Rational design of tetrahydrotetrazinones as potent nonclassical radical-trapping antioxidants for inhibition of ferroptosis. [PDF]
Ouyang C, Huang J, Wu Z.
europepmc +1 more source
Application of dynamic acylhydrazones to achieve CANs with shape‐memory properties. ABSTRACT Covalent adaptable networks (CANs) are based on reversible crosslinks, which are present within the polymer network structure. Due to these reversible moieties, CANs feature interesting properties/abilities such as self‐healing after damage, shape‐memory ...
Farhad Shohraty +6 more
wiley +1 more source
Insights on Regioselective Synthesis of Fused Thiazoles: Density Functional Theory Calculations, Local Reactivity Indices, and Molecular Electrostatic Potential Analysis. [PDF]
Al-Hazmi GH +8 more
europepmc +1 more source
Solvent‐Controlled Electrochemical Cyclization of Areneazo‐2‐(2‐nitro)propanes to Benzo[c]cinnolines
Solvent‐mediated redox pathway control enables the first electrochemical cyclization of areneazo‐2‐(2‐nitro)propanes to benzo[c]cinnolines. Mixed solvent systems containing hexafluoroisopropanol (HFIP) and MeOH additives widen the redox potential gaps and stabilize diazonium intermediates via hydrogen bonding, favoring oxidative intramolecular ...
Chohee Lee +3 more
wiley +1 more source
An Umbrella Review of Meta-Analyses on the Efficacy and Safety of Eltrombopag in Immune Thrombocytopenia. [PDF]
Dabir M +6 more
europepmc +1 more source
Reversible Dihydrogen Splitting and Diradical Reactivity of 1,4‐Digermabenzene‐1,4‐diide
The diradical reactivity of the 1,4‐digermabenzene‐1,4‐diide, [(ADC)Ge]2, has been demonstrated with a range of substrates. Notably, it undergoes reversible dihydrogen splitting and radical coupling with TEMPO (2,2,6,6‐tetramethylpiperidinyloxyl = RO), forming [(ADC)GeH]2 and [(ADC)Ge(OR)]2, respectively.
Falk Ebeler +5 more
wiley +1 more source
Access to Nitrogen-nitrogen Bond-Containing Heterocycles Through Substrate Promiscuity of Piperazate Synthases. [PDF]
Li Y +9 more
europepmc +1 more source
Design and synthesis of new bis-hydrazones and pyridine bis-hydrazones: application in the asymmetric Diels-Alder reaction [PDF]
Bermejo Gómez, Antonio +4 more
core +1 more source
Rhodium‐Catalyzed Regioselective Addition of N‐Hydroxyl Imides to Internal Alkynes
An intermolecular rhodium‐catalyzed regioselective addition of N‐hydroxyl imides to internal alkynes leads to branched O‐allyl compounds, which can be readily transformed to allylic alcohols and O‐allyl hydroxylamines after deprotection. Isotopic labelling experiments suggest a plausible reaction mechanism.
Zi Liu, Bernhard Breit
wiley +1 more source
Ti-catalyzed 1,2-Diamination of Alkynes Using 1,1-Disubstituted Hydrazines. [PDF]
Karmakar PS +7 more
europepmc +1 more source

