Results 121 to 130 of about 4,722,216 (249)

Synthesis, crystal structure and Hirshfeld surface analysis of Fmoc-β-amino butyric acid and Fmoc carbamate [PDF]

open access: yes
In the context of the development of synthetic routes that facilitate the incorporation of β-amino acids into peptide synthesis, the synthesis, crystal structure and Hirshfeld surface analysis are reported of fluorenylmethoxycarbonyl (Fmoc) protected β ...
Abubakar Magaji, M.   +5 more
core   +1 more source

Boosting Built‐In Electric Field via Asymmetric Architecture for Synergistic Production of H2O2 and Benzaldehyde

open access: yesEcoEnergy, EarlyView.
Asymmetric architecture was built for synergistic production of H2O2 and benzaldehyde. The reaction mechanism involves the synergistic utilization of electrons and holes, which jointly enables efficient oxygen activation to support the simultaneous production of two high‐value products.
Han Wang   +7 more
wiley   +1 more source

Glycerol‐Modified Biphasic Silicone Gel for Synergistic Thermal Transport and Dielectric Reliability

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A surfactant‐free glycerol‐modified biphasic silicone gel establishes metastable liquid interfaces that simultaneously enhance phonon transport and induce deep traps (1.28 eV), enabling synergistic electrothermal performance of enhanced thermal conductivity (+33.3%), thermal diffusivity (+48.3%), and DC breakdown strength (+57.6%) with suppressed space
Xinyue Zhang   +3 more
wiley   +1 more source

An Excellent Deep‐Ultraviolet Nonlinear Optical Crystal Realized via a Functional Group Based on a Two‐in‐One Strategy

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A “two‐in‐one” design strategy integrating guanidinium and carboxyl functional groups was developed to overcome the intrinsic trade‐off among SHG response, ultraviolet cutoff edge, and birefringence in DUV NLO crystals. Benefiting from non‐π‐conjugated electronic isolation, Zn‐GPA(II) simultaneously achieves a strong SHG response (2.1 × KH2PO4), an ...
Xiliang Jiang   +8 more
wiley   +1 more source

Selective Adsorption of o‐Xylene From all C8 Aromatics via Secondary Connectivity Manipulation in B←N Frameworks

open access: yesAngewandte Chemie, Volume 138, Issue 42, 12 October 2026.
A programmed assembly strategy based on secondary connectivity integration allows modulating the B←N framework (BNF) microenvironment. Beyond possessing improved stability, the resulting BNFs achieve highly selective adsorption of o‐xylene from all C8 aromatics.
Xiang‐Shuai Li   +9 more
wiley   +2 more sources

A Robust Densification Strategy Toward Ultrahigh Energy Density in All‐Organic Dielectric Polymer Films

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A scalable densification strategy is proposed by incorporating sucrose into a fluoropolymer matrix to build a robust hydrogen‐bond crosslinking network. The intermolecular interactions effectively facilitate polar phase transformation and reduce free volume fraction.
Lingni Yang   +11 more
wiley   +1 more source

Activating Triplet Excitons in COFs via Layer‐Bridging Co Single Atoms for Photocatalytic H2O2 Production and Tandem C─N Coupling

open access: yesAngewandte Chemie, Volume 138, Issue 42, 12 October 2026.
This work demonstrates a layer‐bridging coordination strategy of Co single atoms in COFs that promotes the formation and utilization of triplet excited states. The introduction of Co single atoms induces pronounced energy‐level splitting and enhanced spin–orbit coupling, facilitating the generation of 1O2 and O2•– for efficient photocatalytic H2O2 ...
Guoen Tang   +6 more
wiley   +2 more sources

Multifunctional Oleylamine Enables Direct Regeneration of Spent Lithium Iron Phosphate Cathodes through Coupled Lattice and Interface Repair

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A multifunctional oleylamine‐assisted solvothermal strategy is introduced for coupled lattice and interface repair of S‐LFP cathodes. Benefiting from its strongly coordinating amine groups and long hydrophobic alkyl chains, oleylamine simultaneously acts as an intrinsic reductant, defect‐repair mediator, morphology stabilizer, and carbon/nitrogen ...
Yuan Feng   +11 more
wiley   +1 more source

Structural and Spin–Orbit Coupling Synergy Enables Tunable Afterglow in Cytosine‐Based Hybrid Materials

open access: yesLaser &Photonics Reviews, EarlyView.
Zero‐dimensional organic–inorganic hybrid materials (Cyt)2ZnX4·H2O (X = Cl, Br) were synthesized using cytosine (Cyt) and zinc halides, enabling effective regulation of room‐temperature phosphorescence (RTP) through halogen substitution in the inorganic [ZnX4]2− unit.
Chenxin Fan   +6 more
wiley   +1 more source

Computational design of poly(p‐phenylene vinylene)‐based gas sensors: tunable reactivity and selectivity via side‐group functionalization

open access: yesPolymer International, EarlyView.
Side‐group functionalization enhances the reactivity and optoelectronic properties of poly(p‐phenylene vinylene) (PPV) derivatives for chemical sensing. PPV‐CN and PPV‐NO2 display strong interactions and pronounced responses, providing molecular‐level insights for designing high‐performance polymer‐based sensors.
Bruno Hori Barboza   +3 more
wiley   +1 more source

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