Semi-empirical design and synthesis of novel 4-hydroxy-6-sulphonaphthyl azohydroxynaphthalenes with predominant hydrazone form [PDF]
Due to their enhanced photochromic effects, hydrazone forms of tautomeric azo compounds are commercially preferred as photoreceptors and binary switches.
Olusegun E. Thomas, Olajire A. Adegoke
doaj +2 more sources
Photochemical and electrochemical studies on lanthanide complexes of 6-(hydroxymethyl)pyridine- 2-carboxaldehyde[2- methyl-pyrimidine-4,6-diyl] bis-hydrazone [PDF]
Herein we report the synthesis of the 6-(hydroxymethyl)pyridine-2- carboxaldehyde[2-methyl-pyrimidine- 4,6-diyl]bis-hydrazone by a condensation reaction between 6-(hydroxymethyl) picolinaldehyde with 4,6-(bis-hydrazino)-2- methylpyrimidine.
María Alejandra Fernandez +3 more
doaj +2 more sources
Vinylogous Hydrazone Strategy for the Organocatalytic Alkylation of Heteroaromatic Derivatives [PDF]
A new umpolung approach for the asymmetric FriedelCrafts-type alkylation of electron-poor heteroaromatic systems has been developed. It is based on the vinylogous reactivity of hydrazones derived from heteroaromatic aldehydes.
Beata, Łukasik +3 more
core +1 more source
Asymmetric [4+2]-cycloaddition of Anthracene Derivatives via Hydrazone Activation [PDF]
Enantio- and diastereoselective dearomative [4+2]-cycloaddition reaction between N,N-dimethylhydrazone derived from 9-anthracenecarbaldehyde and α,β-unsaturated aldehydes is reported.
Jakub, Ossowski +3 more
core +1 more source
Nickel-Catalyzed Cross-Coupling Methylation of Aryl and Heteroaryl Electrophiles via Hydrazone Umpolung [PDF]
Methyl groups play a vital role in pharmaceutical substrates, where their installation onto aryl and heteroaryl moieties can often lead to enhanced drug-target interactions.
Daliah, Farajat +7 more
core +1 more source
DNA Functionality with Photoswitchable Hydrazone Cytidine [PDF]
A new family of hydrazone modified cytidine phosphoramidite building block was synthesized and incorporated into DNA oligonucleotides to construct photoswitchable DNA strands.
Ya Ying, Zheng +4 more
core +1 more source
Effect of the alkyl linker length on the photoisomerization of hydrazone switches on metal surfaces [PDF]
A series of bistable hydrazone switches containing alkyl thiolate linkers of various lengths (Cn HAT, n = 3, 8, 10, and 11) were synthesized. We explore the length effect of the carbon chain on the photoisomerization of hydrazone switches using UV-vis ...
Ivan, Aprahamian +6 more
core +1 more source
Catalysis of Hydrazone and Oxime Peptide Ligation by Arginine [PDF]
Hydrazone and oxime peptide ligations are catalyzed by arginine. The catalysis is assisted intramolecularly by the side-chain guanidinium group. Hydrazone ligation in the presence of arginine proceeds efficiently in phosphate buffer at neutral pH but is ...
Jérôme, Vicogne +6 more
core +1 more source
Metallaphotocatalytic Amination of Aryl Chlorides Enabled by Highly Crystalline Acetylene-Based Hydrazone-linked Covalent Organic Frameworks [PDF]
Amination of aryl chlorides by metallaphotocatalysis is highly desired but remained practically challenging. Meanwhile, relying on soluble noble-metal photocatalysts suffers from resource scarcity and structural instability which limit their practical ...
Gang, Wu +12 more
core +1 more source
Synthetic and Biocidal Studies of Zn-Hydrazone Complexes [PDF]
A series of hydrazone derivatives were synthesized through multi-step reactions. The 2-(2-oxo-1,2,3,4-tetrahydroquinoline-7-yloxy)acetohydrazide was prepared from 7-hydroxy-3,4-dihydroquinolin-2(1H)-one as starting material. Then the condensation of 2-(2-
Gupta, Nitin +2 more
core +2 more sources

