Results 111 to 120 of about 6,148 (200)

On Oxalyl Halide Isothiocyanates Part I: Syntheses and Isomerism

European Journal of Inorganic Chemistry, Volume 29, Issue 21, 25 July 2026.
Oxalyl halide isothiocyanates can be prepared from oxalyl halide with one equivalent of NH4SCN in liquid SO2. While oxalyl bromide isothiocyanate can be isolated as a liquid, the respective chloride compound readily undergoes isomerization under formation of a thiazole ring, which is obtained as a solid.
Sven Ringelband, Jonathan Pfeiffer, Frank Tambornino   +2 more
wiley   +1 more source

Actinide 4,4′‐Bipyridine‐N,N′‐Dioxide Coordination Polymers: Cationic Framework Structures Templated by Dicyanoaurate and Tetracyanoaurate Counterions

European Journal of Inorganic Chemistry, Volume 29, Issue 21, 25 July 2026.
Th4+ or UO22+ actinides, neutral bipyridine‐N,N’‐dioxide ligands, and anionic cyanoaurate linkers are combined to generate a family of four coordination polymers. ‘Truss bridge’ and square grid cationic frameworks are yielded when using [Au(CN)2]− or [Au(CN)4]−, respectively, indicating a templating effect guided by either aurophilic interactions ...
Sylvain St. Louis, Thomas E. Karpiuk, Daniel B. Leznoff   +2 more
wiley   +1 more source

Impact of Electronic Substitution and Planarization on the Photophysical Properties of 2‐(2′‐Hydroxyphenyl)benzoxazole or 2‐(2′‐Hydroxyphenyl)‐Dimethylindole

European Journal of Organic Chemistry, Volume 29, Issue 28, 25 July 2026.
We report the synthesis, structural characterization, and photophysical investigation of a series of Excited‐State Intramolecular Proton Transfer‐active HBO and HDMI derivatives. By varying heterocyclic cores, substituents, and ethynyl planarization, we establish structure–property relationships governing fluorescence behavior.
Mathieu Gervais, Timothée Stoerkler, Gilles Ulrich, Pascal Retailleau, Tristan Asset, Adèle D. Laurent, Denis Jacquemin, Julien Massue   +7 more
wiley   +1 more source

Crystal structure and Hirshfeld surface analysis of dimethyl(phenyl)phosphine sulfide

Acta Crystallographica Section E Crystallographic Communications
The title compound, C8H11PS, which melts below room temperature, was crystallized at low temperature. The P—S bond length is 1.9623 (5) Å and the major contributors to the Hirshfeld surface are H...H (58.1%), S...H/H...S (13.4%) and C...H/H...C contacts (11.7%).
Robin Risken, Yasin Mehmet Kuzu, Annika Schmidt, Carsten Strohmann   +3 more
openaire   +3 more sources

Stabilizing the Hexacyanotrimethylenecyclopropane Electron Acceptor—Structural and Photophysical Characterization

Angewandte Chemie International Edition, Volume 65, Issue 30, 20 July 2026.
An improved low‐temperature synthesis enables the first comprehensive structural and spectroscopic characterisation of neutral hexacyanotrimethylenecyclopropane (CN6CP). Combined IR/Raman, UV–Vis and ssNMR analyses reveal a deeper understanding of its oxidation‐state‐dependent charge redistribution, σ‐aromaticity of the cyclopropane core, and redox ...
Jan P. Soyka, Alok Mahata, Anja Wiesner, Jennifer Hartfiel, Christian E. Halbig, Katharina J. Franke, Ute Resch‐Genger, Biprajit Sarkar, Siegfried Eigler   +8 more
wiley   +1 more source

“Innocent” Electrolytes Can Influence Organic Electrosynthetic Selectivity

ChemElectroChem, Volume 13, Issue 14, 17 July 2026.
Organic electrosynthesis has emerged as a powerful strategy for leveraging inexpensive and abundant electricity in organic synthesis, but understanding the role of inert supporting electrolyte is largely unexplored. This article investigates cobalt‐based metal–carbon bond homolysis and elucidates how supporting electrolytes influence reaction rates ...
Zachary A. Nguyen, Nhu H. Quach, Mayank Tanwar, Joshua A. Beeler, Kevin McFadden, Dylan G. Boucher, Matthew Neurock, Shelley D. Minteer   +7 more
wiley   +1 more source

Crystal structure and Hirshfeld surface of a pentaaminecopper(II) complex with urea and chloride

Acta Crystallographica Section E Crystallographic Communications
The reaction of copper(II) oxalate and hexamethylenetetramine in a deep eutectic solvent made of urea and choline chloride produced crystals of pentaaminecopper(II) dichloride–urea (1/1), [Cu(NH3)5]Cl2·CO(NH2)2, which was characterized by single-crystal X-ray diffraction.
Olivia D. Breen, Tony D. Keene
openaire   +3 more sources

Cyclometalated Au(III) Complexes With C*N^N, N^C*N, and C*N Ligands Through C–H Activation

Zeitschrift für anorganische und allgemeine Chemie, Volume 652, Issue 11, 16 July 2026.
The complexes [Au(QPhPy)Cl][AuCl4], [Au(QPhCF3Py)Cl][AuCl4], [Au(QPhtBuPy)Cl][AuCl4], [Au(QPhPy)Cl]Cl, [Au(QPyPh)Cl2], [Au(QPyPhCF3)Cl2], [Au(QPyPhtBu)Cl2], [Au(bpyAn)Cl][AuCl4], and [Au(phenAn)Cl][AuCl4] (Q = 8‐quinolinyl, Ph = phenyl, An = anthracen‐9‐yl, Py = pyridyl, bpy = 2,2′′‐bipyridyl, phen = 1,10‐phenanthrolinyl) containing N*C^N, N*C, and NN ...
Pascal L. Jurzick, Leo Payen, Bruno Poti e Silva, Francisco Luan Rodrigues Lino, Vladimir Stojadinovic, Axel Klein   +5 more
wiley   +1 more source

Synthesis, crystal structure and Hirshfeld surface analysis of 5-methyl-1H-pyrazol-3-yl 4-nitrobenzenesulfonate at 90 K

Acta Crystallographica Section E: Crystallographic Communications
This study presents the synthesis, crystal structure, and a Hirshfeld-surface analysis of the bioactive compound 5-methyl-1H-pyrazol-3-yl 4-nitrobenzenesulfonate(C10H9N3O5S), a pyrazole derivative with pharmacological potential.
Vinaya, Syida A. Yakuth, Thaluru M. Mohan Kumar, Besagarahally L. Bhaskar, Thayamma R. Divakara, Hemmige S. Yathirajan, Yeriyur B. Basavaraju, Sean Parkin   +7 more
doaj   +1 more source

Hirshfeld surfaces from experimental charge-density data [PDF]

Acta Crystallographica Section A Foundations of Crystallography, 2010
Radosław Kamiński, Anna A. Hoser, Krzysztof Woźniak   +2 more
openaire   +1 more source