Results 71 to 80 of about 948,396 (365)

Features of triamyl citrate synthesis

open access: yesТонкие химические технологии, 2023
Objectives. To find an effective way for obtaining triamyl citrate, an environmentally friendly, biodegradable citric acid ester used as a plasticizer for PVC-based polymer compositions.Methods.
A. D. Shiryaeva   +3 more
doaj   +1 more source

Modelling and Environmental Assessment of Heterogeneous Catalysis Biodiesel Process Using War Algorithm [PDF]

open access: yes, 2013
Environmental assessment in a preliminary designing stage of a process is important to evaluate the environmental friendliness of a process design, minimizing the environmental impact of the process.
As Eleyana, Ali
core  

NanoMOF‐Based Multilevel Anti‐Counterfeiting by a Combination of Visible and Invisible Photoluminescence and Conductivity

open access: yesAdvanced Functional Materials, EarlyView.
This study presents novel anti‐counterfeiting tags with multilevel security features that utilize additional disguise features. They combine luminescent nanosized Ln‐MOFs with conductive polymers to multifunctional mixed‐matrix membranes and powder composites. The materials exhibit visible/NIR emission and matrix‐based conductivity even as black bodies.
Moritz Maxeiner   +9 more
wiley   +1 more source

A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis

open access: yesNature Communications, 2019
Supramolecular interactions may be responsible for higher degree of efficiency and selectivity in homogeneous catalysis. Here, the authors exploit the concept of supramolecular catalysis to develop a domino rhodium-catalyzed hydroformylation of α ...
Weiwei Fang   +3 more
doaj   +1 more source

Cu‐Based MOF/TiO2 Composite Nanomaterials for Photocatalytic Hydrogen Generation and the Role of Copper

open access: yesAdvanced Functional Materials, EarlyView.
HKUST‐1/TiO2 composite materials show a very high photocatalytic hydrogen evolution rate which increases as a function of the irradiation time until reaching a plateau and even surpasses the performance of the 1%Pt/TiO2 material after three photocatalytic cycles.
Alisha Khan   +9 more
wiley   +1 more source

Homogeneous catalysis [PDF]

open access: yesJournal of Organometallic Chemistry, 1974
J. Burgess   +2 more
  +5 more sources

A study of effects of H–H quartic auto catalytic reaction with equal diffusivity in the swirling flow exterior to a rotating cylinder

open access: yesInternational Journal of Thermofluids, 2023
In this study, we investigate the influence of quartic auto catalysis with equal diffusivity in the flow past a rotating cylinder. The flow-thermal fields are modeled using partial differential equations (PDEs), assuming a homogeneous–heterogeneous ...
S. Saranya   +3 more
doaj   +1 more source

Pickering Emulsion-Derived Liquid-Solid Hybrid Catalyst for Bridging Homogeneous and Heterogeneous Catalysis.

open access: yesJournal of the American Chemical Society, 2019
We describe a novel method to prepare a liquid-solid hybrid catalyst via interfacial growth of a porous silica crust around Pickering emulsion droplets, which allowed us to overcome the current limitations of both homogeneous and heterogeneous catalysts.
Xiaoming Zhang   +6 more
semanticscholar   +1 more source

MnI‐Functionalized Covalent Organic Framework as Efficient Electrocatalyst for CO2 Reduction in a Catholyte‐Free Zero‐Gap Electrolyzer

open access: yesAdvanced Functional Materials, EarlyView.
This work demonstrates the successful integration of a phenanthroline‐based 2D COF with MnI catalytic sites into a catholyte‐free membrane‐electrode‐assembly cell for CO2 electroreduction. The crystalline COF actively suppresses Mn⁰–Mn⁰ dimerization, achieving a turnover frequency of 617 h⁻¹ at 2.8 V (full‐cell potential), and enabling stable operation.
Laura Spies   +8 more
wiley   +1 more source

Rapid and scalable photocatalytic C(sp2)–C(sp3) Suzuki−Miyaura cross-coupling of aryl bromides with alkyl boranes

open access: yesNature Communications
In recent years, there has been a growing demand for drug design approaches that incorporate a higher number of sp3-hybridized carbons, necessitating the development of innovative cross-coupling strategies to reliably introduce aliphatic fragments. Here,
Ting Wan   +6 more
doaj   +1 more source

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