Results 201 to 210 of about 927,205 (366)

Synthesis of Unnatural Amino Acids via β‐Aminoaldehyde C–H Arylation using HAT‐Metallaphotoredox Catalysis

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract Unnatural amino acids play a crucial role in advancing protein engineering and drug development. In this study, we present the synthesis of a series of γ‐aryl‐keto‐α‐amino acids through the direct C−H arylation of readily accessible β‐aminoaldehydes and aryl bromides, promoted by hydrogen atom transfer combined with metallaphotoredox catalysis.
Mariana dos S. Dupim   +3 more
wiley   +1 more source

A rapid method for fractionating serum bilirubin by HPLC.

open access: bronze, 1987
H Nakamura   +3 more
openalex   +2 more sources

Biomimetic Orthogonal Removal of Arylacyl Protecting Groups from the C‐Terminus of Substituted Amino Acids and Oligopeptides via Flavin N(5)‐iminium Covalent Adducts

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract Flavin co‐factors and other flavin derivatives are traditionally associated with one‐ or two‐electron redox reactions. Flavins also form covalent intermediates with a variety of substrates. While extensive attention has focused on reactions at the C(4a) position of the flavin ring, recent interest has shifted toward the dynamic potential of ...
Tetiana Pavlovska   +3 more
wiley   +1 more source

Double‐Sided Control of Product Type Preference in the Visible‐Light Initiated Reaction of 1,3‐Dicarbonyl Compounds with Alkenes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract The demonstrated light‐initiated addition of radicals formed on an active methylene group to styrene derivatives exhibits a product selectivity influenced by the presence of a protic solvent. Under protic conditions, the predominant products are branched compounds with the alkene moiety attached to the methylene group.
Małgorzata Pałyga   +2 more
wiley   +1 more source

Simultaneous determination of zeranol, 17.BETA.-estradiol and diethylstilbestrol in beef by HPLC with amperometric detection using column switching.

open access: bronze, 1989
Kenjiro WATABE   +6 more
openalex   +2 more sources

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