesis of sulfide SEs.
Murugesan Karuppaiah   +4 more
wiley   +1 more source

Sputtering Mechanism of an Unsintered Organic–Inorganic Sputtering Target for Perovskite Solar Cells

open access: yesAdvanced Energy Materials, EarlyView.
An unsintered MAPbI3 sputtering target fabricated via a mechanochemical route enables large‐area vacuum deposition of perovskite absorber layers, while revealing an ion–photon coupled decomposition mechanism that governs target erosion and film composition under RF plasma exposure.
Doha Lim   +9 more
wiley   +1 more source

Mechanisms of Alkali Ionic Transport in Amorphous Oxyhalides Solid State Conductors

open access: yesAdvanced Energy Materials, EarlyView.
Large‐scale machine learning‐based molecular dynamics simulations are used to investigate isovalent amorphous oxyhalides, revealing a remarkable chemically independent ionic conductivity. A rigorous analysis of alkali residence times across different metal–anion environments identifies divalent anions as key diffusion bottlenecks.
Luca Binci   +3 more
wiley   +1 more source

Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations

open access: yesAngewandte Chemie, EarlyView.
Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera   +2 more
wiley   +2 more sources

Complex Iridium Oxides Converge In Structure And Reactivity During Acidic Oxygen Evolution Electrocatalysis

open access: yesAdvanced Energy Materials, EarlyView.
Ir‐based double perovskites restructure during acidic oxygen evolution electrocatalysis through dissolution of non‐Ir cations and convergence toward IrOx active‐site motifs with similar structure and intrinsic activity across compositions. The identity of the dissolving cations controls dissolution and surface reconstruction kinetics, clarifying how ...
Harrison H. Lippie   +5 more
wiley   +1 more source

A Decoupled Cycling Architecture of Asymmetric Zinc‐Air Battery Unlocks Stable Catalyst Strategy and pH‐Dynamic Influence

open access: yesAngewandte Chemie, EarlyView.
A decoupled cycling architecture along with cost‐effective membrane and efficient catalyst is developed for asymmetric zinc‐air battery. The decoupled design ensures stable operation of catalyst and the pH‐dynamic influence on battery performance is explored, which provides paths for efficient utilization of pH‐decoupling electrolytes.
Yeshu Tan   +6 more
wiley   +2 more sources

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