Results 91 to 100 of about 24,235 (299)

Synthesis, crystal structure and hydrogenation properties of MgxLi3 − xB48 − y (x = 1.11, y = 0.40)

open access: yesActa Crystallographica Section E: Crystallographic Communications
The ternary magnesium/lithium boride, MgxLi3 − xB48 − y (x = 1.11, y = 0.40, idealized formula MgLi2B48), crystallizes as its own structure type in P43212, which is closely related to the structural family comprising α-AlB12, Be0.7Al1.1B22 and tetragonal
Nazar Pavlyuk   +3 more
doaj   +1 more source

Ultrastable Self‐Cross‐linkable Electro‐Optic Materials Based on a Bisanthracene Scaffold

open access: yesAdvanced Electronic Materials, EarlyView.
A novel bisanthracene‐based self‐cross‐linkable electro‐optic chromophore (TD2) is developed. TD2 exhibits a high r33 of 141 pm/V and a cross‐linked Tg up to 195 °C, retaining 99.75% of its initial EO response after 500 h at 85 °C, showing record‐high thermal stability for single‐molecule self‐cross‐linking EO materials.
Xingtao Wang   +6 more
wiley   +1 more source

Arenas of Expectations for Hydrogen Technologies [PDF]

open access: yes
Technological options can be regarded as variations in an evolutionary development process. The variations are put forward by their respective technological communities and are selected by technology selectors.
Harro van Lente   +2 more
core  

Materials engineering of metal hydrides [PDF]

open access: yes, 1981
Intermetallic hydrides of the AB/sub 5/ type have enthalpies in the range valid for chemical heat pumps. A scheme for manufacturing hydrides with optimal properties for a chemical heat pump is described, using LaNi/sub 5-x/Al/sub x/ and ZrV/sub 2x/Cr/sub
Mendelsohn, M. H., Gruen, D. M.
core  

Sodium-based hydrides for thermal energy applications [PDF]

open access: yes, 2016
Concentrating solar–thermal power (CSP) with thermal energy storage (TES) represents an attractive alternative to conventional fossil fuels for base-load power generation.
Humphries, Terry   +2 more
core   +1 more source

Catalytic Enantioselective Multicomponent Reactions of Sulfoxonium Ylides Enabled by a Formal Rearrangement—A Versatile Entry to Enantioenriched α‐Sulfanyl Carbonyl Compounds

open access: yesAngewandte Chemie, EarlyView.
A catalytic network embedding a formal rearrangement enables the first catalytic enantioselective multicomponent reaction (MCR) of sulfur ylides. In the presence of a bulky chiral phosphoric acid, the reaction combines sulfoxonium ylides, aldehydes and thiols, and affords synthetically versatile β‐hydroxy‐α‐sulfanyl carbonyl compounds in ...
Nicolò Santarelli   +10 more
wiley   +2 more sources

Fabrication of Composite Cathode for All‐Solid‐State Sodium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
The design of composite cathodes for all‐solid‐state sodium batteries must address three critical challenges—interfacial side reactions, interfacial delamination, and highly tortuous transport pathways. This work outlines structural and interfacial strategies to optimize ion transport and mechanical stability, enabling durable, and high‐performance ...
Gaoming Sun   +6 more
wiley   +1 more source

Mechanochemical synthesis of magnesium-based hydrogen storage materials

open access: yes, 2003
PhDA systematic investigation of the structural stability, evolution and hydrogenstorage properties of Mg-based hydrides was carried out, involving mechanical milling and chemical alloying.
Shang, Congxiao
core  

Addition of Nitrogen-Containing Heteroallenes to Iron(II)-Hydrides

open access: yes, 2016
The reactions between cis-Fe(dmpe)2H2 (dmpe = Me2PCH2CH2PMe2) (1) or cis-Fe(PP3)H2 (PP3 = P(CH2CH2PMe2)3) (2) and phenyl isothiocyanate (PhNCS), ethyl isothiocyanate (EtNCS), and phenyl isocyanate (PhNCO) were investigated.
Leslie D. Field (1599472)   +2 more
core   +1 more source

Bifurcation of *COOH Pathway Determines HCOOH Formation in CO2 Electroreduction on Bismuth

open access: yesAngewandte Chemie, EarlyView.
Driven by the mechanistic debate of Bi‐catalyzed CO2‐to‐HCOOH conversion, ambiguity remains regarding true reaction pathways. To resolve this, we combined constant‐potential AIMD simulations with spectroscopic evidence to analyze the competitive pathways.
Hyun Dong Jung   +4 more
wiley   +2 more sources

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