Homogeneously catalysed conversion of aqueous formaldehyde to H2 and carbonate
Nature Communications, 2017 Aqueous formaldehyde is an attractive hydrogen storage system due to the high weight percentage of hydrogen present. Here the authors report a highly active homogeneous ruthenium catalyst system, allowing hydrogen production from formaldehyde-water under
M. Trincado +5 more
doaj +1 more source
Magnetically Separable Base Catalysts: Heterogeneous Catalysis vs. Quasi-Homogeneous Catalysis
Applied Sciences, 2012 The synthesis of magnetically separable quasi-homogeneous base catalyst and heterogeneous base catalyst is described. The quasi-homogeneous catalyst is achieved by supporting silane monomers functionalized with different amine groups directly on the ...
Raed Abu-Reziq, Howard Alper
doaj +1 more source
Homogeneous, heterogeneous, and enzyme catalysis in microfluidics droplets
Smart Molecules, 2023 Microfluidics has received extensive attention due to its ability to rapidly prepare a large number of microdroplets with controlled sizes and defined morphologies.
Fang Mei +5 more
doaj +1 more source
Trispyrazolylborate Ligands Supported on Vinyl Addition Polynorbornenes and Their Copper Derivatives as Recyclable Catalysts [PDF]
, 2019 Polynorbornenes prepared by vinyl addition poly- merization and bearing pendant alkenyl groups serve as skeletons to support trispyrazolylborate ligands (Tpx) built at those alkenyl sites.
Albéniz Jiménez, Ana Carmen +6 more
core +2 more sources
Graphitic phosphorus coordinated single Fe atoms for hydrogenative transformations
Nature Communications, 2020 Phosphorus ligands have been extensively used in metal complexes for homogeneous catalysis. Here, the authors broaden this scope to heterogeneous catalysis by preparing a P-coordinated Fe single atom catalyst with excellent catalytic performance in ...
Xiangdong Long +8 more
doaj +1 more source
Physical Chemistry, Chemical Physics - PCCPThe application of density functional theory (DFT) methods in catalysis has been growing fast in the last few decades thanks to both the availability of more powerful high computing resources and the development of new efficient approximations and ...
Valeria Butera
semanticscholar +1 more source
Review of catalytic systems and thermodynamics for the Guerbet condensation reaction and challenges for biomass valorization [PDF]
, 2015 The Guerbet condensation reaction is an alcohol coupling reaction that has been known for more than a century. Because of the increasing availability of bio-based alcohol feedstock, this reaction is of growing importance and interest in terms of value ...
Gabriels, D +4 more
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Model arenes hydrogenation with silica-supported rhodium nanoparticles:The role of the silica grains and of the solvent on catalytic activities [PDF]
, 2009 Silica-supported rhodium-based nanoheterogeneous catalysts were easily prepared by impregnation with a pre-stabilized colloidal suspension. The resulting catalysts contain rhodium nanoparticles well-dispersed in the silica pores with a mean size of 5 nm.
Barthe, Laurie +5 more
core +4 more sources
Heterogeneous Catalysis on a Disordered Surface
, 1995 We introduce a simple model of heterogeneous catalysis on a disordered surface which consists of two types of randomly distributed sites with different adsorption rates.
D. ben-Avraham +17 more
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Ring-opening copolymerization (ROCOP): synthesis and properties of polyesters and polycarbonates [PDF]
, 2015 Controlled routes to prepare polyesters and polycarbonates are of interest due to the widespread application of these materials and the opportunities provided to prepare new copolymers. Furthermore, ring-opening copolymerization may enable new poly(ester–
Brooks, R +5 more
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